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Environmental fate of copper-based wood preservatives in different soil substrates - Part 1: Screening of the metal adsorption potential
1998 - IRG/WP 98-50101-21 a
In treatment plants, spillage of wood preservatives onto soil may be of environmental concern. This potential soil contamination served as an objective for a screening study. Three different mineral soils, a mineral substrate and two horticultural substrates are examined for their sorptive potential of copper through mixing with wood preservative solutions. Depending on the soil/substrate charact...
G M F Van Eetvelde, J M Mwangi, F Tack, R Hartmann, M Stevens


The content and mobility of copper, chromium and arsenic in the soil of a wood preserving plant using CCA
1998 - IRG/WP 98-50122
Analyses were carried out on soil and water samples obtained from a wood preserving plant using CCA-type preservatives. The plant has been in operation since 1969. The soil samples were obtained on 8 points from 4 different depths. The estimation of the type of soil was followed by investigations of copper, chromium and arsenic contents, and the mobility of these elements. The soil samples were al...
N Erdin, S N Kartal, A Dilek Dogu, M O Engür


Occupational exposure risk assessment at a commercial treatment plant using copper azole preservative
1998 - IRG/WP 98-50101-15
Experience with traditional water-based preservatives such as chromated copper arsenate (CCA) applied in closed system vacuum pressure impregnation plants has shown that operator atmospheric exposure is low during normal operation. TANALITH E is a commercially available copper azole wood preservative introduced as a chrome and arsenic-free alternative to CCA based on the actives copper, tebuconaz...
A S Hughes, M Connell


Uptake of copper by mycelium of wood decay fungi growing on copper S-substituted thioglycolate containing nutrient media
1998 - IRG/WP 98-10291
Mycelia of Trametes versicolor, Coniophora puteana and Poria monticola were grown on potato dextrose agar (PDA) media, containing various concentrations of copper N,N-dimethyldithiocarbamoylacetate (which may be regarded as a copper S-substituted thioglycolate). The tested copper compound revealed relatively low fungicidal activity. After 13-18 day growing period, we determined concentrations of a...
M Humar, M Petric, F Pohleven, P Kalan


Fungicidal activity of some organic solvents, copper carboxylates and their complexes with 2-aminoethanol
1997 - IRG/WP 97-30136
We evaluated the activity of eight organic solvents against wood - rotting fungus Trametes versicolor in order to choose the most appropriate one for rapid screening tests of some copper(II) carboxylates and their adducts with 2-aminoethanol. Their activity against the selected fungus was classified in the following order: chloroform > N,N-dimethylformamide > acetonitrile > methanol > ...
M Petric, F Pohleven


Termite resistance of pine wood treated with chromated copper arsenates
1997 - IRG/WP 97-30128
Two four-week, no-choice laboratory tests were performed with CCA-treated southern yellow pine and radiata pine against Formosan subterranean termites, Coptotermes formosanus. CCA retentions as low as 0.05 kg/m3 (0.03 pcf) provided protection from all but light termite attack (rating of 9 on a 10-point visual scale). Similar and consistent light attack on wafers containing retentions as high as 6....
J K Grace


The effect of steam conditioning on Southern yellow pine treated with copper naphthenate
1997 - IRG/WP 97-40086
The current study was undertaken to investigate the influence of steam conditioning on Southern yellow pine treated with copper naphthenate (Cu-N). Pre-steamed and /or kiln-dried Southern yellow pine were pressure treated with Cu-N. After treatment, one group of samples were post-steamed. It was found that samples changed color from green to dark-brown after post-steaming. To elucidate the effect ...
Jun Zhang, D P Kamdem, M H Freeman, R D Arsenault


Comparative performance of several ammoniacal copper preservative systems
1997 - IRG/WP 97-30151
The efficacy of several ammoniacal copper-based wood preservative systems was evaluated in this study. The selection of potential co-biocides was based on the results of an agar plate test. Following this, the most promising systems were evaluated in a standard field stake test. Good correlation was found between the agar plate and field stake test results. Of the preservative systems tested, copp...
D D Nicholas, T Schultz


A comparison of the leaching resistance of diammine-copper complexes and copper carbonate precipitated in wood
1997 - IRG/WP 97-30158
Previous studies have shown that during treatment of wood with ammoniacal copper solutions, both simple copper precipitates and diammine-copper complexes are formed. The objective of the present study is to determine the relative importance of both forms of copper, on such aspects as preservative leachability and biological performance. In the current experiment, the leachability of copper carbona...
Xiao Jiang, J N R Ruddick


Chromated copper arsenate preservative treatment of hardwoods. Part 2: leaching performance of seven North American hardwoods
1997 - IRG/WP 97-30132
Seven North American hardwood species were treated with 2% CCA-C solution and fixed at temperatures of 21°C and 50°C and conditions of high relative humidity (95%) as described in Part 1 of this presentation. Red pine (Pinus resinosa) was included as a softwood for comparison. Adequately fixed wood blocks (99.9% chromium fixation) were exposed to leaching tests according to AWPA E11-87 test. Par...
T Stevanovic-Janezic, P A Cooper, Y T Ung


Stake test with ammoniacal copper in combination with different agents started in 1962
1997 - IRG/WP 97-30130
In 1962 a stake test was started with ammoniacal copper in combination with chromium, arsenic, pentachlorophenol, boron, salicylic acid, benzoic acid, sorbic acid, pyridine and tannin. Different concentrations of the copper component were used as well as the added agents. For each concentration and test site, ten stakes of Pinus sylvestris L. sapwood were treated. The stakes were set out at two te...
B Häger, Ö Bergman


Amine copper reaction with wood components: acidity versus copper adsorption
1997 - IRG/WP 97-30161
The bonding sites for copper in wood from CCA, as well as ammoniacal/amine based systems, has long been a topic of investigation. Both phenolic and carboxylic functional groups have been discussed as potential bonding sites for copper. However, no consensus on the adsorption mechanism has been realized. Thus, the selective adsorption of copper in southern yellow pine from ethanolamine-copper solut...
S M Thomason, E A Pasek


Chromated copper arsenate preservative treatment of hardwoods. Part 1: CCA fixation performance of seven North american hardwoods
1997 - IRG/WP 97-30131
There has been an increased interest in utilisation of hardwoods from eastern North America for exterior applications which require protection with preservatives such as CCA. We have examined CCA fixation at two selected temperatures of seven common North American species: red maple (Acer rubrum L.,), white birch (Betula papyrifera ), yellow poplar (Liriodendron tulipifera L.), trembling aspen (Po...
T Stevanovic-Janezic, P A Cooper, Y T Ung


Preliminary study of the fungicidal and structural variability in copper naphthenates and naphthenic acids
1996 - IRG/WP 96-30114
Copper naphthenates, an oil-borne wood preservative listed by the American Wood-Preservers' Association (AWPA), is manufactured by complexing copper(II) with naphthenic acids. Prior to AWPA listing as a wood preservative, field experiments showed that copper naphthenates generally had good stability and were active against wood-destroying organisms. Recently, however, there have been reports ...
T Schultz, D D Nicholas, L L Ingram Jr, T H Fisher


Effectiveness and synergistic effects between copper and polymer betaine
1996 - IRG/WP 96-30097
Different formulations of "Copper Amine" and Polymer Betaine were studied. During laboratory tests a synergism between both active ingredients against soft rot and dry rot has been found. The efficacy against soft rot according to the "BAM method" and the European Standard ENV 807 depends only on the amount of copper. Long term tests in a fungus cellar for determining the relative protective effec...
H Härtner, V Barth


Treatability of Siberian larch and spruce with chromated copper arsenate
1996 - IRG/WP 96-40060
Heartwood of Siberian larch (Larix gmelini) and spruce (Picea jezoensis) was pressure treated with chromated copper arsenate (CCA) Type B using a full cell process. Larch heartwood was somewhat difficult to treat than the spruce, although both species did not meet a minimum requirements of penetration and retention specified by the American Wood Preservers' Association (AWPA) for difficul...
Gyu-Hyeok Kim, Woo-Gue Jee, Jae-Jin Kim


In-ground evaluation of a copper azole wood preservative (Tanalithâ E) at a tropical Australian test site
1996 - IRG/WP 96-30100
A field trial to determine the in-ground termite and decay resistance of Pinus radiata D. Don impregnated with a copper azole formulation, TANALITHâ E, has been established at a tropical site in the Northern Territory of Australia. Four retentions of TANALITHâ E, containing 1.54, 2.08, 2.92 and 4.30 kg/m³ of Cu, are being evaluated. For comparison, Pinus radiata specimens treated to two retenti...
J W Creffield, J A Drysdale, N Chew


Fixation of chromated copper arsenate (CCA) wood preservative in Australian hardwoods: A comparison of three Eucalyptus species
1996 - IRG/WP 96-30107
New environmental guidelines for the management of CCA treatment plants were released in Australia in 1995. This has stimulated interest in techniques for controlling or accelerating the fixation of CCA in freshly treated timber products. The ability to understand, then effectively control and/or accelerate fixation of CCA in treated timber products can be an economic, technical and environmental ...
J Holmes


Leaching and fixation characteristics of chrome-copper-fluoride-zinc (CCFZ) treated wood
1996 - IRG/WP 96-30096
The leaching characteristics of radiata pine sapwood blocks treated with CCFZ were evaluated by the AWPA standard leaching test. The rate of fixation of the preservative components in CCFZ treated radiata pine were also evaluated by quantitative analysis of solution expressed from the treated wood. Both leaching and fixation characteristics of CCFZ were compared with CCA-Type C treated wood sample...
Gyu-Hyeok Kim, Jong-Bum Ra


Fixation of copper-chrome-arsenic treated timber: A comparison of leaching methodologies
1996 - IRG/WP 96-50075
Five packs of kiln dried radiata pine heartwood were treated with copper-chrome-arsenic preservative treated, utilising a modified Bethell treatment schedule. Two methods of determining the level of preservative fixation were compared. These included the diphenylcarbazide method and simulated rainfall testing. The fixation levels were generally higher for tests involving simulated rain leaching. F...
S Walley, P R S Cobham, P Vinden


Accelerated termicidal performance data for new water-based copper linoleate formulations
1996 - IRG/WP 96-30104
An organic solvent based copper linoleate (Culin) has proved itself as an effective wood preservative in long term field trials in South Africa over a period of 30 years. Whilst the organic solvent based product offers good wood preservative performance, primary industrial interest has been in an emulsified version of the product. The objective of this study was to evaluate the influence of two di...
D Conradie, P Turner


Performance of copper-chrome formulations in ground contact in five test sites in New Zealand
1996 - IRG/WP 96-30113
Copper-chrome-arsenate (CCA), copper-chrome-boron (CCB), copper-chrome-fluoride (CCF) and copper-chrome-phosphate (CCP) have been tested at four retentions each in ground contact (25 x 50 x 500 mm³ radiata pine sapwood stakes) for 16 years in five test sites in New Zealand. Results to date show that test site characteristics have a marked effect on relative performance. In a warm and wet site (an...
M E Hedley, R N Wakeling, J Foster, B E Patterson


Leaching of copper-chrome-arsenic treated timber: Simulated rainfall testing
1996 - IRG/WP 96-50074
Six kiln dried radiata pine sapwood packs of timber were preservative treated with copper-chrome-arsenic preservative using a modified Bethell treatment schedule. The packs were then subjected to simulated rain leaching at specified periods after treatment. Higher chromium leachate was obtained when higher volumes of simulated rainfall were applied. Lower chromium leachate was obtained for timber ...
S Walley, P R S Cobham, P Vinden


Modelling of copper emission fron treated wood leached according to NEN 7345 and ENV 1250.2
1996 - IRG/WP 96-20097
A series of water leaching experiments is carried out investigating pine and spruce treated and fixed using different copper-containing preservative solutions and process technologies. Water changes took place as prescribed in the Dutch standard NEN 7345 and the European test method ENV 1250.2, each of the leachates being chemically analysed for their copper content. Irrespective of the preservati...
G M F Van Eetvelde, S G L Michon, M Stevens


Preservative leaching from copper-chrome-arsenic treated timber: Towards an international standard for environmental monitoring
1996 - IRG/WP 96-50076
A review of standards and legislative requirements around the world relating to environmental contamination from copper-chrome-arsenic wood preservative indicates a plethora of methodologies for expressing and determining contamination levels. The imposition of arbitrary quarantine periods for treated timber, or special fixation processes, appear to be applied without a rational analysis of what l...
S Walley, P R S Cobham, P Vinden


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