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Kinetics of the dissociation of Cr, Cu, and As in fixed CCA-treated wood
2001 - IRG/WP 01-50168
The results of an experiment showing the kinetics of the dissociation of CCA compo-nents in water within treated wood samples are presented. Dry red pine (Pinus resinosa Ait.) samples were simultaneously vacuum-treated with water, then expressed to re-move the water at successive time intervals. The expressate was then analyzed for Cr, Cu, and As concentration by inductively coupled plasma (ICP). ...
L Waldron, P A Cooper


Recycling and disposal of timber treated with waterborne copper based preservatives
1993 - IRG/WP 93-50008
Recycling and disposal technologies are briefly reviewed. Details are given of chemical extraction techniques suitable for recovery of copper from timber treated with a new copper based preservative, and traditional chromium based products. Details of thermal decomposition tests according to the DIN 53436 protocol under flaming and non-flaming conditions are given. The decomposition products were ...
J A Cornfield, S Vollam, P Fardell


Fungal decay of acrylate treated wood
2004 - IRG/WP 04-30357
Natural durability of wood species is variable. Chemical wood preservatives, such as biocides are necessary for extension of their service life. Many methods have been developed to increase the resistance of wood and wood products against wood-destroying organisms during the last years. The most frequently used methods are chemical and thermal modification of wood. In wood modification the basic c...
Z Tiralova, L Reinprecht


Inorganic preservative levels in soil under treated wood decks after 8 years natural exposure in Borås, Sweden
2005 - IRG/WP 05-50233
Inorganic preservative components (Cu, Cr and As) were measured to a depth of 150 mm under deck structures made with Scots pine lumber treated with several different wood preservatives and installed in Borås Sweden 8 years ago. Higher contaminant levels were observed mainly under the drip lines and in the top 50 mm of soil. Under CCA treated decks, soil arsenic concentrations increased from ba...
P A Cooper, Y T Ung, M-L Edlund, J Jermer


Modelling of copper emission fron treated wood leached according to NEN 7345 and ENV 1250.2
1996 - IRG/WP 96-20097
A series of water leaching experiments is carried out investigating pine and spruce treated and fixed using different copper-containing preservative solutions and process technologies. Water changes took place as prescribed in the Dutch standard NEN 7345 and the European test method ENV 1250.2, each of the leachates being chemically analysed for their copper content. Irrespective of the preservati...
G M F Van Eetvelde, S G L Michon, M Stevens


Control of wood biodeterioration by fungal metabolites
1992 - IRG/WP 92-1527
Treating wood with different conventional preservative chemicals for protection and economic utilisation is well known. Tough some of these chemicals are toxic to skin, their use as wood preservative is unavoidable as they should be toxic to biodeteriorating organisms also. Recent advances in chemistry of natural products enabled the use of wood extractives as biocidal compounds against biodeterio...
H S Ananthapadmanabha, H C Nagaveni, V V Srinivasan


Tropical In-Ground Durability of Structural Sarawak Hardwoods Impregnated to High Retention with CCA-salts, CCA-oxide and FCAP after 20 Years Exposure
2005 - IRG/WP 05-30384
Statistical analysis (ANOVA) was conducted on durability (termite and decay combined) rating data collected over 20 years exposure period of over 140 species of Sarawak timbers with altogether 30,000 stake specimens, at the Forest Department’s Sibu “graveyard” stake test sites from 1977. About 20 replicated stakes were pressure-treated to refusal with 10% g/ml concentration of up to 3 CCA-sa...
Wang Choon Ling, A H H Wong


Enhanced removal of CCA from treated wood by Bacillus licheniformis in continuous culture
1997 - IRG/WP 97-50083
A gram positive, spore-forming bacterium, which was isolated from a 20-year-old Forest Service test plot of CCA-treated 2 x 4's in Madison, WI., demonstrated the ability to release copper, chromium, and arsenic from CCA-treated wood in liquid culture. CCA-treated sawdust was exposed to this organism, which has been presumptively identified as Bacillus licheniformis. Analysis of the sawdus...
C A Clausen


Pollution in wood preservation - Aspects and problems
1973 - IRG/WP 55
In the field of wood preservation too, pollution problems have to be considered. They originate with the wood preservatives used. The extent of pollution differs widely with the type of preservative and the treatment process used. Per unit of impregnated timber, pollution will be lower if treatment is performed in treating plants than in distributed places. It will be highest for the old type Bouc...
H Willeitner


Isolation and identification of the fungal flora in treated wood. Revised technique
1977 - IRG/WP 159
At the 8th Annual Meeting in Wildhaus a paper was presented for discussion on the isolation of fungi from treated wood.·Since then work of this nature has been undertaken at Imperial College and as a result a revision of that document has been made and is presented here. The main alterations are: 1) To streamline the isolation procedure 2) Modification of the benomyl agar 3) The inclusion of a st...
C P Clubbe, J F Levy


Ten year performance of l-joints made from borate diffusion treated wood
2000 - IRG/WP 00-30225
While there are decades of experience with borate-treated wood in coated, exterior applications in New Zealand and the UK, other countries have been more reluctant to use this process. As part of a research program on the potential use of borates by the Canadian wood products industry, Forintek set up, in 1990, an L-joint test of untreated and borate-diffusion treated hem-fir (western hemlock and ...
P I Morris


Ecotox Testing of Leachates as an Alternative Approach for Environmental Impact Assessment of Wood Preservatives
2002 - IRG/WP 02-50185
Driven by the implementation of the EU Biocidal Product Directive (BPD) in the environmental assessment of treated wood different methodologies and test strategies are at present under discussion within industry, regulatory authorities and standardizing comittees. Test procedures for the analytical determination of emissions to different environmental compartments according to exposure scenario...
H-W Wegen


Comparison of laboratory tests and field experiments for the estimation of emissions from treated wood
2005 - IRG/WP 05-50224-6
The authorisation procedure for biocidal products according to the European Biocides Direc¬tive in¬cludes the assessment of possible environmental risks by the emission of ac¬tive ingre¬dients. This needs an input of data on the expected emissions of biocides into environmental com¬part¬ments. The procedures for the estimation of these emissions should be harmonised. La¬boratory test proce...
U Schoknecht


Gestion des déchets dans le groupe Rhône-Poulenc
1990 - IRG/WP 3583
La gestion rigoureuse de l'ensemble des déchets est une condition essentielle du développement des activités du groupe RHONE-POULENC. Les différentes activités, de la Chimie à la Santé en passant par l'Agro et les Fibres, génèrent des quantités importantes de sous-produits ou déchets. Afin de gérer avec rigueur l'ensemble de ces résidus, les différents site...
R P Furminieux


Harmonisation of technical requirements of treated wood in Europe. What can we learn from the experience in the Nordic countries?
1995 - IRG/WP 95-50040-20
In the Nordic countries the Nordic Wood Preservation Council (NWPC) has since 1972 harmonised the technical requirements for pressure treated timber in a Nordic standard. These requirements were used by the control schemes that exist in every country. In 1976 the first Nordic standard for pressure treated wood was accepted and in 1978 NWPC changed from recommendations to approvals for the preserva...
F G Evans


Exposure of preservative treated wood to terrestrial microcosms, pure cultures of fungi and in the field
1997 - IRG/WP 97-20114
Small stakes (5x10x100 mm3) of treated and untreated Pinus sylvestris sapwood were exposed in terrestrial microcosms with different soils, two taken from test fields in Sweden, one soil from a conifer forest and one garden compost soil. Stakes of the same size were also exposed to pure cultures of the brown and white rot fungi, Postia placenta and Phanerochaete chrysosporium. After exposure, weigh...
M-L Edlund


Treatment groups and remedies for CCA treated hardwood and softwood poles
1999 - IRG/WP 99-40142
Different hardwood and softwood species from Bangladesh and Bhutan was investigated regarding density, green fiber stress, natural durability of heartwood and CCA treated sapwood, CCA treatability grades, sapwood thickness, and kiln-drying properties for long term use as electric poles. These properties along with the past service records for nineteen years, separated ten heardwood and five softwo...
A K Lahiry


Biological resistance of furfuryl alcohol-treated wood
1992 - IRG/WP 92-3703
Biological resistance of FFA (furfuryl alcohol)-treated wood was investigated in relation to the rise of ASE (anti-swelling efficiency) resulting from the treatment. Sapwood blocks of Japanese red pine, cedar and beech were vacuum-impregnated with various concentrations of aqueous FFA solutions to get the target levels of% (w/w) RL (resin loading). Air-dried blocks were kept in an oven at 120°C f...
J Y Ryu, Y Imamura, M Takahashi


The examination of preservative-treated radiata pine using electron spin resonance spectroscopy
1987 - IRG/WP 3423
Electron spin resonance spectroscopy (ESR) may be used to characterise the molecular environment of chemical species containing unpaired electrons. These species include free radicals, bi-radicals, point defects in solids, localised crystal imperfections and many transition metal ions. ESR has previously been applied to the examination of wood weathering or wood pyrolysis and now FRI and Massey Un...
D V Plackett, E W Ainscough, A M Brodie


Screening of the technical performance and aquatic toxicity of N-methylolacrylamide treated wood
2000 - IRG/WP 00-40166
In the course of the last decades chemical modification of wood species, with a limited natural durability, has been subjected to intensive research. As a possible alternative and supplementary treatment of non-durable wood in a range of applications it remains one of the major topics in the wood preservation world. Different modification systems have been scaled-up and are now in an industrialisi...
V Rijckaert, S De Geyter, J Van Acker, M Stevens


Detoxification of salt impregnated wood by organic acids in a pulping process
1993 - IRG/WP 93-50012
The paper descibes a novel method to detoxify pine wood (Pinus silvestris L.) treated with CCB-, CCF- CC-, and Cu-HDO-type salt preservatives. In the process of biological detoxification organic acids produced by strains of Antrodia vaillantii and other brown rot fungi are used for the dissolution of the previously fixed inorganic compounds. These findings are the basis for applying an acid pulpin...
I Stephan, H H Nimz, R D Peek


Effect of remediation on the release of copper, chromium, and arsenic from particleboard made from CCA treated wood
2001 - IRG/WP 01-50170
This study sought to determine the effect of remediation with oxalic acid (OA) extraction and Bacillus licheniformis fermentation on the release of copper, chromium, and arsenic from particleboard made from remediated wood particles and also investigates durability of the particleboard against white and brown- rot fungi. Particleboard samples were manufactured using untreated, CCA-treated, OA-extr...
S N Kartal, C A Clausen


Comparative performance of copper azole and copper-chrome-arsenate treated rubber wood in Australian, Malaysian and New Zealand tests sites
2000 - IRG/WP 00-30213
Rubberwood (Hevea brasiliensis) has been used for non-structural products where appearance is important. It has rarely been used for structural uses where preservative treatment is required. In order to evaluate the in-ground durability of preservative-treated rubberwood, test stakes (20 x 20 x 500 mm3) were treated to four retentions of CCA and copper azole (Tanalith® E) and installed in test si...
J A Drysdale, M E Hedley, E Loh, L T Hong


Termite resistance of treated wood in an above-ground field test
1985 - IRG/WP 2241
A field test method has been developed for evaluating the susceptibility of wood products to termites in protected situations above ground. In this method fungal attack on the wood products is minimal, though decay has been observed in conjunction with termite attack in some specimens. Preliminary results from exposure of replicate wood samples treated with preservatives in Florida to Reticuliterm...
A F Preston, P A McKaig, P J Walcheski


FTIR studies on the weathering of didecyldimethylammonium compound (DDAC) treated wood
1993 - IRG/WP 93-30013
Wood treated with alkylammonium compounds (AACs), such as DDAC, weathered more rapidly than untreated wood. In order to examine the influence of DDAC treatment of wood on its weathering, treated and untreated microtomed sections of southern yellow pine earlywood of various thicknesses, were prepared and weathered for approximately one month. The changes in these samples were monitored using FTIR. ...
R Liu, J N R Ruddick


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