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The Effect on Biological and Moisture Resistance of Epichlorohydrin Chemically Modified Wood
2002 - IRG/WP 02-40224
Southern pine solid wood and fiber were chemically modified with epichlorohydrin to help in understanding the role of moisture in the mechanism of biological effectiveness of chemically modified wood. The solid wood had weight gains from 11% to 34%, while the fiber had weight gains from 9% to 75%. After modification, part of the specimens were water leached for 2 weeks or extracted for 2 hours ...
R E Ibach, B-G Lee


Thermal modification of non-durable wood species 2. Improved wood properties of thermal treated wood
1998 - IRG/WP 98-40124
Properties of wood treated in a new heat-treatment process called the PLATO-process have been studied. Several wood species have been treated using this new thermal modification process using a range of process conditions (mainly time and temperature). In this study the characteristics of the treated wood were determined using samples from whole planks treated on pilot plant scale. The modified ch...
B F Tjeerdsma, M J Boonstra, H Militz


Microwave modification of wood properties - Improvements in wood permeability
2000 - IRG/WP 00-40181
A new method of microwave (MW) wood modification is described. Microwave irradiation of timber provides an improvement in wood permeability mainly in the radial and longitudinal directions. This is achieved by physically modifying ray cells and forming a large number of cavities in the radial - longitudinal planes. More extensive MW irradiation of different species transforms the wood into a new m...
G Torgovnikov, P Vinden


Dimensional stability and decay resistance of wood upon modification with some new type chemical reactants
1994 - IRG/WP 94-40028
Solid wood of home grown species can be upgraded by chemical modification with environmentally acceptable chemicals. The best kwown example of modification reaction is acetylation with acetic anhydride. A continued search for reactive chemicals other than acetic anhydride is ongoing, aiming at the improvement of technical properties of wood. This contribution deals with the results of a screening ...
P Goethals, M Stevens


Assessing the bioresistance conferred to solid wood by chemical modification
1997 - IRG/WP 97-40099
The chemical modification of wood using straight chain alkyl anhydrides can considerably enhance its durability. This paper presents an assessment of the effectiveness of these modifiers in improving the biological resistance of a susceptible softwood when exposed to four different basidiomycete fungi, soft rots and the larvae of the house longhorn beetle (Hylotrupes bajulus). It was clear that so...
E D Suttie, C A S Hill, D Jones, R J Orsler


Bending properties of wood after its decay with Coniophora puteana and subsequent modification with selected chemicals
1999 - IRG/WP 99-40146
Mechanical properties of wood are often decreased due to decay processes caused by biotic and/or abiotic factors. Damaged wooden elements (e.g. historical structures) can be reinforced by more methods, including their modification with convenient chemicals. This paper presents influences of selected chemicals on basic bending properties (modulus of elasticity - MOE, modulus of rupture - MOR) of so...
L Reinprecht, S Varinska


Comparison of thermally modified wood originating from four industrial scale processes – durability
2002 - IRG/WP 02-40229
This study examined the differences in biological wood properties of heat treated wood originating from four different European industrial heat treatment plants. The manufacturers of heat treated material were: PLATO Hout B.V./Netherlands, Thermo Wood/Finland, New Option Wood/France and Menz Holz/Germany where Oil-Heat treated Wood (OHT) is produced. The results of miniblock tests with basidiomyc...
C R Welzbacher, A O Rapp


The kinetics of anhydride modification reactions of wood. Experimental results and theoretical modelling
1998 - IRG/WP 98-40125
Although the chemical modification of wood remains a fertile area for research, there has been little work performed on the kinetics of the modification process. The reaction kinetics of a series of linear chain and cyclic anhydrides has been studied and activation energies of the reaction determined. The reaction kinetic profiles are determined by the relative rates of reaction of the reagent wit...
C A S Hill, J G Hillier


Microwave modification of Yellow Stringybark (Eucalyptus Muelleriana) posts for impregnation with Copper-Chrom-Arsenic (CCA) preservatives
2000 - IRG/WP 00-40185
Yellow Stringybark posts with diameters ranging from 60-100 mm were microwave conditioned using a 60 kW microwave (MW) generator. A substantial improvement in heartwood penetration of preservatives and relaxation of growth stresses was indicated such that there was no split formation following drying of the posts. High preservative absorption of copper-chrome-arsenic (CCA) was achieved ranging fro...
G Torgovnikov, P Vinden


Modification of solid wood: research and practical potential
1997 - IRG/WP 97-40098
The polymeric structure of the wooden cellwall mainly consists cellulose, hemicellulose and lignin. The most reactive sites on these components are the hydroxyl groups. The cellwall polymers (and its reactive hydroxyl groups) are responsible for most physical and chemical properties of wood. By changing the basic chemistry of the cellwall polymers, it is possible to change different undesirable at...
H Militz, E P J Beckers, W J Homan


Biological degradation resistance of wood acetylated with thioacetic acid
1983 - IRG/WP 3223
Chemically, modification of wood is being considered as an alternative to conventional preservation by toxic chemicals. Acetylated wood has been reported to be quite resistant to most biodegrading organisms at weight percent gains (WPG) around 15-19. The conventional acetylation techniques with acethic anhyrdride result in generation of acetic acid. However, acetylation with thioacetic acid overco...
S Kumar, S C Agarwal


Three years of field tests with "Lignomer" stakes in ground contact
1981 - IRG/WP 3166
The "Lignomer" (Wood Polymer Composite) is a material obtained during the polymerisation of various monomers or its mixtures in wood. As laboratory tests have shown, this material is characterized by a high resistance against biological deteriorating agents. The laboratory investigations on the durability of various materials against biological deterioration are in many instances extended by field...
K Lutomski


Three-year field trials of polymeric formulations which provide a new basis for the invention and design of non-toxic wide-spectrum wood preservatives
1994 - IRG/WP 94-40029
Three types of non-toxic polymeric formulations invented using a new approach to wood preservation were challenged with termites and fungi in three-year ground-contact field trials in the sub-tropical climate of Natal. These formulations were copper soaps of carboxylic acid groups of unsaturated fatty acids of waxes and edible vegetable oils; of resin acids of rosin, and, of synthetic unsaturated ...
A A W Baecker, A Pizzi


Screening of the technical performance and aquatic toxicity of N-methylolacrylamide treated wood
2000 - IRG/WP 00-40166
In the course of the last decades chemical modification of wood species, with a limited natural durability, has been subjected to intensive research. As a possible alternative and supplementary treatment of non-durable wood in a range of applications it remains one of the major topics in the wood preservation world. Different modification systems have been scaled-up and are now in an industrialisi...
V Rijckaert, S De Geyter, J Van Acker, M Stevens


Characteristics of thermally modified wood in vacuum
2004 - IRG/WP 04-40287
In commercial thermal wood modification processes nitrogen, steam or oil has been used for the reduction of oxygen content in the reactor atmosphere. In present study no special heating medium, but an initial vacuuming step has been used for this purpose. Mass loss, resistance to fungal decay, dimensional stability, bending strength and modulus of elasticity of heat treated wood were evaluated and...
G Rep, F Pohleven, B Bucar


Oral toxicity of TIM-BOR®, Bora-Careä, boric acid and ethylene glycol against the formosan subterrean termite and easter subterrean termite
1993 - IRG/WP 93-10045
Oral toxicities (LD50) of boric acid, TIM-BOR® (disodium octaborate tetrahydrate: DOT) and BORA-CAREä (40% DOT in ethylene glycol) and ethylene glycol (ca. 80% monoethylene and ca. 20% polyethylene glycol) were estimated. Oral toxicities of BORA-CAREä were significantly higher (LD50: 256.2 µg/g DOT and 304.9 mg/g BAE) than TIM-BOR® alone (LD50: 408.2 µg/g DOT and 485.7 µg/g BAE); indicating...
M Tokoro, N-Y Su


Effect of fungal degradation on the chemical composition of acetylated beech wood
2003 - IRG/WP 03-40267
This study investigated the impact of fungal attack on the chemical composition of acetylated wood. Beech wood acetylated to different degrees was exposed to decay by the white-rot fungus Trametes versicolor under solid-state fermentation conditions. Laboratory soil-bed assays were also conducted to study the degradation of acetylated wood by soft rot fungi and other soil-inhabiting microorganisms...
H Militz, Dong-won Son, L Gómez-Hernández, R Sierra-Alvarez


Test methods for modifies wood: The EU-Thematic network approach
2002 - IRG/WP 02-20255
The last decade wood modification systems have become new wood treatment methods in Europe. Alongside several industrial initiatives for heat treatments also scaling up and pilot plant projects for chemical wood modification have recently been carried out. In 2000 an initiative to create a network related to these new developments was supported by the European Commission. Within the work proposed ...
J Van Acker, D Jones


Melamine resins as preservatives results of biological testing
1996 - IRG/WP 96-40061
Based on previous work of the authors on resins, the upgrading of wood with a true solution of a methanol etherificated melamine resin in low aqueous concentration was performed. For the relative assessment of the biological resistance against brown and white-rot fungi were used not only untreated controls of pine sapwood (Pinus sylvestris L.), but also heartwood of European larch (Larix decidua M...
A O Rapp, R-D Peek


Characterization of wood decay enzymes by MALDI-MS for post-translational modification and gene identification
2002 - IRG/WP 02-10442
The recent sequencing of the Phanerochaete chrysosporium genome presents many opportunities, including the possibility of rapidly correlating specific wood decay proteins of the fungus with the corresponding gene sequences. Here we compare mass fragments of trypsin digests, determined by MALDI-MS (Matrix Assisted Laser Desorption Ionization-Mass Spectrometry), with predicted mass fragments derive...
T H de Koker, P J Kersten


Effects of the sulfuric acid modification of CCA treating solution
1987 - IRG/WP 3415
Sulfuric acid modification of CCA treating solution is often used to control the formation of sludges and undesirable deposits on the surface of treated wood. The consequences of sulfuric acid addition are examined in this work and negative effects are shown to far outweigh any benefits. Major risks include the loss of copper due to leaching from treated wood and the accelerated corrosion of treat...
R F Fox, H J Fry, E A Pasek, A S Ross


Boracol 40 - A potential remedial and preservative treatment for lyctids
1983 - IRG/WP 1192
The paper reports on a preliminary assessment of the efficacy of a diffusion formulation, Boracol 40, when applied as a brush treatment: to the surface of Eucalyptus obliqua against the powder-post borer Lyctus brunneus. After a five month bioassay, Boracol 40 has severely retarded the progress of active infestations of Lyctus brunneus and has been 100 per cent effective as a preventative treatmen...
J W Creffield, H Greaves, C D Howick


Blue Staining of Coated Modified and Unmodified Wood
2006 - IRG/WP 06-10589
We investigated resistance of unmodified, DMDHEU modified and oil heat treated uncoated and coated Scots pine wood against blue stain fungi. Both EN 152-1 and the reverse exposure tests showed excellent resistance of DMDHEU and especially of oil heat treated wood against blue staining. It is not needed to add any additional protective coating layers to prevent modified wood from staining. However,...
M Petric, M Pavlic, M Humar, M Tomažic


High-energy multiple impact (HEMI)-test – Part 2: A mechanical test for the detection of fungal decay
2006 - IRG/WP 06-20339
The suitability of the high-energy multiple impact (HEMI)-test for detection of early fungal decay was examined. The HEMI – test characterizes the treatment quality of thermally modified wood by stressing the treated material by thousands of impacts of pounding steel balls. This method differentiates between heat treatment intensities, which are expressed by structural changes of the wood. Simil...
C R Welzbacher, C Brischke, A O Rapp


High-energy multiple impact (HEMI)-test – Part 1: A new tool for quality control of thermally modified timber
2006 - IRG/WP 06-20346
Thermal modification processes improve durability and dimensional stability of wood, but the strength properties, especially the dynamic ones, are compromised and need to be considered with respect to industrial quality control. Results from standard dynamic strength testing, such as impact bending tests, suffer from high variability, and therefore require a high number of replicates. To overcome ...
C Brischke, A O Rapp, C R Welzbacher


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