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Occupant re-entry times following insecticidal remedial treatments of timber in dwellings
1995 - IRG/WP 95-50055
This work was carried out principally to obtain quantitative data on the aerial concentrations of permethrin and white spirit likely to arise following the remedial treatment of timber in buildings, using insecticidal formulations. Such data are needed to allow assessments to be made of the length of time buildings should remain unoccupied following such treatments prior to re-occupation, and the ...
R J Orsler, G E Holland, G M F Van Eetvelde


Respiratory response of the wood boring teredinid, Lyrodus pedicellatus (Quatrefages) to copper stress
2004 - IRG/WP 04-10528
Wood boring teredinid molluscs engulf most of the wooden particles scrapped by them while actively boring into wood, obtaining nourishment for their metabolic activities. In order to protect the wooden structures from the biodeteriorating activity of such organisms, the wood is treated with different chemical formulations to prolong their service life. Copper chrome arsenic (CCA) is one such woo...
V Kuppusamy, M Balaji, M V Rao, K S Rao


The suitability of high pressure sap-displacement for the retention of UK grown spruce and pine
1990 - IRG/WP 3595
The concentration and radial distribution of copper, chrome, arsenic (CCA), and the moisture content and depth of radial checking in UK grown, field exposed spruce and pine poles treated by high pressure sap-displacement are examined. The concentration of CCA elements in samples obtained from increment cores is similar in Norway spruce, Scots pine and Corsican pine but is significantly lower in Si...
P D Evans, S D Hainey, A Bruce, G M Smith, B King


Influence of CCA and TnBTO on wood decay, under different oxygen levels and various initial moisture content
2001 - IRG/WP 01-10415
Fagus sylvatica (beech) and Pinus sylvestris (Scots pine) were impregnated by TnBTO (tributyl-tin oxide) and CCA (chromated copper arsenate). In wood blocks two levels of moisture content (50% and 100% of saturation point) were used. Three levels of oxygen concentrations (10, 21, and 50%) were chosen. Treated and untreated wood were exposed to three fungi (C. versicolor a white rot, C. puteana, a ...
S M Kazemi, R J Murphy, D J Dickinson


Effect of climate, species, preservative concentration and water repellent on leaching from CCA-treated lumber exposed above ground
2001 - IRG/WP 01-50178
Few studies have examined leaching of chromated copper arsenate (CCA) from treated wood in above ground exposures due to the assumption that leaching is less severe compared to wood in continuous contact with soil or water. However, a significant portion of CCA treated wood is used for above ground applications, exposing considerable volumes of the preservative to precipitation and potential leach...
J L Taylor, P A Cooper


The remaining concentration of inorganic wood preservative components in EN 252 stakes after ground contact
2000 - IRG/WP 00-50159
In order to determine the biological efficiency and the remaining concentration of different inorganic and organic active ingredients during service, EN 252 specimens were impregnated with 3 copper based wood preservatives. The stakes were installed in the test field of the DESOWAG GmbH, Rheinberg, for at least 7 years. At the end of the field test some of these stakes were divided into 10 uniform...
E Melcher, H-W Wegen


Standardization of preservative treated timber species for conductor, insulator and transformer packing of REB
1996 - IRG/WP 96-40071
In order to resolve the post landing failure problem of wooden packing for conductor, insulator, transformer of REB, the names of the suitable timber species from different parts of the world, irrespective of countries of origin have been standardized along with their strength and treatability grades. The CCA treatability of some Pakistani timber species have been presented for example which was t...
A K Lahiry


Chitosan for wood protection - state of the art
2005 - IRG/WP 05-30378
The aim of this paper was to give a state of the art description of chitosan as a wood protecting agent. Chitosan is a metal free natural compound derived from crustacean shells and is under evaluation as an environmentally benign wood protecting agent. Information from journals states that chitosan may act both fungistatically and at higher concentrations, as fungitoxic, but the mode of action is...
M Eikenes, G Alfredsen, E Larnøy, H Militz, B Kreber, C Chittenden


Determination of the amine to copper ratio remaining in wood after leaching
2002 - IRG/WP 02-30285
The effectiveness of the protection and the environmental impact of the treated wood are two of the most important aspects that need to be understood for all preservatives. Both are particularly influenced by the loss of biocidal components from treated wood. For amine copper preservatives, copper fixation determines the leaching resistance of the copper and amine compounds formed in wood. Previou...
N Lucas, J N R Ruddick


Simulation test of subchronic inhalation toxicity of TBTO vapours in the air
1987 - IRG/WP 3454
The test was carried out in a wainscotted room of a normal size. Wooden panelling had been treated with one coat of basic preserving agent and, after the installation, with 2 coats of stain. Laboratory animals (rats) were kept in this room for 90 days. For the same period a control group of test animals was kept in a room of equal size where there was no panelling. During the test, concentration o...
V Skubic, S Kobal, J Stupar, R Ajlec, J Korošin, G R Pecenko


Mould growth at lumber surfaces of pine after kiln and air drying
1994 - IRG/WP 94-40033
Distribution of water soluble substances in green wood and later redistribution during drying is of importance for the colonisation of wood by microorganisms. According to literature the availability of nitrogenous materials is probably a major limiting factor to the microbial colonisation of wood. King et al. (1974) and Oxley et al. (1976) have shown correlation between surface nutrient concentra...
N Terziev, J Bjurman, J B Boutelje


Moderate temperature fixation of CCA-C
1989 - IRG/WP 3522
Several Canadian treating plants are using moderate temperature (40-60C°) fixation chambers to reduce drippage and leaching from fresh CCA treated wood. In this study, chromium reduction and surface leaching properties of CCA-C treated red pine (Pinus resinosa) pole sections were monitored during exposure to temperatures of 50-60C° and 90-100% RH conditions. Chromium-VI concentration in the abso...
P A Cooper, Y T Ung


Effect of species, retention and conditioning temperature on copper stabilization and leaching for ACQ-D
2004 - IRG/WP 04-30342
The time to stabilization or equalization of the copper component of ACQ-D was highly dependent on treating solution concentration (preservative retention) and post treatment temperature. Stabilization was rapid for low preservative retentions but extended times were needed for wood treated with higher concentration solutions. The extent of stabilization was also concentration dependent with a h...
Y T Ung, P A Cooper


Estimation of the impregnation degree of pine wood by the distribution analysis of active ions concentration in the cross-section
1999 - IRG/WP 99-20174
Samples in the form of pine wood rollers of diversified moisture content of ca. 50, 28 and 12% were impregnated with a water solution of the mixture type CCB with the use of the full-cell process. Moisture content was determined in individual layers from the girth to the pith. In the same way the concentrations of copper and chromium ions with the use of the spectrophotometric method and recalcula...
K Lutomski, B Mazela


Assessing health risks to occupants following remedial insecticidal treatment of timber in dwellings
1998 - IRG/WP 98-50101-27
Experiments have been carried out to assess (i) the aerial concentrations of volatile wood preservative constituents, and (ii) the potential for contamination from treated surfaces, following in situ insecticidal treatment of timbers in dwellings. Using white spirit as a model for volatile constituents in the treatment of free-standing, wood-lined chambers indicated that temperature and air exchan...
R J Orsler, E D Suttie, V Rijckaert


A technical note on the limitations of atomic absorption spectrophotometric analysis of copper/chrome/arsenic solutions according to BS 4072 (1974) and BS 5666: Part 3 (1979)
1988 - IRG/WP 2320
British Standards BS 4072 (1974) and BS 5666: Part 3 (1979) detail an atomic absorption spectrophotometric method for the quantitative determination of copper, chrome and arsenic in both preservative solutions and treated timber. Use of this technique during a research programme at Aberdeen has highlighted some potential inaccuracies with this method if these standard specifications are adhered to...
A J Pendlebury, J A Petty


Minimum inhibitory concentration of methylene bisthiocyanate towards selected wood inhabiting fungi in liquid culture and on radiata pine
2001 - IRG/WP 01-30261
The objective of the current study was to determine the minimum inhibitory concentration (MIC) of methylene bisthiocyanate (MBT) towards wood inhabiting fungi common on unseasoned radiata pine (Pinus radiata D. Don). The fungi used were Ophiostoma floccosum, Leptographium procerum, Sphaeropsis sapinea and Trichoderma viride. Fungi were individually inoculated into nutrient media spiked with differ...
T Singh, B Kreber, C Chittenden, R N Wakeling, A Stewart


The role of oxygen and oxygen radicals in one-electron oxidation reactions mediated by low-molecular weight chelators isolated from Gloeophyllum trabeum.markup
1994 - IRG/WP 94-10086
The KTBA assay for determination of one-electron oxidation activity was used to assay reactions of low-molecular weight chelators isolated from the brown rot fungus Gloeophyllum trabeum. The assay, performed either under air or nitrogen showed that molecular oxygen was an important factor in chelator-mediated oxidation reactions. A reduction in oxidative activity was observed when superoxide dismu...
Jun Lu, B Goodell, Jiang Liu, A Enoki, J Jellison, H Tanaka, F Fekete


Leaching of components from CCF treated timber in ground contact
1998 - IRG/WP 98-50108
In order to investigate the depletion of different CCF-salts during service small stakes (10*10*450mm³) were treated with five water-borne wood preservatives and after fixation brought into ground contact for several years. After failing some of the broken down stakes were used to determine the remaining concentration of relevant ions and their distribution in different segments of the stakes. A...
E Melcher


Experimental variations in the distribution of CCA preservative in lignin and holocellulose as a function of treating conditions (temperature, concentration, pH, species, and time)
1984 - IRG/WP 3277
The exact distributions between lignin and holocellulose and retentions on wood of copper, chromium and arsenic as a function of various sets of conditions in a 3x3x4x2 factorial experiment in which combinations of three temperatures of treatment, three CCA solution concentrations, four pH's of the initial CCA solution and two timber species, namely Pinus radiata and Eucalyptus grandis, a...
A Pizzi, E Orovan, M Singmin, A Jansen, M C Vogel


The resistance of wood coated with different water-borne paints against colonisation by decay fungi
1996 - IRG/WP 96-10165
The susceptibility of wood painted with model paints of known composition to decay fungi was tested without previous weathering. Included in the study were five alkyd emulsion paints and five acrylic paints; one linseed oil paint and two solvent-borne alkyd paints. It was found that several components influenced the susceptibility of these paints. The results of the present study indicate that the...
J Bjurman


Use of the Digital Refractometer for the On-site Analysis of Copper-based Preservative Systems
2007 - IRG/WP 07-20371
In some counties, there are no on-site chemical analysis methods available for treatment plants to use to determine the key active ingredients in the preservative treatment solutions. The complexity of the sophisticated methodology; cost of analytical instruments and training required for operating these instruments in treating plant level are the reasons for lacking such practice. In this paper...
L Jin, T Cashman, A Preston, J Trompetter, H Trompetter


Effect of a biological treatment on below ground decay of Douglas-fir pole sections
2008 - IRG/WP 08-40433
The use of exogenous sugars to accelerate microbial growth and eventually limit available oxygen in soil surrounding wood in soil contact was investigated on untreated Douglas-fir poles exposed over a 3 year period in Western Oregon. Isolation frequencies differed markedly between treated and untreated poles and the treatment did appear to shift the frequency of some basidiomycetes. The treatment ...
C Freitag and J J Morrell


Degradation of wood veneers by Fenton’s reagents: effects of low molecular weight phenolic compounds on hydrogen peroxide decay and tensile strength loss
2009 - IRG/WP 09-20400
Pine wood (Pinus sylvestris) veneers strips were incubated in acetate buffer containing hydrogen peroxide and iron to mimic mechanisms of brown rot decay and assess the degradation of cellulose through analysis of the tensile properties of the decayed wood. The tensile properties of thin wood strips treated with Fenton system reagents or precursors were determined and correlated to weight loss as ...
Yanjun Xie, R Well, Zefang Xiao, B Goodell, J Jellison, H Militz, C Mai


Effects of concentration and temperature of CCA and CCB on wood strength of Turkish fir (Abies bornmulleriana Mattf.)
2009 - IRG/WP 09-40450
The purpose of this study was to present evidence for the effects of concentration and temperature of solutions of water-borne preservatives (chromated copper arsenate, CCA and chromated copper boron, CCB) on the static bending properties (modulus of elasticity, MOE and modulus of rupture, MOR) of Turkish fir (Abies bornmulleriana Mattf.). Wood samples were mechanically tested after a mild full ce...
I Usta, M Hale


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