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Long-term performance of DMDHEU-treated wood exposed in ground, above ground and in the marine environment
2018 - IRG/WP 18-40825
Chemical wood modification with N-methylol compounds such as 1.3-dimethylol-4.5-dihydroxyethyleneurea (DMDHEU) has been studied intensively since the 1990s. Research of the past years focused on treatment of Scots pine (Pinus sylvestris L.) and European beech wood (Fagus sylvatica L.) and was shown to be applicable to improve specific material properties. A high resistance against wood-destroying ...
L Emmerich, H Militz, C Brischke


Hydrolytic stabilization of chemically modified Bambusa vulgaris Shrad ex JC Wendl
2018 - IRG/WP 18-40830
The main drawback which greatly limit the utilisation of bamboos is their high moisture intake, biodegradation and physical properties changes with environmental variations. To prevent excessive dimensional changes and improve moisture properties of bamboo, Bambusa vulgaris was chemically treated with acetic-anhydride without co-solvent. To evaluate the influence of acetylation on the moisture pro...
N A Sadiku, S M Akintayo


Chemical defense of trees and wood natural durability: from protection to valorization
2019 - IRG/WP 19-10943
Natural durability of wood is defined as “the inherent resistance of wood against various wood-destroying organisms” (European standard EN 350-1). This property is due in particular to heartwood extractives. However, the wood natural durability is included in a wider defense system, and other organs such as bark and roots also host protective compounds. Studying the mechanisms on which global ...
E Houel, D Stien, N Amusant


Determining the natural durability on xylarium samples: mini-block test, wood powder and chemical profiling
2019 - IRG/WP 19-10944
Xylaria, or wood collections, can be considered sleeping beauties in terms of wood technological and biological output. In this study we focus on determining the natural durability of xylarium specimens from the Federal Xylarium in the Royal Museum for Central Africa. The Federal Xylarium contains over 80,000 specimens, covering more than 13,000 species, mainly from Central Africa. These specimens...
V Deklerck, L De Ligne, J Van den Bulcke, E Espinoza, H Beeckman, J Van Acker


Coula edulis baill an unknown wood species as an alternative to the main durable wood species used in Gabon
2019 - IRG/WP 19-10945
The Congo Basin hosts an exceptional biodiversity of trees, flora and fauna. However, the immense natural heritage of the forests in this area is increasingly threatened by many anthropogenic factors, due to selective exploitation of certain wood species. In Gabon, whose ecosystem is representative of this area, the forest represents nearly 80% of the national territory. Only a minority of wood sp...
C S A Bopenga Bopenga, S Dumarçay, P Edou Engonga, P Gerardin


Chemical composition, antitermite and antifungal activity of Dacryodes edulis oleoresin
2019 - IRG/WP 19-20653
Damages to wood structures and other cellulosic materials caused by wood destroying insects and fungi are estimated to several billions of dollars each year in the world. Among these, termites are considered as one of the most economically important pests for wooden structures. In the past, several wood protection chemicals like CCA, creosote, lindane or pentachlorophenol have been used. However, ...
W F Bedounguindzi, K Candelier, P E Engonga, Se Dumarcay, M-F Thevenon, P Gerardin


Chemical Analysis of Southern Pine Pole Stubs Sixty Months Following Treatment with a Methylisothiocyanate-Based Solid Fumigant Stick
2019 - IRG/WP 19-30740
Methylisothiocyanate-based fumigants have been commercially used in the United States for over 35 years to control internal decay in utility poles and other wooden structures with little technological advancement. The most recently commercialized methylisothiocyanate-based fumigant is chemically known as dazomet. Dazomet is a free-flowing powder or granule that decomposes in the presence of mois...
D J Herdman, T Pope, R R Browning


The use of bicine and tricine as possible Maillard reagents in a combined thermal/chemical modification of beech
2019 - IRG/WP 19-40852
The effects of thermal modification have been well established, particularly in terms of reductions in mechanical performance. In recent years, there has been an increase in studies related to the Maillard reaction. More commonly associated with food chemistry, it involves the reaction of amines and reducing sugars during cooking procedures. This paper has attempted to combine the use of amines an...
D Jones, C-M Popescu, D Krzisnik, M Hocevar, M Humar, M-C Popescu


Development of beech wood thermo-chemical modification treatments based on different vinylic derivatives of glycerol and polyglycerol
2019 - IRG/WP 19-40855
In this study, a combination between chemical and thermal wood modification has been investigated. Seven types of a low concentration of 10% aqueous additive solution of vinylicglycerol [glycerol-maleic anhydride (Gly-MA), glycidyl methacrylate (GM), and Glycerol methacrylate-maleic anhydride (GM/MA(2eq))], vinylicpolyglycerol [polyglycerol-maleic anhydride (PG-MA), polyglycerol methacrylate (PGM...
M Mubarok, S Dumarcay, H Militz, K Candelier, M-F Thevenon, P Gerardin


Study on the ability of wood-destroying fungi to grow through chemically modified wood
2019 - IRG/WP 19-40858
Over the last decades, chemical wood modification technologies were developed to increase the resistance against attack by wood-destroying organisms without using biocides. Most of those technologies are based on an impregnation step initially. In most treated wood products, mainly by using solid wood in thicker dimensions as in posts, poles, sleepers, deckings etc. it is known that wood impregnat...
L Emmerich, S Strohbusch, C Brischke, S Bollmus, H Militz


The anti-weathering mechanism of extractives in thermally modified Scots pine
2019 - IRG/WP 19-40880
Results from the electron spin-resonance spectroscopy (ESR) analysis indicated that thermally modification of wood can inhibit the generation of phenoxyl radicals during UV irradiation and consequently lead to the increase of the color stability of wood. In order to clarify the evolution and role of extractives in thermally modified wood during the process of weathering, the compositions of aceton...
H Shen, J Cao


Alternative products enhancing dimensional stability comparing to conventional treated products in Japan
2019 - IRG/WP 19-40885
The Act on the Promotion of the Utilization of Wood in Public Buildings (2010) in Japan has made a new stream of the utilization field of timber from housing constructions to larger scale non-housing constructions. After the act, the performance of dimensional stability in preservative treated products becomes more important factor than before. Therefore, various technologies have been developed, ...
K Yamamoto, D Tezuka, Y Sugai, S Maeda, I Momohara


Evaluation of chemical densification of three hardwood species through in-situ electron beam polymerization
2020 - IRG/WP 20-40893
Hardwoods are the most suitable species for wood flooring for their appearance as well as their hardness. Yet, improving hardness can provide substantial benefit for the wood flooring market. Chemical densification of wood and in-situ polymerization through electron beam technology was chosen to increase hardness of three hardwoods (Yellow birch (YB) (Betula alleghaniensis Britt.), Sugar maple (SM...
J Triquet, P Blanchet, V Landry


Comprehensive protection of timber in seawater
2020 - IRG/WP 20-10970
The hazard of wood in seawater can be divided into two areas: Below the water level, shipworm (Teredo navalis) and gribble (Limnoria lignorum) can attack non-resistant or insufficiently protected wood; above the water level, there is a risk by wood-destroying fungi and, to a lesser extent, insects. In a national project funded by the Deutsche Bundesstiftung Umwelt (DBU, German Federal Environmenta...
E Melcher, J Müller, T Huckfeldt


The influence of chemical compounds on wood cell wall to surface cracks
2020 - IRG/WP 20-40908
Degradation due to cracking and dimensional changes caused by drying, have a significantly negative impact on the preservation and durability of wood. Therefore, the prevention of surface cracking, which tends to occur during the drying process, is vital. High temperature set drying is one of the most effective methods for preventing wood surface cracking. It begins with softening the wood at a hi...
R Suzuki, Y Mori, K Yoshihiro, K Yamashita, M Kiguchi


The iron reduction by chemical components of wood blocks decayed by wood rotting fungi
2021 - IRG/WP 21-10979
Brown-rot fungi, a group of wood rotting fungi, is well known to be one of major microorganisms that cause the deterioration of wooden buildings in Japan and have been considered to use chelator-mediated Fenton (CMF) reaction in concert with hydrolytic and redox enzymes for degradation of wood cell wall. CMF can be described as a non-enzymatic degradation system that utilizes hydroxyl radicals pro...
R R Kondo, Y Horikawa, K Ando, B Goodell, M Yoshida


Mechanical and biological durability properties against soft-rot and subterranean termite in the field (grave-yard test) of beech wood impregnated with different derivatives of glycerol or polyglycerol and maleic anhydride followed by thermal modification in an opened or in a closed system
2021 - IRG/WP 21-40917
This paper presents mechanical and biological durability properties in soil beg test (soft-rot test) and field test (grave-yard test) against subterranean termite of the wood modified with an aqueous vinylic derivative of glycerol/polyglycerol or maleic anhydride cured in an opened or in a closed system. Wood modification was performed through impregnation of European beech (Fagus sylvatica) with ...
M Mubarok, H Militz, S Dumarcay, I W Darmawan, Y S Hadi, P Gerardin


Chemical composition of agarwood of Aquilaria crassna Pierre ex. Lecomte induced by Basidiomycetes from French Guiana
2022 - IRG/WP 22-10988
Aquilaria trees subjected to stress induce the formation of a transformed wood named agarwood. The formation of agarwood is a plant defense mechanism that occur in complex interactions with environmental microorganisms. Agarwood chemical compounds are mainly chromones and oxygenated sesquiterpenes such as eudesmol, agarospirol, jinkoh-eremol and valerianol, which are valued in perfumery. Its deriv...
C Zaremski, M Ducousso, C Andary, G Michaloud, C Menut, A Zaremski, N Amusant


Antifungal and antitermite activities of acetonic extractives from Cedrus Atlantica heartwood
2022 - IRG/WP 22-10990
Cedrus atlantica is a woody species present in France, which in a context of climate change can be privileged in the next years. In addition, this woody species presents great ecological and socio-economic interest as it is mainly recognized for its durable timbers and its essential oil presenting some interesting chemical properties. Therefore, the studies of its heartwood formation and propertie...
R Dijoux, R Ducruet, E Kieny, D Aznar, C Cayzac, L Bidel, C J Allemand, K Candelier


Comparative study on the efficacy of biobased wood preservative over conventional wood preservatives against fungi and termites
2022 - IRG/WP 22-30761
The current focus of wood preservation research is on developing wood preservatives from natural and environmentally compatible compounds for industrial application. Liquefaction of wood is one of the promising approaches to utilize woody waste where the wood powder is converted into a chemically active liquid with the help of a liquefying agent like phenol, cresol, plant-based solvent as CNSL and...
A Kumar, A John, B N Hazarika


Environmentally Friendly Wood Modification based on Tannin-Furfuryl alcohol - Effect on stabilisation, mechanical properties and decay durability
2022 - IRG/WP 22-40929
Furfurylation is a well-known wood modification technology. This paper studied the effect of tannin addition on the wood furfurylation. Three kinds of dicarboxylic acids, adipic acid, succinic acid, and tartaric acid, as well as glyoxal as a comparing agent, were used to catalyse the polymerisation of furanic or tannin-furanic solutions during wood modification. Impregnation of furanic or tannin-f...
M Mubarok, E Azadeh, F O Akong, S Dumarçay, A Pizzi, C Charbonnier-Gérardin, P Gérardin


Surface chemical wood densification through in situ electron beam polymerization: description and dose study
2022 - IRG/WP 22-40933
Traditional wood chemical densification processes can be used to improve wood mechanical properties by increasing density of the material throughout its thickness. While mechanical surface densification has heavily been investigated, surface treatments involving impregnation of monomers remain unexplored. This study describes a new material, surface densified through lateral impregnation of acryla...
J Triquet, P Blanchet, V Landry


Chemical modification of cellulose nanofibrils for tailoring properties of composites
2022 - IRG/WP 22-40934
Due to its natural abundance, complete biodegradability and excellent properties, cellulose is one of the most promising materials for the production of bio composites, as well as one of the most promising fillers for biodegradable polymer composites. This is also true for nanocellulose. A large number of hydroxyl groups on the surface of fibers or fibrils enables a whole series of chemical reacti...
I Poljanšek, J Levanič, V Ž Bogataj, V Vek, P Oven


Novel bio-based tannin/furfurylic alcohol thermosets: application to wood preservation
2022 - IRG/WP 22-40959
This project is integrated within the overall context of sustainable development and targets the valorization the wood industry by-products such as polyphenolic extractives, and in particular tannins. The objective targets the use of the same polymer used for production of tannin-furanic foams, but here for wood preservation to avoid the utilization of biocides. The aims is to the design of copoly...
C Gérardin-Charbonnier, E Azadeh, A Pizzi, P Gerardin


Efficacy of a wide-spectrum plant bio-based anti-termite product - Laboratory trials
2023 - IRG/WP 23-11024
Compared to the number of timbers available, the list of wood species resistant to termites is rather limited and largely composed of tropical timbers. In addition, due to climate change and environmental degradation, together with global trade, a significant global expansion of termites is predicted along with the economic losses due to their activities. Therefore, there is a demand to find produ...
M-F Thévenon, F Chopinet, J Vuillemin, A Robert, S Lafay, D Messaoudi


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