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The content and mobility of copper, chromium and arsenic in the soil of a wood preserving plant using CCA
1998 - IRG/WP 98-50122
Analyses were carried out on soil and water samples obtained from a wood preserving plant using CCA-type preservatives. The plant has been in operation since 1969. The soil samples were obtained on 8 points from 4 different depths. The estimation of the type of soil was followed by investigations of copper, chromium and arsenic contents, and the mobility of these elements. The soil samples were al...
N Erdin, S N Kartal, A Dilek Dogu, M O Engür


Microdistribution of Copper in Copper-Ethanolamine (Cu-EA) Treated Southern Yellow Pine (Pinus spp.) related to density distribution
2004 - IRG/WP 04-40270
The relationship between copper absorption and density distribution in wood cell walls was investigated in this study. The density distribution on layer level was obtained from two approaches: (1) calculation by using data obtained from literature; (2) microdistribution of carbon and oxygen atoms in the wood cell. The microdistribution of carbon and oxygen in untreated southern yellow pine (Pinus ...
Jinzhen Cao, D P Kamdem, E Pasek


Determination of bis-(N-cyclohexyl-diazeniumdioxy)-copper in different matrices by photometer, thermal energy analyzer and HPLC
1999 - IRG/WP 99-20179
For the quantitative analysis of bis (N-cyclohexyl-diazeniumdioxy)-copper (Cu-HDO) three analytical methods are used. The employment of the different methods depends on the matrices involved. For several years now, the colorimetric determination of Cu-HDO by photometer has been applied to solutions and concentrates of wood preservatives. In principle, the technique consists of a quantitative conve...
J Wittenzellner, W Hettler, M Maier


Kinetics of the dissociation of Cr, Cu, and As in fixed CCA-treated wood
2001 - IRG/WP 01-50168
The results of an experiment showing the kinetics of the dissociation of CCA compo-nents in water within treated wood samples are presented. Dry red pine (Pinus resinosa Ait.) samples were simultaneously vacuum-treated with water, then expressed to re-move the water at successive time intervals. The expressate was then analyzed for Cr, Cu, and As concentration by inductively coupled plasma (ICP). ...
L Waldron, P A Cooper


Inorganic preservative levels in soil under treated wood decks after 8 years natural exposure in Borås, Sweden
2005 - IRG/WP 05-50233
Inorganic preservative components (Cu, Cr and As) were measured to a depth of 150 mm under deck structures made with Scots pine lumber treated with several different wood preservatives and installed in Borås Sweden 8 years ago. Higher contaminant levels were observed mainly under the drip lines and in the top 50 mm of soil. Under CCA treated decks, soil arsenic concentrations increased from ba...
P A Cooper, Y T Ung, M-L Edlund, J Jermer


FTIR characterization of copper ethanolamine - wood interaction
1999 - IRG/WP 99-20154
The interaction of copper ethanolamine (Cu-EA) and wood components was studied by using Fourier transform infrared spectroscopy (FTIR). In Cu-EA treated wood, significant reduction was noticed on the band attributed to carbonyl vibration from carboxylic groups at 1735±5 cm-1 and an increase in band intensity was obtained from carbonyl in carboxylate at 1595±5 cm-1. The same observation was made ...
Jun Zhang, D P Kamdem


Detoxification of salt impregnated wood by organic acids in a pulping process
1993 - IRG/WP 93-50012
The paper descibes a novel method to detoxify pine wood (Pinus silvestris L.) treated with CCB-, CCF- CC-, and Cu-HDO-type salt preservatives. In the process of biological detoxification organic acids produced by strains of Antrodia vaillantii and other brown rot fungi are used for the dissolution of the previously fixed inorganic compounds. These findings are the basis for applying an acid pulpin...
I Stephan, H H Nimz, R D Peek


Removing Cu, Cr and As from CCA treated yellow pine by oleic acid
2003 - IRG/WP 03-50202
In this study, CCA treated yellow pine utility poles were cut into three different dimensions and 4 different pH levels (2, 2.5, 3.5 and 5) of Oleic acid was used. The leached wood samples were collected at the end of the 1, 3, 7 and 14 days to determine the remaining Cu, Cr and As concentrations. The concentrations of Cu, Cr and As were determined by X-RF. The effects of pH, dimension and duratio...
E D Gezer, Ü C Yildiz, S Yildiz, E Dizman, A Temiz


Kinetics and mechanism of fixation of Cu-Cr-As wood preservatives. Part 4: Conversion reactions during storage
1974 - IRG/WP 332
Precipitates simulating those produced in wood by preservative fixation reactions were prepared by the reduction of Boliden K 33 and Celcure AP solutions with hydrogen peroxide and hydrazine. The pH changes on aging at 20 and 50°C were studied and related to the chemistry of fixation previously described. Hydrolysis of copper arsenates may render arsenic acid temporarily water soluble pending pre...
S-E Dahlgren


A comparison of shower test results from CCF, CCZF, CCB and Cu-quat treated timber
1995 - IRG/WP 95-50054
The shower test quantifies the amount of specific preservative components which leach from treated timber under simulated open storage conditions. The test method measures leaching from both organic and inorganic salt treated timber. Shower tests of CCF, CCZF, CCB and Cu-quat treated timber which have been performed over the last 5 years by TNO are reviewed and compared. Leached components are qua...
M J Boonstra, A J Pendlebury, P Esser


Micro-Distribution of Metals in Wood Treated with a Nano-Copper Wood Preservative
2007 - IRG/WP 07-40360
The microdistribution of copper in southern pine treated with a newly-developed nano-copper wood preservative was examined to determine if it differed from that reported for wood treated with conventional copper-based wood preservatives. Field Emission Scanning Electron Microscopy (FE-SEM) in combination with x-ray microanalysis (EDX) revealed the presence of nano-sized copper and iron particles i...
H Matsunaga, M Kiguchi, P Evans


Kd values of Cu, Cr, As in different soil matrix
2007 - IRG/WP 07-50247
Chromated copper arsenate (CCA), a long history of successful preservative, have raised environmental concerns. Adsorption characteristics of domestic soils for chromium, copper, and arsenic were assessed by measuring distribution coefficient (Kd) values of these metal components. The results revealed that Kd values were higher in chromium, followed by arsenic and copper in soil matrix. Different...
Sung-Mo Kang, Seung-Hun Shin, Ja-Oon Koo


Effect of steam on fixation of Cu-amine preservative treated wood
2008 - IRG/WP 08-50251
The rates of copper fixation in copper amine preservative treated wood were investigated with different fixation conditions (20° with drying and 50° without drying) and post-steaming. We also measured the degree of leaching for other biocide components (azoles, quatz, and Cu-HDO). Treatments conditioned at 20° with drying required 50 days or more to fix in woods. While copper was stabilized i...
Sung-Mo Kang, In-Yong Hwang, Suk-Kuwon Kim


Copper nanoparticles in southern pine wood treated with a micronised preservative: Can nanoparticles penetrate the cell walls of tracheids and ray parenchyma?
2010 - IRG/WP 10-30547
This study tests the hypothesis that copper nanoparticles can penetrate the cell walls of southern pine wood treated with a micronised preservative. We examined the nanodistribution of particles in tracheid and ray parenchyma cell walls using state-of-the-art HR (High Resolution)-TEM and HR-STEM (Scanning Transmission Electron Microscope)-EDX. These devices are capable of atomic-scale resolution. ...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Effect of Nano-Silver Treatment on Densified Wood Properties. Part One: Swelling, Recovery Set, Bending Strength
2010 - IRG/WP 10-40533
In this research the effect of Nano-Silver treatment on compressed wood properties, was studied. Wood specimens were cut from Popolus alba (poplar) and impregnated with Nano-Silver and water. Then the saturated samples were compressed through radial direction in a hot press under pressure of 6 MPa, for 1 and 4 hours. The temperatures of press were 150°C and 175°C. Swelling (24h), recovery set ...
G Rassam, H Reza Taghiyari, B Jamnani, M Ali Khaje


Wood protection by nano silver against white rot
2011 - IRG/WP 11-30554
This research was done with the aim of investigation on the natural durability of poplar (populous deltoides) in natural situation and treated with nano silver against the white rot. Testing samples was treated with the method of modified soaking and nano silver in 3 treating level of 0,200 and 400ppm. In this study effect of coriolus versicolor fungus (identificated as white rot) on populous del...
V Tazakor Rezai, A Usefi, M Soltani


Effect of Nano-silver Treatment on Densified Poplar Wood Properties. Part Two: Spring Back, Compression set, Impact Load Resistance and Hardness
2011 - IRG/WP 11-40568
This paper is the second part of the study of applying nano-silver treatment before densification of poplar wood (Popolus alba). The specimens were prepared in four groups of: 1) nano-silver impregnated 2) water impregnated 3) dried with no impregnation and 4) the control specimens. The impregnation process was done by empty cell process. Then, the groups of 1 to 3 were compressed in a hot press a...
G Rassam, H Reza Taghiyari, B Jamnani, M Ali Khajeh


Effects of nano-silver on brittleness of heat-treated solid woods
2011 - IRG/WP 11-40572
The present study is aimed at the effect of heat-treatment of normal as well as nano-silver-impregnated Populus nigra, Populus deltoides, and Fagus orientalis on brittleness. Specimens were impregnated with 200 ppm water-based solution of nano-silver particles under 3 bars in a pressure vessel using empty-cell process. For heat treatment, both nano-silver-impregnated and normal specimens were kept...
H Reza Taghiyari, B Moradi Malek, A Karimi


Effects of Nano-Wollastonite on Ignition Time Reduction in MDF
2012 - IRG/WP 12-40576
Effects of wollastonite nano-fibers on ignition time reduction in medium density fiberboard were studied. Nanowollastonite was applied at 5, 10, 15, and 20 g/kg dry weight basis of wood fibers and compared with control specimens. Two application methods of nanowollastonite were used: surface application, and internal application. Specimens of 150×130×9 mm were prepared and the ignition times wer...
H Reza Taghiyari, H Rangavar, P Noori, A Karimi


Effects of Nano-Zycosil on Liquid and Gas Permeability of MDF
2012 - IRG/WP 12-40578
Effects were studied of zycosil nanoparticles, with size range from 30 to 90 nm, on liquid and gas permeability of medium density fiberboard. 100 g of nanozycosil was added to each kg of dry fibers. Density was kept constant at 0.67 g/cm3. The obtained results indicated that addition of zycosil to the mat resulted in a significant increase in gas permeability due to the lower fiber-content in the ...
H Reza Taghiyari, K Heidarhaee, P Noori, A Karimi


Effects of nano-wollastonite impregnation on fire resistance and dimensional stability of Poplar wood
2012 - IRG/WP 12-40595
The fire-retardant properties of Nano-Wollastonite (NW) in poplar wood (Populus nigra) were determined in this study. Some physical properties such as water absorption, volumetric swelling and Anti-Swelling Efficiency (ASE) were also measured. Specimens were prepared according to the ISO 11925 standard for the fire-retarding properties, and ASTM D4446-2002 standard for the physical properties. Imp...
A Karimi, A Haghighi Poshtir, H Reza Taghiyari, Y Hamzeh, A Akbar Enayati


Nano structural properties of La2O3-Beech Wood Flour With XRD technique
2012 - IRG/WP 12-40607
This research was considered to study various properties of the Lanthana mixed with beech wood flour (BWF), as a new structure. For this purpose, La2O3 powders in the BWF have been obtained by sol-gel method using simultaneous gelation of all cations. La2O3 - BW samples are analysed by X-ray diffraction .The obtained results showed the formation of nano crystalline La2O3 phases. The average crys...
M Ghorbani Kokandeh, I Bahamni, A Bahari


A case study of investigating fungi that affect traditional Japanese shake roof with/without copper plates
2013 - IRG/WP 13-10810
A Japanese traditional shake roof is made from split logs. To keep the roof long, copper (Cu) plates are often inserted between the shakes. It has been thought that Cu elements from copper plates would flow out when a shake roof is exposed to rain and inhibit growth of wood rotting fungi. Actually there are some examples where the Cu plates seem to be effective in preventing fungal damage, but on ...
T Wada, Y Fujiwara, Y Fujii, R Kigawa


Effect of Nano and Micronized Particles as Wood Preservatives for Termite Control
2013 - IRG/WP 13-30620
Subterranean termites are a major factor in the biodegradation of wood constructor products. In this study the efficacy of wood treated with micronized copper, zinc oxide and their mixture was compared to that of wood treated with soluble amine copper oxide with subterranean termites in a laboratory test. All of the formulations tested were effective in controlling wood degradation by the termites...
M Akhtari, D Nicholas, A Rowlen, M Arefkhani


Copper leaching from copper-ethanolamine treated wood during exposure to terrestrial microorganisms
2013 - IRG/WP 13-30621
Copper-ethanolamine based wood preservatives are still the most important solutions for protection of wood in ground applications in Europe. Wood in ground is exposed to variety of organisms, which can act synergistically. In order to simulate these conditions in laboratory, Scots pine (Pinus sylvestris) specimens impregnated with copper-ethanolamine preservative of three different concentrations ...
M Humar, N Thaler, B Lesar


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