Your search resulted in 16 documents.
Fungal degradation of wood treated with metal-based preservatives. Part 2: Redox states of chromium
1996 - IRG/WP 96-10164
Concerns have arisen about the leaching of heavy metals from wood treated with metal-based preservatives, such as chromated copper arsenate (CCA). Of particular concern is the toxic redox state of chromium and arsenic in aging and decayed CCA-treated wood. Generally, hexavalent chromium is more toxic than trivalent chromium and trivalent arsenic is more toxic than pentavalent arsenic. The desired ...
B Illman, S Bajt, T L Highley
A study of salt imbalances observed in recycled copper/chrome/arsenic preservative solutions in commercial practice
1987 - IRG/WP 3461
The study reported monitored tank solutions, sludge and other by-products using a standard CCA solution, when recycled. This recycling of the CCA solution is quite usual in between any commercial treatment schedules. Salt imbalances were observed and the possible reasons for such phenomena were studied. The paper discusses the procedure followed, the method of sampling the liquid after the charge ...
V R Sonti, S Sonti, B Chatterjee
The variability of preservative distribution in test blocks
1973 - IRG/WP 220
The techniques for the assessment of likely effectiveness of preservative systems have long been the subject of much discussion. The whole field has recently been reviewed by Hilditch and Hamblyn (1971) who described in detail many of the laboratory test procedures used, but who also indicated the deficiencies in many of these techniques. It has long been the view of many associated with the wood ...
F W Brooks, M R Gayles, R W Watson
Photo-discoloration and Degradation of Wood and its Stabilisation by Modification with Benzoyl Chloride
2004 - IRG/WP 04-40274
Photo degradation of Pinus roxburghii (chir pine) and Hevea brasiliensis (rubber wood) was studied under artificial accelerated weathering conditions in a Xenon test chamber. The irradiated samples were analyzed for color changes and chemical changes. Analysis of colour changes in wood surfaces by UV-Vis. irradiation was carried out using a colour measuring (CIELAB) system and chemical changes ...
K K Pandey
Correlation between changes in colour and chemical composition during photo-degradation of wood surfaces
2005 - IRG/WP 05-40301
Changes in colour of wood (yellowing) during photo degradation or weathering reflect chemical changes in wood. Therefore, the relationship between changes in chemical composition and CIELAB colour parameters is very important to characterize photodegradation of lignocellulosic surfaces. In this study, the changes in chemical composition and yellowing due to photo-degradation was studied by expos...
K K Pandey
Laboratory evaluation of chlorothalonil against the Formosan subterannean termite
1992 - IRG/WP 92-1559
The fungicide chlorothalonil was evaluated as a wood preservative to prevent attack by the Formosan subterranean termite, Coptotermes formosanus Shiraki (Isoptera: Rhinotermitidae). Southern yellow pine wafers treated with chlorothalonil (CTL) in P9 oil, CTL + chlorpyrifos in P9 oil, or CTL in xylene were conditioned by evaporative aging at 40° C for 4 weeks and exposed to termite attack in a mod...
J K Grace, P E Laks, R T Yamamoto
Application of energy dispersive X-ray fluorescence spectrometry to the quantitative analysis of organotin preservative solutions and treated wood
1978 - IRG/WP 3125
One technique frequently used for the quantitative analysis of material containing inorganic compounds is energy dispersive X-ray fluorescence spectrometry. It has been shown previously that this technique can be readily used to determine the retentions of chromated copper arsenate and ammoniacal copper arsenate treated wood. This paper reports the results of a preliminary study to determine wheth...
J N R Ruddick
Basidiospore structure and germination of Serpula lacrymans and Coniophora puteana
1988 - IRG/WP 1340
Using a nuclear staining technique and fluorescence microscopy, the basidiospores of Serpula lacrymans were shown to be uninucleate whereas those of Coniophora puteana were binucleate. The germination rate of the Serpula lacrymans spores, which was considerably lower than that of Coniophora puteana, decreased further after storage or heat treatment. Transmission electron micrographs indicate that ...
B M Hegarty, U Schmitt
A comparison of analytical techniques
1995 - IRG/WP 95-20061
This paper compares carefully-controlled weight retentions and analysis by XRF, ICP, combustion methods and a new extraction procedure for the new preservative, Copper(II) Dimethyldithiocarbamate (CDDC). Various experimental parameters such as particle size and drying conditions were investigated. In general, the correlations between and among the procedures are very high. The extraction-colorimet...
A C Gallacher, C R McIntyre, M H Freeman, D K Stokes, W B Smith
The use of low cost X-ray fluorescence instruments in the determination of copper chromium and arsenic in preservative treated wood
1987 - IRG/WP 2278
Internal quality control in timber treatment plants can be pursued by analysis of preservative treatment solutions and treated timber. Treaters must proceed with costly and lengthy analyses through analytical laboratories. An alternative approach for the timber treater, is to use low cost analysers (L.C.A.'s) based upon x-ray fluorescence. Detailed comparisons have been made between stand...
J Norton, L E Leightley
Evaluation of rapid methods for detecting wood preservatives in waste wood
1994 - IRG/WP 94-50024
For the disposal of wood waste under ecological sound conditions information about its hazardous potential is required. Several analytical methods are available for the detection of most elements in wood preservatives. Industrial process conditions, however, demand methods with very short turn around times. In this research several methods of analysis were judged on their speed and accuracy. A num...
W J Homan, H Militz
Assaying Pentachlorophenol-treated Wood Using XRF
2007 - IRG/WP 07-20362
A study was conducted to evaluate the effect of oil type on the performance of test posts treated with oil-penta and exposed in DeQueen, AR for forty years in ground contact. The original assays for the poles were done by lime ignition, a practice used sparingly today in treating plants or by independent inspectors, in part due to the complicated analysis procedure and chances for error. XRF ins...
H M Barnes, C R McIntyre, D W Bullock , M H Freeman, G B Lindsey
Use of X-Ray Fluorescence (XRF) Spectroscopy to Determine 4,5-Dichloro-2-n-Octyl-4-Isothiazolin-3-one (DCOIT) in Wood
2007 - IRG/WP 07-20373
Organic preservative based systems are being developed as replacements for the metal based systems. Typically the chemical actives of organic preservative systems are analyzed using HPLC or GC. However, these analytical techniques require complex sample processing and involve relatively long analysis times. In addition the equipment requires maintenance and a skilled operator. One organic preser...
P Walcheski, J Ashmore, D M Laganella
Wood biodeterioration monitoring using molecular fluorescence
2016 - IRG/WP 16-20589
Wood is an extremely complex and heterogeneous biological material, susceptible to biodeterioration by wood-destroying organisms. This process can be evaluated by natural resistance tests or non-destructive techniques, such as molecular fluorescence. The fluorescence of wood can be attributed to the presence of fluorophores groups or extractives, as a characteristic of some species. This study aim...
E Meneses Oliveira, A Florian da Costa, J W Batista Brag
Preparation of Calibration Standards for the Analysis of Pentachlorophenol in Treated Wood by X-ray Fluorescence
2016 - IRG/WP 16-20591
The primary purpose of this project was to develop a method for preparing calibration standards that can be used by the wood treating industry to calibrate X-ray fluorescence instrumentation. Calibration standards of penta/P9-oil in southern yellow pine that cover the retention range of 0.2 to 0.9 pcf (0.6 to 1.9 %) were successfully prepared. A detailed procedure for mixing penta in treating sol...
L L Ingram Jr, H M Barnes, R Shmulsky, D Jeremic
Measurement of copper concentration in Cu-HDO treating solutions by handheld XRF
2022 - IRG/WP 22-20685
Copper based preservatives diluted in water dominate the wood preservative industry around the world. Periodically measurements and adjustments of the concentration of treating solutions must be performed as a part of the quality control at the treatment plant to achieve desired quality of the preservative treated wood. Many analytical methods are time consuming and must be performed under laborat...
P O Flaete