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Microwave digestion of preserved wood for the determination of Cu, Cr, As, B and P in quality control
1991 - IRG/WP 2364
A microwave digestion method for the determination of copper, chromium, arsenic, boron and phosphorus in preserved woods is described. Samples were digested with nitric acid in pressure-relief type teflon PFA vessels by microwave heating in a commercial laboratory microwave oven. Fast, efficient and complete digestion was achieved within 29 min for 12 samples. The digestion time compared favourabl...
N Bernth, L B Sheard


Reduction of kiln brown stain in radiata pine lumber after log fumigation with methyl bromide
1997 - IRG/WP 97-30129
Methyl bromide fumigation of freshly felled radiata pine log sections effectively killed living cells in parenchyma to at least 75mm into sapwood. Lumber cut from logs (fumigated and control) stored 1 month outdoors (dry) showed slightly reduced brown stain when kiln dried at conventional temperatures. A more dramatic reduction and elimination of brown stain was noted in lumber cut from fumigated ...
E Schmidt, M E Hedley, D R Page, D Cross


Dutch national environmental policy strategy (NMP): Implications throughout the life cycle of treated timber and for the Dutch preservation industry
1993 - IRG/WP 93-50001-31
All overview of relevant environmental legislation and instruments for control is given for each stage of the life cycle of treated timber. Recent policy in the Netherlands has been focused around the "National Environmental Policy Strategy", in which a general policy with regard to reduction of pollution to the air, soil and water is described. The principle is one of an "Integrated Chain of Cont...
P Esser, D A Lewis, A J Pendlebury


Moderate temperature fixation of CCA-C
1989 - IRG/WP 3522
Several Canadian treating plants are using moderate temperature (40-60C°) fixation chambers to reduce drippage and leaching from fresh CCA treated wood. In this study, chromium reduction and surface leaching properties of CCA-C treated red pine (Pinus resinosa) pole sections were monitored during exposure to temperatures of 50-60C° and 90-100% RH conditions. Chromium-VI concentration in the abso...
P A Cooper, Y T Ung


Studies of the mechanism of chromated-copper preservative. Fixation using electron spin resonance
1992 - IRG/WP 92-3701
Two softwoods and one hardwood species were treated with chromium trioxide, copper sulphate, chromated-copper wood preservative (CCA). The treated wood samples were analyzed during fixation by electron spin resonance (ESR). ESR spectra indicated that more than one Cr(V) species was generated from Cr(VI) soon after CCA treatment. The Cr(V) signal became strong within increased several hours followe...
K Yamamoto, J N R Ruddick


Strategies of risk reduction in sensitive environments - Case studies
2001 - IRG/WP 01-50166-11
The application of risk assessment procedures is based on widely agreed criteria and, whenever necessary, default values. The assessment itself aims to cover a wide extent of situations through "reasonable worst case scenarios". The result, based on the ratio of predictive to no-effect concentrations "PEC/PNEC", is usually performed into various regulations on a pass/fail basis, practically by ban...
G Ozanne


Fouling organisms as indicators of the environmental impact of marine preservative-treated wood
1995 - IRG/WP 95-50063
This study evaluates the use of fouling organisms (epibiota) to assess the environmental impact of preservative treated wood. This paper presents initial findings from treated panels exposed for 6 months at Sagres, Algarve, Portugal. Panels were treated with CCA, two copper-containing quaternary ammonium (ACQ) formulations and creosote, with nominal retentions from 10 to 40 kg/m³ (creosote 25 pcf...
R M Albuquerque, S M Cragg


Basilit CCFZ. Further studies on ecotoxicological behaviour
1992 - IRG/WP 92-3722
Basilit CCFZ is a new developed water based preservative for the protection of timber in hazard class 4 and 5 (ground-, fresh- and salt-water contact). The active components of this salt are copper, chromium, zinc and fluorine. In addition to primarily studies on the acute toxicity against organisms of the aquatic food chain a long term ecotoxicological study was performed. In a prolonged toxicity...
H W Wegen


Fouling assemblage development on copper-chromium-arsenic-treated timber submerged in European waters
2002 - IRG/WP 02-50181
The effect of the anti-marine-borer timber preservative CCA on community development of non-target marine fouling animals was investigated. Panels of Scots pine treated to target retentions of 12, 24 and 48 kg CCA per m3 of wood, plus untreated controls were submerged at seven coastal sites (Portsmouth, UK; La Tremblade (2 sites), France; Ria Formosa, Portugal; Sagres, Portugal; Kristineberg, Swed...
C Brown, R J Eaton, S M Cragg, P Goulletquer, A Nicolaidou, M J Bebianno, J Icely, G F Daniel, T Nilsson, A J Pitman, G Sawyer


Recovery of copper, chromium, and arsenic compounds from the waste preservative-treated wood
1991 - IRG/WP 3651
In Japan, about 40 percents of waste wood is incinerated and the residue is dumped into the landfill site. The waste preservative-treated wood, which is mixed in nontreated wood, is incinerated in the same way, too. However, it will cause the serious problems that the gases contained with high concentration arsenic compounds are discharged from the smokestacks of the incineration facilities and th...
A Honda, Y Kanjo, A Kimoto, K Koshii, S Kashiwazaki


Effect of compression wood on leaching of chromium, copper, and arsenic from CCA-C treated red pine (Pinus resinosa Ait.)
2000 - IRG/WP 00-30232
In this study, the effect of compression wood formation on the release rate of chromium, copper, and arsenic elements from red pine (Pinus resinosa Ait) was investigated. Wood blocks from red pine containing compression and normal wood portions were treated with a 1.0% CCA-C solution and were then allowed to fix at 23 ± ??2°C (74 ± 4°F) for 0, 6, 24, 48, 96, 192, and 336 hours. After each fixa...
S N Kartal, S T Lebow


Industrial fixation of chromium based wood preservatives
1990 - IRG/WP 3630
Fixation is an abstract and non-defined process. Nevertheless it is a specified requirement in most impregnation standards. The impregnation industry is facing increased pressure to deliver fixed products and to increase the safety of the handling of impregnated products. Industrial fixation of impregnated wood can be obtained by using different methods. The purpose of the process is to transform ...
T Christensen


The content and mobility of copper, chromium and arsenic in the soil of a wood preserving plant using CCA
1998 - IRG/WP 98-50122
Analyses were carried out on soil and water samples obtained from a wood preserving plant using CCA-type preservatives. The plant has been in operation since 1969. The soil samples were obtained on 8 points from 4 different depths. The estimation of the type of soil was followed by investigations of copper, chromium and arsenic contents, and the mobility of these elements. The soil samples were al...
N Erdin, S N Kartal, A Dilek Dogu, M O Engür


Assessment of the effects of rentex remedial treatment on some wood pole inhabitant micro-organisms
1994 - IRG/WP 94-30053
The effects of a remedial ground-line treatment using Rentex, a stabilised paste containing a mixture of fluoride and dichromate salts, on the micro-organisms inhabiting a sample of some 160 creosoted, on-line, electricity distribution poles, have been investigated as part of an appraisal of the efficacy of this remedial treatment. Half of the poles were treated and the other half used as controls...
D C R Sinclair, G M Smith, A Bruce, H J Staines


Leaching of copper-chrome-arsenic treated timber: Simulated rainfall testing
1996 - IRG/WP 96-50074
Six kiln dried radiata pine sapwood packs of timber were preservative treated with copper-chrome-arsenic preservative using a modified Bethell treatment schedule. The packs were then subjected to simulated rain leaching at specified periods after treatment. Higher chromium leachate was obtained when higher volumes of simulated rainfall were applied. Lower chromium leachate was obtained for timber ...
S Walley, P R S Cobham, P Vinden


A quantitative weathering study of wood surfaces modified by chromium VI and iron III compounds
1989 - IRG/WP 2330
Thin veneers of Pinus radiata were treated with dilute aqueous solutions of chromium VI and iron III compounds and exposed to natural weathering for 35 days. Zero-span tensile strength and weight losses of treated veneers were compared with losses observed in untreated specimens In a study designed to demonstrate the applicability of strength and weight loss measurements to the rapid quantitative ...
P D Evans, K J Schmalzl


The effect of acid rain on CCA treated timber
1990 - IRG/WP 3579
The effect of acid precipitation on the leaching of copper, chromium and arsenic from timber treated with different CCA preservatives was studied in the presence of three types of soil under simulated field conditions. Pine sapwood, embedded in soil, was subjected to simulated rainfall at three different levels of acidity. The CCA preservative formulations tested were:- American Wood Preservers&am...
R J Murphy, D J Dickinson


Biodetioration and strength reductions in preservative treated aspen waferboard
1983 - IRG/WP 2195
Experimental aspen waferboards, bonded with liquid or powdered phenol formaldehyde resins and treated by various methods with a wide selection of preservatives, were tested for fungal resistance in accelerated laboratory trials. Mold growth on the surface as well as weight and strength losses due to the actions of decay fungi were determined. Testing of board strength after decay in high and moder...
E L Schmidt, H J Hall, R O Gertjejansen, R C De Groot


Recycling and disposal of timber treated with waterborne copper based preservatives
1993 - IRG/WP 93-50008
Recycling and disposal technologies are briefly reviewed. Details are given of chemical extraction techniques suitable for recovery of copper from timber treated with a new copper based preservative, and traditional chromium based products. Details of thermal decomposition tests according to the DIN 53436 protocol under flaming and non-flaming conditions are given. The decomposition products were ...
J A Cornfield, S Vollam, P Fardell


A study of the rate of fixation of various chromium-containing preservatives
1991 - IRG/WP 3653
Denmark, and Scandinavia in general, has perhaps the widest range of approved industrial wood preservative types in the world. As an aid in setting realistic fixation periods, work was undertaken to investigate the rate of fixation of chromium in CCA salt, CCA oxide, CCP, CCB, CC and CCF formulations at summer and winter temperatures. The rate of fixation measured in terms of the concentration of ...
L B Sheard


Inter-laboratory comparison of assessment methods for wood preservatives against subterranean termites: Determination of protection threshold limits for CCA
1999 - IRG/WP 99-10317
In 1996, several institutes conducted laboratory bioassays on the efficacy of unleached Pinus radiata specimens treated with copper-chromium-arsenic (CCA) and copper naphthenate (Cu Naph) at retentions of 0.5, 1.0, 2.0 and 4.0 kg/m3 (total salt for CCA; elemental copper for Cu Naph) against a range of species of subterranean termites (IRG/WP/96-10174). Each participant employed the standard test m...
J W Creffield, M Lenz


Investigation of copper fixation in timber by sodium nitrit
1992 - IRG/WP 92-3707
Solutions containing mixtures of water soluble copper salts and sodium nitrite have been shown to be capable of producing leach resistant copper treatments when impregnated into timber. A rapid leaching trial showed that copper fixation levels of 85-90% were possible which compared well with the fixation level obtained with conventional hexavelant chromium containing systems in the same test regim...
C Waldie, J A Cornfield


Effect of remediation on the release of copper, chromium, and arsenic from particleboard made from CCA treated wood
2001 - IRG/WP 01-50170
This study sought to determine the effect of remediation with oxalic acid (OA) extraction and Bacillus licheniformis fermentation on the release of copper, chromium, and arsenic from particleboard made from remediated wood particles and also investigates durability of the particleboard against white and brown- rot fungi. Particleboard samples were manufactured using untreated, CCA-treated, OA-extr...
S N Kartal, C A Clausen


Practical considerations of the Formosan subterranean termite in Louisiana: A 50-year-old problem
2000 - IRG/WP 00-10330
In an eleven-year censusing (1989 through 1999) in the French Quarter of New Orleans and surrounding areas, Coptotermes formosanus alate numbers were found to be increasing dramatically in all years but one. Moreover, in parks and neighborhoods in New Orleans and Lake Charles, LA, as well as in Sam Houston Jones State Park near Lake Charles surveyed in 1998, alarmingly high numbers of this exotic ...
G Henderson


Determination of toxicity data for preservatives against Basidiomycetes by measuring the reduction in compression strength of wood
1988 - IRG/WP 2297
Blocks of Pinus radiata D. Don were treated to 12 retention levels with CCA and NaPCP. These were exposed for 12 weeks in agar jars to the dry rot (brown rot) Serpula lacrymans (Schum. ex Fr.) S.F. Gray. After mass loss determination, the same blocks were tested for reduction in compression strength parallel to the grain. Using both these parameters, together with interpolated 6 week strength loss...
J Wazny, J D Thornton


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