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A practical method to evaluate the dimensional stability of wood and wood products
1990 - IRG/WP 2342
This paper presents a new simple method to evaluate wood and wood products for their resistance to swelling and to assess wood preservatives for their ability to dimensionally stabilize treated wood exposed to water. Permeable wood of various dimensions and treated with different preserving chemicals have been measured for swelling in the radial and tangential direction during immersion in liquid ...
J P Hösli


Long-term performance of a "wax" type additive for use with water-borne pressure preservative treatments
2000 - IRG/WP 00-40159
Field performance results are updated for matched CCA treated decking boards with and without an emulsion water repellent additive incorporated with the initial pressure treatment. Decks have been exposured for over 9 years in Harrisburg, NC. Boards were evaluated for in-service and laboratory performance for water repellent efficacy, as well as additive loadings in the boards after this exposure....
A R Zahora


Dimensional stabilization of wood with dimethylol compounds
1987 - IRG/WP 3412
This study showed that a substantial degree of dimensional stability can be imparted to wood by crosslinking with low concentrations of dimethyloldihydroxyethyleneurea. It was demonstrated that by selecting the right catalyst system the cure temperature can be reduced to the point that strength loss of the treated wood is minimized....
D D Nicholas, A D Williams


Combined effects of the treatment of wood with formaldehyde
1978 - IRG/WP 3117
Treatment of fibrous materials with reagents in a vapor phase is neither new nor unique. Numerous examples exist in literature of vapor phase experiments on cellulose fibers and fabrics, and on wood. For many years the textile research and industry have used vapor phase processes for the treatment of textiles. The chemical modification of cellulose is based on different types of reactions e.g. est...
M Stevens, J Schalck


Treatment of wood with formaldehyde. Acid catalysis of the reaction between formaldehyde and wood
1980 - IRG/WP 3146
Formaldehyde reacts with the free OH-groups in wood forming cross-linking bonds. The reaction can be brought about without any catalyst but in that case the activation energy is very high and high temperatures and long reaction times are needed. Normally, the reaction is catalysed by different acids. Acid catalysts, however, tend to degrade the cellulose and the wood matrix causing reduction in th...
T Vihavainen, K Piispanen, P Mansikkamäki


Improvements of stability and durability of beechwood (Fagus sylvatica) by means of treatment with acetic anhydride
1991 - IRG/WP 3645
In the present investigations, beechwood (Fagus sylvatica) was treated with non-catalysed acetic anhydrid at 120°C and some physical- and biological parameters of the treated wood were compared with those of non-treated wood. The radial and tangential shrinkage and swelling, respectively, and the absorption capacity of the acetylated wood against moisture is considerably lower. The durability aga...
H Militz


Adsorption of ACQ and CuMEA Wood Preservatives in Red pine
2005 - IRG/WP 05-30374
The rates of stabilization or fixation of ACQ subcomponents (CuO, DDAC and MEA) in red pine (Pinus resinosa) were compared for different solution concentrations (0.75%, 1.5%, 2.25% and 3% ACQ-D) and post treatment conditioning temperatures. Preservative solutions were impregnated into red pine sapwood by a full-cell treatment. Copper and MEA adsorptions from copper monoethanolamine solutions witho...
C Tascioglu, P A Cooper, Y T Ung


The effects of chemical modification on the physical properties of alder and spruce particleboards
2005 - IRG/WP 05-40300
In this paper, it was aimed to improve some physical properties of chemically modified particleboard, made from spruce and alder species, spreading widely at Black sea region in Turkey. Spruce and alder chips were reacted with acetic, succinic, maleic and phthalic anhydrides at constantly heat for 3 hours then, hot pressed at 150 °C by using Phenol formaldehyde (PF) resin. Target board density wa...
E Dizman, Ü C Yildiz, H Kalaycioglu, S Yildiz, A Temiz, E D Gezer


Comparative field performance of CCA and CCA-water repellent treated Southern pine lumber
1995 - IRG/WP 95-30089
This paper describes the field performance of end-matched southern pine boards treated with either CCA type C or CCA type C containing an emulsion water repellent (WR) additive. Boards were either kiln or air-dried after treatment, constructed into decks, and exposed for over 3 years at Harrisburg, NC. During this exposure, matched boards were monitored for internal moisture content, cupping at mi...
A R Zahora


Dimensional stabilization and decay resistance of wood treated with brown-rotted lignin and copper sulfate
1990 - IRG/WP 3608
The objective of this study was to evaluate the potential usefulness of brown-rotted lignin (BRL) as a dimensional stabilization and copper complexing agent for wood treatment. For dimensional stabilization, aqueous solutions of the lignin extract were combined with either copper sulfate, glyoxal or other additives. Anti-shrink efficiency (ASE) values as high as 42% were obtained with wood treated...
L Jin, D D Nicholas, T Schultz


Effect of species, retention and conditioning temperature on copper stabilization and leaching for ACQ-D
2004 - IRG/WP 04-30342
The time to stabilization or equalization of the copper component of ACQ-D was highly dependent on treating solution concentration (preservative retention) and post treatment temperature. Stabilization was rapid for low preservative retentions but extended times were needed for wood treated with higher concentration solutions. The extent of stabilization was also concentration dependent with a h...
Y T Ung, P A Cooper


Restrictions on the use of chlorosilanes as potential wood preservatives
1985 - IRG/WP 3345
The biological protection of wood by chemical modification with different types of chlorosilanes has been investigated. The impregnation of wood has been carried out by means of liquid phase and vapor phase treatments using pure silane and silane-solvent systems. The biological efficacy against wood rotting fungi, molds and staining fungi was determined in a number of screening trials, subsequentl...
M Stevens


Impregnation of timber with tannin as a mean of improving its dimensional stability
1992 - IRG/WP 92-3695
The results of a joint project carried out at the Timber Division of LNEC under the 2nd research programme of the CEC DGXII - "Wood as a renewable raw material" entitled "Stabilization of wood by impregnation processes" is presented. Pieces Maritime pine timber was impregnated with tannin under pressure to see if the treatment with tannin improved the behavior of wood regarding its dimensional sta...
J S Machado


Wood preservation by a mixed anhydride treatment: Using simple models of polymeric wood compounds
2008 - IRG/WP 08-30457
Treatment of wood by a mixed aceto/oleic (or other fatty acid residue) anhydride promoted as a safe and environment friendly wood preservation system has been examined quantitatively by liquid phase 13C NMR and solid phase MAS-DEC (proton decoupling) 13C NMR through all its different stages to determine which reactions occur with simple model compounds of the polymeric constituents of wood. The p...
F Lyon, M-F Thevenon, A Pizzi, G Tondi, A Despres, J Gril, S Rigolet


Stabilization of IPBC in wood through the use of organosilicon compounds
2012 - IRG/WP 12-30597
The aim of the research was to increase durability of wood treated with 3-Iodo-2-propynyl butylcarbamate (IPBC). The study used a blend of silanes. Biological examination against microfungi was performed to determine resistance of Scots pine wood treated with the tested formulations. Chemical analysis by the Electrospray Ionization Mass Spectrometry (ESI-MS) of water extracts from the leaching per...
B Mazela, W Perdoch


Wood treatment with organosilanes – perspective for IPBC stabilization
2014 - IRG/WP 14-30641
The aim of the research was a new model preservative’s antifungal properties evaluation. The formulation contained 3-Iodo-2-propynyl butylcarbamate (IPBC) at the reduced concentration. The IPBC was combined with organosilicon compounds (i.e. alkilosilicones with amino groups or fluorine) for supporting its antifungal properties. Due to the fact, that IPBC can be easily destabilized under the in...
W Perdoch, B Mazela, A Waśkiewicz


Improvement of wood properties by impregnation with liquefied spruce bark based resins
2016 - IRG/WP 16-40761
In this paper, biobased phenolic thermosetting resins are designed to be used as wood stabilization treatment. The originality of the study stands in substituting part of phenol by spruce (picea abies) bark: this is achieved by a liquefaction process in phenol in the presence of sulfuric acid as catalyst. Next, thermosetting resins are synthetized from liquefied bark by condensation on formaldehy...
X Duret, E Fredon, E Masson, P Gérardin


Hydrolytic stabilization of chemically modified Bambusa vulgaris Shrad ex JC Wendl
2018 - IRG/WP 18-40830
The main drawback which greatly limit the utilisation of bamboos is their high moisture intake, biodegradation and physical properties changes with environmental variations. To prevent excessive dimensional changes and improve moisture properties of bamboo, Bambusa vulgaris was chemically treated with acetic-anhydride without co-solvent. To evaluate the influence of acetylation on the moisture pro...
N A Sadiku, S M Akintayo


A Synergistically Stabilized Oil-in-Water Paraffin Pickering Emulsion Used in Wood Treatment
2018 - IRG/WP 18-40840
Pickering emulsions (emulsions stabilized by solid particles) are attractive as they have strong similarities with traditional surfactant-stabilized emulsions. In this study, an oil-in-water (O/W) paraffin Pickering emulsion system with satisfying stability and small droplet size distribution was developed by hydrophilic silica particles and traditional surfactants as mixed emulsifiers. The drople...
J Jiang, J Cao