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Testing a diffusion and reaction model for the leaching of CCA components from unfixed CCA-treated wood
2002 - IRG/WP 02-50193
A previously described physical model applicable to the leaching of any substance undergoing a first-order fixation reaction with wood is applied to the leaching of CCA components from unfixed wood. Using this model and laboratory leaching experiments with small wood samples immersed in water, the diffusion coefficients and reaction rate constant of Cr6+, total Cr, Cu and As in unfixed CCA-treated...
L Waldron, P A Cooper


The use of TCMTB in applications other than sapstain prevention: A review
1990 - IRG/WP 3606
The efficacy of TCMTB against staining fungi and surface moulds has been thoroughly investigated during the last decade. As a result, the chemical is used as an alternative to the chlorinated phenols in various parts of the world for the preservation of freshly sawn timber. Less known are the data obtained against brown rot, white rot and soft rot fungi. The termite repellent and bactericidal prop...
R Van der Eynde


The distribution of introduced acetyl groups and a linseed oil model substance in wood examined by microautoradiography and ESEM
2000 - IRG/WP 00-40169
Microautoradiography, a photographic method that shows the localization of substances labelled with radioactive isotope, and Environmental Scanning Electron Microscopy (ESEM) were combined to enhance sensitivity, resolution and reliability for examination of the distribution of introduced substances in wood. The preparation of microautoradiographs is less complicated when investigated with ESEM an...
M Rosenqvist


An engineering model for the decay of timber in ground contact
2003 - IRG/WP 03-20260
To predict the residual strength of an engineered structure, it is first necessary to predict the effect of decay. A model was developed in which the effective area of structural decay in large section timbers was defined as that area that could be picked out with a pen-knife. Some limited studies indicated that for practical purposes the remaining wood could be assumed to have its full residual s...
R H Leicester, C-H Wang, M N Nguyen, J D Thornton, G Johnson, D Gardner, G C Foliente, C MacKenzie


Tebuconazole - a new triazole fungicide for wood preservation
1991 - IRG/WP 3680
The great potential of Tebuconazole for wood preservation is demonstrated. Test carried out by official institutes shown that Tebuconazole is particularly effective against wood-rotting basidiomycetes strains. The efficacy of Tebuconazole against the brown rot Gloeophyllum trabeum is outstanding: the toxic value measured in accordane with EN 113, without·ageing, after leaching (EN 84) and after e...
O Exner


A new model for wetting and drying of wood end-grain – with implications for durability and service-life
2011 - IRG/WP 11-20477
New experimental data for wetting and drying of wood end-grain, Sandberg (2009), imply that traditional models for moisture transport are not at all applicable. A new model is developed to consider the phenomenological behaviour of water transport in and out of end-grain, using the pore water pressure and sorption scanning properties. Modelling results are compared to experimental results and the ...
L-O Nilsson, K Sandberg


Model of termite distribution in Portugal - Follow-up
2003 - IRG/WP 03-10470
In Portugal, subterranean termites of the genus Reticulitermes are indigenous and a well-established pest of wood in service. Mapping their distribution has therefore become important. A field sampling campaign was established along a North-South transect based on 50x50 km cells (Universal Transverse Mercator grid system, UTM). A variety of typical habitats, ranging from forest sites of Eucalyptu...
T Nobre, L Nunes


The use of a physical field model to study the effects of remedially treated timber on the growth of perennial ryegrass (Lolium perenne) and rye (Secale cereale), and the accumulation of toxic preservative constituents in Lolium perenne
1995 - IRG/WP 95-50040-02
Low cost laboratory model systems can be used to give relatively rapid indications of the environmental effects of preservative treated timber in soil contact. This paper details the effects of remedially treated timber on the growth of crops of Lolium perenne and Secale cereale seeded on soilbeds of different texture in close proximity to remedially treated creosoted pole sections. Lolium perenne...
D C R Sinclair, G M Smith, A Bruce, H J Staines


Resistance of painted wood to mould fungi. Part 2. The effect of wood substrate and acrylate paint systems on mould growth
1997 - IRG/WP 97-10234
Resistance of acrylate paint systems on different types of pine and spruce sapwood to mould fungi was studied. Dipping into the preservative prior to painting, a primer with and without a fungicide (propiconazole + IPBC 0.50 + 0.2%) and a topcoat with and without a fungicide (propiconazole + IPBC 0.25 + 0.12%) were combinations of the treatments studied. The efficacy of the treatment systems varie...
H Viitanen, P Ahola


Assessment of dehydrogenase activity, fluoride content and total chromium content of soil profiles exposed to preservative treated wood within a model system
1993 - IRG/WP 93-10015
The development and prospective use of a closed model system to facilitate study of a number of indicators of environmental impact of wood preservatives laboratory conditions has been described (IRG/WP/2395-92). Chemical analysis of leachate samples collected from drained soil profiles containing creosoted pole sections remedially treated with a chromated fluoride preservative indicated small incr...
G M Smith, D C R Sinclair, A Bruce, H J Staines


Initial results and observations of a model system to assess the efficacy and environmetal impact of preservative treated wood
1993 - IRG/WP 93-50001-02
The development of a closed model system for the laboratory assessment of the efficacy and environmental impact of a chromated fluoride remedial treatment for creosoted distribution poles has been described (IRG/WP/2395-92). The model consists of a precipitation apparatus above a treated pole section positioned in a soil profile from which leachate was collected via a series of simulated field dra...
D C R Sinclair, G M Smith, A Bruce, H J Staines


Reaction of osmium tetroxide with a diphenolic compound as a model substance for demethylated lignin
1986 - IRG/WP 1303
By using caffeic acid as a model substance for diphenolic moieties of demethylated lignin it was found that electron dense particles called by the authors "osmiophilic particles" in former papers are reaction products of OsO4 with the model substance. By these products it is possible to indicate the enzymatic demethylation of lignin taking place during wood decay. The appearance of the electron de...
K Messner, E Srebotnik


Evaluating possibilities of leaching of deltamethrin and TCMTB (insecticides and fungicide for protecting wood) by rain water or by soaking in water
1988 - IRG/WP 3464
Deltamethrin and TCMTB have been subjected to several field leaching tests on freshly fallen trees and in the laboratory, using standard EN 84. All the trials gave the same results and confirm that Deltamethrin and TCMTB are not washed out after they have been allowed to penetrate the trunk surface properly. According to the EN 84 standard, less than 1% Deltamethrin and less than 1.7% TCMTB were r...
J S Duguet, V Dartigues


Proposed model for the penetration and decay of wood by the hyphal sheath of the brown-rot fungus Postia placenta
1989 - IRG/WP 1391
Scanning electron microscopy (SEM) of Pinus sp. decayed by the brown-rot fungus Postia placenta confirmed the existence of extracellular membranous structures previously described by transmission electron microscopy (TEM). These structures appear to be an integral part of the hyphal sheath and assume a variety of forms including lamellar sheets, fibrils, and vesicles. These structures were observe...
F Green III, M J Larsen, L L Murmanis, T L Highley


Degradation of lignin model compounds with coordinated copper in the presence of peroxide
1998 - IRG/WP 98-10282
A novel diffusible system capable of decomposing lignin model compounds with copper, coordinators and peroxides has been proposed. When pyridine was used as a copper coordinator, two synthetic dyes, Poly-R and RBBR were intensively decolorized with Cu(II) and H2O2 in aqueous solutions at room temperature. Although reactions with Cu(II) and H2O2 produce a strong oxidant, hydroxyl radical, via a Fen...
K Koller, K Messner, T Watanabe


The impact of global warming on the UK distribution of house longhorn beetle Hylotrupes bajulus (L)
2001 - IRG/WP 01-10414
This paper reviews the effects of global warming on insect populations and distribution. The affects of global warming on the spread of Hylotrupes is predicted through a review of research related to the influence of temperature on its life-cycle and flight. Records of Hylotrupes distribution were obtained from published surveys, entomologists and museum collections and were plotted for the UK. Th...
P Oevering, A J Pitman


Dimensional lumber model demonstrates the sensitivity of the particle capture immunoassay in early detection of brown-rot fungi
1995 - IRG/WP 95-20058
A dimensional lumber model was designed to test the sensitivity of the particle capture immunoassay (PCI) compared to traditional methods of culturing and microscopic examination for detection of brown-rot fungi. Southern yellow pine 2 x 4's (5.1x10.2 cm²), and 86.4 cm in length, were inoculated on one end with the brown-rot fungus, Postia placenta, and tested over the full length of the...
C A Clausen, L Ferge


Development of a model system to assess the efficacy and environmental impact of a chromated fluoride remedial treatment for creosoted distribution poles
1992 - IRG/WP 92-2395
A closed model system was designed to facilitate a controlled study of the leachability and environmental fate of a remedial preservative under laboratory conditions. The elements of the model include a precipitation apparatus above a treated pole section which is positioned in a representative soil profile supporting a sward of perennial ryegrass. The model will allow detailed examination of the ...
D C R Sinclair, G M Smith, A Bruce, B King


Integrated protection of freshly sawn lumber using Bacillus subtilis and selected fungicide
1997 - IRG/WP 97-10235
Bioprotection against stain fungi has tremendous potential for reducing discoloration of freshly sawn wood while decreasing chemical consumption. Unfortunately, most bioprotectants appear to be unable to consistently perform under the array of conditions to which freshly sawn wood is exposed. While research is underway to understand the nature of the inconsistent performance, a more pragmatic appr...
M E Mankowski, M Anderson, J J Morrell


Properties-enhanced albizzia particleboards by incorporating fungicide and insecticide in the glue
1994 - IRG/WP 94-30060
Preservative-treated particleboards were prepared by using tropical fast-growing albizzia and adding fungicides and insecticides to the adhesive-glue. the physical and biological properties of these boards were evaluated. No significant reduction in bending or internal-bond strength due to incorporation of the chemicals was detected. Treated particleboards effectively resisted attack by Coptoterme...
B Subiyanto, S Yusuf, Y Imamura, S Fushiki, T Saito, T Katuzawa


Tebuconazole - A new triazole fungicide for wood preservation
1990 - IRG/WP 3629
The main cause of economic damage to timber and millwork worldwide are Basidiomycetes (brown and white rot). After testing a wide range of triazole derivatives for their effectiveness against decay fungi, Tebuconazole, a triazole compound, was selected. The physico-chemical, toxicological and ecotoxicological data of this substance are described. Tebuconazole is unleachable, light-stable, heat-sta...
R Gründlinger, O Exner


Mechanistic aspects of the reactions of copper complexes with lignin in the presence of hydrogen peroxide and lipid hydroperoxide model compounds as proposed for white rot fungi
2001 - IRG/WP 01-10399
The structural principles and the oxidative reactions of the catalytic system consisting of copper, hydroperoxides, and copper coordination compounds that contain aromatic nitrogen atoms are similar to those of catalytic centers of oxidative enzymes involved in delignification reactions of white rot fungi. The system is capable of selectively degrading lignin and its low molecular weight would all...
K Fackler, P Lamaipis, E Srebotnik, M Humar, C Tavzes, F Pohleven, M Sentjurc, T Watanabe, K Messner


The suitability of isothiazolone microemulsions as long term wood preservatives
1997 - IRG/WP 97-30150
Microemulsion formulations of 4,5 dichloro-2-n-octyl-4-isothiazolin-3-one were investigated to determine the leaching potential of these formulation types as well as their efficacy against decay fungi. These patented low leaching formulations exhibited good anti fungal efficacy in standard tests combined with minimal leaching of the active ingredient from the wood. The data suggests that the excel...
B M Hegarty, Bing Yu, L E Leightley


IPBC - A new fungicide for wood protection
1984 - IRG/WP 3295
3-iodo-2-propynyl butyl carbamate (IPBC) is presented as a potential low toxic alternative to pentachlorophenol and the sodium chlorophenoxides. Data on its effect against basidiomycetes is shown. Tests according to both the European standard method, EN-113, and American, ASTM D-413, have shown its potential. The chemical gives protection against both the wood destroying fungi, blue stain, mould and algae. It is possible to have it formulated in both water-based and organic solvent-based products. Treatment of wood out of ground contact (vac-vac products, pretreatment products, primers, stains, etc.) and sapstain control are some of the most potential end use areas within wood protection. Besides wood protection, the IPBC is used as a fungicide in paint, adhesives, caulks and sealants, cement, leather, paper, cutting oil, ink and in different roofing materials.
J Hansen


Practical experiments with Boracol 10 Rh used as a fungicide in the repair process after attack by the dry rot fungus (Serpula lacrymans)
1987 - IRG/WP 3458
The test is carried out in an old house in Nyhavn, Copenhagen. The roof and the walls close to were heavily attacked by dry rot fungus (Serpula lacrymans) because damage to the zinc covering the frontspice were letting in water to the wood and wall construction. An attack by the dry rot fungus is more complicated to repair compared with other wood destroying fungi because beside the damage on wood...
J Bech-Andersen


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