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Studies on the infestation behaviour of the powder-post beetle Lyctus brunneus (Steph.) and its physical control in the wood yards of the Caspian forests of Iran
1985 - IRG/WP 1271
Lyctus brunneus (Steph.) is a pest which has not been previously thoroughly studied in Iran. It severely attacks Iranian hardwoods, especially those used in wooden houses and that have not been treated. Research work was necessary to determine the natural resistance of the most important timber species in Iran against this insect....
P Niloufari


Health aspects concerning the use of bifluorides in wood
1981 - IRG/WP 3173
An attempt has been made to find a correlation between the quantities F¯ and HF present among other ions in an 'Improsol' solution consisting of NH4F.HF and KF.HF, the quantity absorbed by the wood from this after immersion and the toxicological effects of this treated wood when it is used in rooms destined for the residence of people or animals or for the storage of foodstuffs....
H F M Nijman


The influence of crystalline and amorphous cellulose on extracellular hydrogen peroxide production by brown-rot fungi
1991 - IRG/WP 1482
The production of hydrogen peroxide (H2O2) has been suggested to play a key role in the degradation of wood by wood-rotting fungi. The production of extracellular hydrogen peroxide was studied by a quantitative method which detects the oxidation of the 2,2-azinobis(3-ethylbenzthiazoline-6-sulphonic acid) (ABTS) by H2O2 and horseradish peroxidase (HRP) in liquid culture medium. The carbon sources u...
A-C Ritschkoff, L Viikari


Cytochemical localization of hydrogen peroxide in brown rot fungus Tyromyces palustris by cerium chloride technique
1999 - IRG/WP 99-10299
Cerium chloride (CeCl3) was used to localize H2O2 cytochemically for studying relationship between ultrastructural and functional characteristics of cellulose degradation by brown rot fungi. This technique proved very useful in localizing discrete electron-densereactionproducts at high resolution with minimal nonspecific deposition. The cytochemical localization of extracellular H2O2 by CeCl3 usin...
Yoon Soo Kim, Seung-Gon Wi


Effect of fatty acid removal on treatability of Douglas-fir
1993 - IRG/WP 93-40008
Treatment of Douglas-fir with chromated-copper-arsenate (CCA) poses a major challenge. Several hypotheses based on the anatomical aspects as well as chemical reactivity of the preservative formulations with cell wall constituents and deposits have been proposed. Techniques to prevent pit aspiration or slow fixation reactions have, however, not significantly improved treatment. The presence of high...
S Kumar, J J Morrell


The use of bifluorides-diffusion in remedial treatments
1983 - IRG/WP 3256
A description is given about the experience to date of a 14 years' development to bring bifluorides-diffusion from laboratory evaluation to commercial service application. The described treatment is an adjunct to good design and not a replacement for it. The process is also used with an injection method for the remedial treatment of premature decayed external joinery....
H F M Nijman


Diffusion of bifluorides and borates from preservative rods in laminated beams
1991 - IRG/WP 3644
Laminated beams from spruce, pine and larch were treated with two preservative rods, based on bifluorides and octaborate respectively. After 3 and 6 months placed in different climates (65% r.h., 100% r.h., water) the diffusion of the active ingredient was measured. After the 6 months period, the diffusion of the bifluorides was, in all species, ca. 5 times larger than the diffusion from octaborat...
H Militz


Involvement of hydrogen peroxide in wood decay by brown-rot and white-rot fungi
1985 - IRG/WP 1256
To gain further understanding of the role of H2O2 in wood degradation by brown- and white-rot fungi, we studied the following: (a) extracellular H2O2 production, (b) effect of various hydroxyl radical (·OH) and singlet O2 (1O2) quenching agents on wood and cellulose degradation, (c) intracellular H2O2 production and catalase activity, and (d) cytochemical localization of H2O2 with diaminobenzidin...
T L Highley, L L Murmanis


Remedial treatment of joinery. Comparison of distribution of organic solvent preservative and ammonium bifluoride
1978 - IRG/WP 3115
It is some years since it was recognised in the United Kingdom that there was a problem of premature decay in untreated external joinery. Consequently, recommendations for preservative treatment were made by the Building Research Establishment, Princes Risborough Laboratory. In addition, the National House-Building Council has also included the preservative treatment of external joinery in its req...
J M Taylor


Iron in stone wool - one reason for the increased growth and decay capacity of Serpula lacrymans
1992 - IRG/WP 92-1537
The chemical compositions of stone wool and glass wool were analysed. There was more iron in the stone wool than in the glass wool. It was found that iron present in stone wool was easily dissolved by oxalic acid that Serpula lacrymans is able to produce. The stone wool promoted the decay of pine wood by Serpula lacrymans. The glass wool had no effect on the decay capacity of Serpula Iacrymans. Th...
L Paajanen, A-C Ritschkoff


Screening of lignin peroxidase from white-rot fungi
1998 - IRG/WP 98-10274
Since lignin peroxidase was first found in the ligninolytic culture of Phanerochaete chrysosporium, it has been regarded as an enzyme responsible for the lignin biodegradation and studied comprehensively. As the results of these studies its unique characteristics have been revealed. On the other hand, the features of lignin peroxidase produced by other white-rot fungi have not been studied so much...
I Momohara


Controlling the sapstain fungus Ceratocystis coerulescens by metabolites obtained from Bjerkandera adusta and Talaromyces flavus
1993 - IRG/WP 93-10024
Sapstain causes severe damage to wood and wood products, posing a major economic problem for the wood industry. The purpose of this study was to determine if metabolites from Bjerkandera adusta and Talaromyces flavus would (1) decolorize stain in wood caused by Ceratocystis coerulescens and (2) prevent sapstain by Ceratocystis coerulescens. We studied the interaction of the sapstain fungus Ceratoc...
S C Croan, T L Highley


Risk of pulmonary damage as a result of an evaporation of ca. 50 ppb = 42 mg HF, evaporated from wood treated by difluorides
1987 - IRG/WP 3401
In this review of the literature the effects of fluorides and fluorine on man are described, especially the low level effects of inhaled HF on human beings. The term "fluoride" is used as a general term everywhere, where exact differentiation between ionic and moluecular forms or between gaseous and particulate forms is uncertain or unnecessary. The term covers all combined forms of the element, r...
H F M Nijman


Production of exraxellular hydrogen peroxide and oxalic acid by brown-rot fungus Poria placenta
1995 - IRG/WP 95-10112
Hydrogen peroxide and oxalic acid have been suggested to be essential in the degradation of wood carbohydrates by brown-rot fungi. Hydrogen peroxide has been suggested to be one of the diffusible low molecular weight agents produced by brown-rot fungi for the degradation of wood carbohydrates by generating highly active radicals. The production of hydrogen peroxide and oxalic acid by Poria placent...
A-C Ritschkoff, M Rättö, J Buchert, L Viikari


Extracellular hydrogen peroxide producing and hydrogen peroxide reducing compounds of wood decay fungi
1991 - IRG/WP 1516
Extracellular H2O2-producing and H2O2-reducing compounds were isolated from wood-containing cultures of all the white-rot and brown-rot fungi and Ascomycetes which well degraded wood, but were not detected in the culture of the fungi which degraded little wood. The compounds are glycopeptides with a low molecular weight, require H2O2 for one-electron oxidation, catalyze the redox reaction between ...
A Enoki, G Fuse, H Tanaka


Emissions from the combusting of boron and fluoride containing wood
1995 - IRG/WP 95-50040-18
The combustion properties of waste wood and wood residues containing wood preservatives were investigated in several test series after having been blended with untreated wood at a ratio of 1:4. The results for CFB, SF and boric salt show that, provided an optimized combustion, the concentrations of the stack pollutants correspond approximately with those found for untreated wood. Only during the c...
T Salthammer, H Klipp, R-D Peek


Extracellular substance from the white rot basidiomycete Irpex lacteus involved in wood degradation
1992 - IRG/WP 92-1571
Cellulases, phenol oxidase, and a substance that both produced and reduced H2O2 were isolated from cultures containing wood or glucose on which the white-rot fungus Irpex lacteus was growing. The rate of wood degradation by the fungus with different amounts of glucose in the medium was measured. More of the substance that produced and reduced H2O2 was found extracellularly in cultures containing w...
H Tanaka, T Hirano, G Fuse, A Enoki


Basisiospore production by Lentinus lepideus in vitro
1987 - IRG/WP 2276
Evaluation of fungicides active against the lower fungi by spore based bioassays is very common. Possibilities of using similar assays to evaluate preservatives against brown rot and white rot fungi, especially for use in above ground constructions, are limited by the lack of methods for production of basidiospores. Tested media containing glucose 10-30 g/l and ammonium tartrate concentrations 2-2...
J Bjurman


The role of oxidation in wood degradation by brown-rot fung
1992 - IRG/WP 92-1562
Brown-rot fungi are suggested to degrade cellulose by oxidation with hydrogen radicalsformed eg. in the conversion of hydrogen peroxide in the Fenton type reactions. The stuctural changes in the holocellulose in wood induced by Fenton's reaction on wood components are very similar to those caused by brown-rot fungi. In this work the effect of the Fenton reaction on wood components was stu...
A-C Ritschkoff, J Pere, J Buchert, L Viikari


Formation of polychlorinated dibenzo-p-dioxins (PCDD) and polychlorinated dibenzofurans (PCDF) during the combustion of impregnated wood
1995 - IRG/WP 95-50040-19
Wood waste and industrial wood residues often contain various preservatives. The waste management for these residuals can be recycling, deposition or combustion. Among the three possibilities, combustion seems to be the most efficient way of disposal. To obtain detailed information about emissions of organic compounds with environmental impact, especially polychlorinated dibenzo-p-dioxins (PCDD) a...
T Salthammer, H Klipp, R-D Peek


Mechanistic aspects of the reactions of copper complexes with lignin in the presence of hydrogen peroxide and lipid hydroperoxide model compounds as proposed for white rot fungi
2001 - IRG/WP 01-10399
The structural principles and the oxidative reactions of the catalytic system consisting of copper, hydroperoxides, and copper coordination compounds that contain aromatic nitrogen atoms are similar to those of catalytic centers of oxidative enzymes involved in delignification reactions of white rot fungi. The system is capable of selectively degrading lignin and its low molecular weight would all...
K Fackler, P Lamaipis, E Srebotnik, M Humar, C Tavzes, F Pohleven, M Sentjurc, T Watanabe, K Messner


Extracellular hydrogen peroxide-producing and one-electron oxidation system of brown-rot fungi
1990 - IRG/WP 1445
Wood-component-degrading compounds involved in the initial degradation of the cellulose and lignin in wood were isolated from wood-containing culture of brown-rot fungi, Gloeophyllum trabeum and Tyromyces palustris and partially purified by gel filtration on Sephadex G-25 and DEAE-Sepharose ion-exchange chromatography. The compounds were glycoproteins. The molecular weights of the glycoproteins as...
A Enoki, S Yoshioka, H Tanaka, G Fuse


Site characteristics impacting historic waterlogged wood: A review
2000 - IRG/WP 00-10344
Survival of waterlogged wood from hundreds and in rare cases millions of years presents scientists with a unique opportunity to examine wood specimens which, due to select properties of the wood itself and/or the depostional environment, have not been completely degraded. Although degradation patterns of various types of microbial wood decay have been studied in detail, the site parameters of the ...
B A Jordan, E L Schmidt


Experiments on the degradation of tributyltin oxide: A progress report
1984 - IRG/WP 3287
A variety of experiments designed to assess the chemical and physical factors affecting the degradation of tributyltin oxide in treated timber are described. Simple procedures in which temperature and oxygen availability were increased in the presence of wood and water suggest that the wood itself was of prime importance. Attempts to decrease degradation with antioxidants were unsuccessful but led...
R J Orsler, G E Holland


In-house accelerated method for testing decay resistance of treated wood
2004 - IRG/WP 04-20286
Fungicidal compounds often change their effectiveness when they are incorporated into candidate formulations. For this reason fungistatic effectiveness needs to be re-evaluated as many times as the formula has been modified for better performance. To avoid multiple expenses, in-house fungistatic tests are essential. Our goal was to develop in-house usable, simple but reliable and reproductive proc...
N Vidovic


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