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The examination of preservative-treated radiata pine using electron spin resonance spectroscopy
1987 - IRG/WP 3423
Electron spin resonance spectroscopy (ESR) may be used to characterise the molecular environment of chemical species containing unpaired electrons. These species include free radicals, bi-radicals, point defects in solids, localised crystal imperfections and many transition metal ions. ESR has previously been applied to the examination of wood weathering or wood pyrolysis and now FRI and Massey Un...
D V Plackett, E W Ainscough, A M Brodie


A comparison of analytical and visual techniques used for assessment of weathering properties of chromium and copper azole treated timber
1994 - IRG/WP 94-20023
The weathering properties of preservative treated timber were studied by measuring surface lignin loss and by microscopic examination after weathering, and results were related to qualitative assessments of visual appearance after weathering. Measurement of relative rates of delignification of untreated and preservative treated timber obtained by FTIR analysis, and weight loss determined on thin v...
J A Cornfield, M D C Hale, G Fettis


Examination of preservative-treated Pinus sylvestris using electron paramagnetic resonance
1992 - IRG/WP 92-3710
EPR is currently being used to help elucidate the nature and extent of the chemical reactions occurring between wood and copper based timber preservatives. In the work reported here treated Scots pine samples were examined at room temperature and in the frozen state. Plots of the electronic parameters A|| vs. g|| were found to be a useful index of the electronic properties of the various formulati...
A S Hughes, R J Murphy, J F Gibson, A J Cornfield


Hole delimination inside round timber via ultrasonic techniques
1990 - IRG/WP 2358
A fast and economic circular scanning method to localize and evaluate holes inside round timber is presented. This method consists in measuring transit times of the ultrasonic wave by fixing the transmitter probe in the perimeter of the sample, then moving the receiver probe every ten degrees until completion of the circle. The scanning is done with a cheap and light instrument. Tests are made wit...
G Prieto, A Fernández Cancio


Phenol oxidase activity and one-electron oxidation activity in wood degradation by soft-rot deuteromycetes
2007 - IRG/WP 07-10615
Wood degradation, one-electron oxidation activity as assayed by ethylene generation from 2-keto-4-thiomethylbutyric acid (KTBA), and phenol oxidase activity were measured in cultures of six deuteromyce fungi, with glucose or wood as the carbon source. The four fungi that degraded Japanese beech wood had higher one-electron oxidation activities in wood-containing cultures than in glucose-containing...
H Tanaka, M Yamakawa, S Itakura, A Enoki


Weathering of Wood Modified with the N-Methylol Compound 1,3‑dimethylol-4,5-dihydroxyethyleneurea (DMDHEU)
2009 - IRG/WP 09-40467
Scots pine (Pinus sylvestris L.) sapwood boards were treated with a methylated 1,3‑dimethylol-4,5-dihydroxyethyleneurea (mDMDHEU) causing weight gains of approx. 25% and exposed to weathering for 18 months. Compared to untreated boards, treatment with mDMDHEU reduced surface discoloration mainly caused by staining fungi. Boards treated with mDMDHEU exhibited clearly lower moisture content th...
C Mai, Yanjun Xie, A Krause, K Urban, P D Evans, K Richter, H Militz


The Use of Micro-Tensile Testing to Assess Weathering Decay and Oxidative Degradation of Wooden Items
2010 - IRG/WP 10-20433
This paper presents a method to study the weathering performance of wooden items and to assess the oxidative degradation of wood via the Fenton reaction. Weathering resistance and photo-stability of wood was tested using pine wood (Pinus sylvestris) veneer strips measuring approximately 60 µm in thickness. The veneer strips were treated using a reactive chemical to impart surface protection. The ...
C Mai, Yanjun Xie, Zefang Xiao, P D Evans, H Militz


Analyzing hyphal growth of the bio incising fungus Physisporinus vitreus with light-, confocal laser scanning- and, Synchrotron X-ray tomographic microscopy
2010 - IRG/WP 10-20438
Norway spruce wood is an important building material for the forest and wood industry. To improve wood permeability and uptake of wood modification substances Physisporinus vitreus is employed as a bioincising agent. In this study wood specimens were incubated with P. vitreus to assess hyphal colonisation and structural alterations of Norway spruce wood. After different incubation periods, semi-th...
C Stührk, M Fuhr, M Schubert, F W M R Schwarze


Direct estimation of the durability of high-pressure steam modified wood by ESR-spectroscopy
2010 - IRG/WP 10-40508
Heat generated persistent free radicals have been detected by electron spin resonance measurement of thermally modified wood, prepared by high pressure superheated steam treatment. The specific density of these radicals have been correlated with the durability against basidiomycetes, as measured by the European standard EN113 test. In the lower range of specific radical densities, the found correl...
W Willems, A Tausch, H Militz


Copper Nanoparticles in Southern Pine Wood Treated with a Micronised Preservative: Nanodistribution of Copper in the Pit Membrane and Border of an Earlywood Bordered Pit
2011 - IRG/WP 11-30566
Copper nanoparticles can penetrate the cell walls of unlignified parenchyma cells in southern pine wood treated with a micronised wood preservative, but they are excluded from lignified tracheid walls. This paper extends these observations to include the cell wall layers of the bordered pit. Focused ion beam and ion milling were used to make an ultra-thin section of the cell wall layers of an earl...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Further Studies on the Distribution of Copper in Treated Wood Using an XRF Microscope Technique
2011 - IRG/WP 11-40549
There are two distinct forms of copper in aqueous copper based wood preservative systems that are currently used in the United States for treatment of southern pine lumber. These are systems using either soluble copper (typically amine based) or the more recent particulate or “micronized” copper as the primary biocide. Studies reported last year showed that there were distinct differences in...
A Zahora


Accessibility of Wood Cell Walls to Well-defined Platinum Nanoparticles
2012 - IRG/WP 12-20494
Copper nanoparticles are found in the walls of parenchyma cells in southern pine sapwood treated with a micronised wood preservative, but they are absent from tracheid walls. Hence, we hypothesized that small nanoparticles can penetrate the walls of unlignified parenchyma cells, but are excluded from lignified tracheid walls. This paper tests this hypothesis by treating pine sapwood with an aqueou...
H Matsunaga, Y Kataoka, M Kiguchi, P D Evans


Fire performance of the wood treated with retardant
2012 - IRG/WP 12-40591
To prepare the eco-friendly fire retardant wood, Japanese red pine (Pinus Densiflora), hemlock (Tsuga Heterophylla), and radiate pine (Pinus Radiata) were treated with inorganic chemicals, such as sodium silicate, ammonium phosphate, and ammonium boric acid. Different combination and concentration of those chemicals were injected by pressure treatment methods. The electron-beam treatment was used ...
Jong In Kim, Mi-ran kang, Sang bum Park, Dong won Son


Preliminary evaluation of degradation patterns in wood samples from the Yenikapı shipwrecks
2013 - IRG/WP 13-10798
The uncovering of several shipwrecks during the excavation of the Marmaray Rail Tube Tunnel Project in Istanbul provides an important opportunity to evaluate waterlogged woods buried for centuries. Identification of these woods showed that a variety of species was used in the ships. One shipwreck (a galley) from the Yenikapı Marmaray was examined using electron microscopy. The micrographs rev...
C Köse, A M Taylor


Moisture distribution in glulam beams with natural cracks observed with CT Scanning before and after rain
2013 - IRG/WP 13-20534
The way cracks in outdoor wooden constructions affect durability is an interesting topic, since a certain amount of cracks can always be found naturally in wood and glued laminated wood. The question in this was, can cracks lead water into the wood and thereby increase the risk for decay and reduce strength and service life. Moisture balance, i.e., water absorption and water distribution were stud...
K Sandberg


CT scanning of decay in creosoted poles for overhead lines
2013 - IRG/WP 13-30634
Creosote-treated poles have been examined by means of CT scanning in order to investigate the nature of soft spots that have been found more frequently during the last five years in Sweden. CT scanning provides a very good picture of the interior of the poles and decay can easily be detected. It was concluded that the soft spots in most cases were caused by decay which in turn had to do with extre...
C-J Johansson, A Clang, I Johansson, G Berggren


Curing kinetics of nano cupric oxide (CuO) modified PF resin as wood adhesive: Effect of surfactant
2013 - IRG/WP 13-40620
The effect of nano cupric oxide (CuO) in combination with surfactants on the curing kinetics of phenol formaldehyde (PF) resin, as well as the bonding strength of plywood prepared using the modified resin were investigated in this study using dynamic and isothermal differential scanning calorimetry (DSC). The result showed that the incorporation of nano CuO along with alkane surfactant made in the...
Wei Gao, Guanben Du


Effect of electron beam irradiation on the fire retardant penetration into wood
2013 - IRG/WP 13-40642
Electron beam processing which can fast and easy change the nature of the material has received considerable attention recently. Studies using electron beam has been conducted in various fields and it has been applied in many industrial sectors. Electron beam has higher energy than other electromagnetic waves. It has excellent object permeability. It affects degradation of intermolecular cross-lin...
Dong won Son, Jong Sin Lee, Mee Ran Kang, Sang Bum Park


Scanning Transmission X-ray Microscopy as a tool for examining chemical changes in wood cell walls due to enzymatic activity
2014 - IRG/WP 14-20556
As development of techniques for examining enzymatic activity on solid, complex biological materials, is considered to be an important factor in further development of enzyme applications and for understanding the decay of plant materials, this study explores applicability of Scanning Transmission X-ray Microscope (STXM) for determining chemical changes in enzymatically treated samples at the cell...
D Jeremic, R Goacher, R Yan, C Karunakaran, E R Master


Non-destructive monitoring of structure and moisture dynamics of plywood exposed outdoors to improve service life prediction and fit-for-purpose design
2015 - IRG/WP 15-20570
Plywood is an important construction material yet prone to water uptake, which can decrease strength and increase decay risk. To predict service life and improve fit-for-purpose design, it is crucial to understand the moisture behavior and structural changes of plywood. In this research, several plywood specimens were exposed outdoors for approximately one year. During this period, the moisture di...
W Li, J Van den Bulcke, I De Windt, M Dierick, J Van Acker


Development of a new characterization method to analyse Cypermethrin penetration in wood material by immunolabelling
2015 - IRG/WP 15-30674
The preservative efficacy of organic biocides is strongly related to their capacity of penetration and retention within wood tissues. The specific detection of the pyrethroid insecticide cypermethrin is currently obtained after extraction followed by chemical analysis by chromatography techniques. However visualizing the insecticide molecule within the wood structure requires specific probes toget...
S Tapin-Lingua, K Ruel, J-P Joseleau, D Messaoudi, O Fahy, M Jequel, M Petit-Conil


Terrestrial laser scanning (TLS) – a potential tool for improved utilisation of the natural durability of Scots pine for solid wood products
2019 - IRG/WP 19-50358
The natural durability of sapwood of most species is generally low, while heartwood can be more resistant to biodeterioration. For the sawmill industry various lumber products require certain diameters and lengths of the logs in addition to requirements for wood properties. When utilising the heartwood, it is therefore important to acquire information already in the forest about which trees that c...
P-O Flaete


Evaluation of chemical densification of three hardwood species through in-situ electron beam polymerization
2020 - IRG/WP 20-40893
Hardwoods are the most suitable species for wood flooring for their appearance as well as their hardness. Yet, improving hardness can provide substantial benefit for the wood flooring market. Chemical densification of wood and in-situ polymerization through electron beam technology was chosen to increase hardness of three hardwoods (Yellow birch (YB) (Betula alleghaniensis Britt.), Sugar maple (SM...
J Triquet, P Blanchet, V Landry


Surface chemical wood densification through in situ electron beam polymerization: description and dose study
2022 - IRG/WP 22-40933
Traditional wood chemical densification processes can be used to improve wood mechanical properties by increasing density of the material throughout its thickness. While mechanical surface densification has heavily been investigated, surface treatments involving impregnation of monomers remain unexplored. This study describes a new material, surface densified through lateral impregnation of acryla...
J Triquet, P Blanchet, V Landry


Assessment of historical pilings from Lisbon
2024 - IRG/WP 24-41004
The renovation and rebuilding of areas in Lisbon has led to work on buildings constructed in the Pombaline downtown district. These buildings were constructed on wooden pilings, as a means of stabilising unstable soils and transfer the loads from buildings to soils with adequate bearing capacity. These methods also increased the resilience of the reconstruction works to future possible earthquakes...
D Jones, S Duarte, J A J Huber, L Nunes


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