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Comparison of laboratory and semi-field tests for the estimation of leaching rates from treated wood
2010 - IRG/WP 10-50274
The authorization of wood preservative formulations in the European Union according to the Biocidal Products Directive (BPD) includes the assessment of environmental risks by the emission of active ingredients. This risk assessment includes scenarios for preserved wood (e.g. house scenario, noise barrier), in which the predicted environmental concentration (PEC) for soil and water is calculated, u...
N Morsing, M Klamer, B Seidel, J Wittenzellner, M Maier, J Habicht


The Chemical and Biological Properties of Polymeric Betaine
2009 - IRG/WP 09-30512
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. DPAB as a wood preservative has been reported previously. This paper summarizes the chemical, physical, and biological properties of DPAB.
H Härtner, S Schmitt, Futong Cui, H M Barnes


Serpula lacrymans – calcium, iron, and foundering wooden boats
2009 - IRG/WP 09-10691
Serpula lacrymans is one of the most destructive wood-degrading brown rot fungi in temperate environments. Its virulence has often been linked to its ability to grow over non-woody materials and extract calcium (Ca) or iron (Fe) to promote wood degradation in buildings. This fungus has also been a severe problem in historic wooden warships and in modern wooden vessels, sometimes leading to founder...
J S Schilling, S M Duncan


SEM-EDXA of CCA-treated Rubberwood (Hevea brasiliensis)
2009 - IRG/WP 09-20399
The microdistribution of chromated copper arsenate (CCA) preservative in rubberwood was studied using scanning electron microscope in conjunction with energy dispersive X-ray analyzer (SEM-EDXA). Bulk X-ray analysis showed that there was a high accumulation of chromium, copper, and arsenic in the vessels and lower concentration of the three preservative elements in fibres. Chromium appeared to rec...
I Jusoh, D P Kamdem


Durability and fungal colonisation patterns in wood samples after six years in soil contact evaluated with qPCR, microscopy, TGA, chitin- and ergosterol assays
2009 - IRG/WP 09-20402
There is a need to establish new objective and sensitive methods for early detection and quantification of decay fungi in wood materials. Molecular methods have proven to be a useful tool within wood protection issues, however, this field is still poorly explored and so far relatively few have used these methods within the field of wood deterioration. Among the techniques used in the indirect quan...
A Pilgård, G Alfredsen, I Børja, C Björdal


Accelerated H3 above-ground decay trials in Australia
2009 - IRG/WP 09-20411
An above-ground H3 fungal field trial was installed at five sites (3 in Australia, 2 in New Zealand), with the aim of finding a method that would shorten the time required for evaluating new preservatives and protection systems. One-quarter of the H3 preservative retentions were mostly installed, as first results suitable for registration occur when these reach 70% soundness. Chemical analysis of ...
L J Cookson, J Carr


The Promotion of Timber and Timber Product uses in China - Government's Role in Regulation and Standardization
2009 - IRG/WP 09-20424
Chinese Government always pays special attention to resource and environmental issues, therefore, resource saving and environmental protection are part of the basic state policies. This paper provides a brief summary of the key policies which guide the practices in promoting timber conservation and efficient utilization in order to meeting social demands of the wood uses. In the paper, the develop...
Liu Nengwen


Effectiveness of sol-gel treatments coupled with copper and boron against subterranean termites
2009 - IRG/WP 09-30493
Wood modification by sol-gel treatments shows many positive features, like antimicrobial properties. Wood was also successfully modified with alkoxysilanes enhancing its resistance against soil micro-organisms. Silver, copper, zinc compounds, boric acid or organic biocides such as alkylammonium compounds may be added to the sol-gel to enhance its biocidal properties. Nevertheless, if some of these...
E Feci, L Nunes, S Palanti, S Duarte, G Predieri, F Vignali


A theoretical-industrial correlation and perspective on copper-based wood preservatives - a review of thermodynamic and kinetic aspects on copper-wood fixation mechanism
2009 - IRG/WP 09-30499
Copper was and it will continue to remain one of the key active component in wood protection industry. Over the past decades, a significant effort from R&D teams in industry, academia and research institutes was directed toward understanding the copper-wood fixation mechanism, optimising the copper retentions in the wood and reduce leaching in order to maximized performance, prolong the lifetime o...
R Craciun, M Maier, J Habicht


Re-Distribution of Copper in the Cell Walls of Wood Treated with Micronized Copper Quat
2009 - IRG/WP 09-30506
Wood treated with copper-based preservatives to be used in ground contact may fail to inhibit soft rot fungi if penetration of copper into the cell wall is insufficient. Preservatives containing soluble copper are known to penetrate the cell wall; however, it is not known whether preservatives containing particulate copper will also migrate into the cell wall in sufficient quantities to control so...
R Stirling, J Drummond


Laboratory test of some formulations against stain and mould fungi isolated from bamboo wood
2009 - IRG/WP 09-30508
To screen the effective anti-mould formulations, fungicides such as carbendazim, tebuconazole, fludioxonil, difenoconazole, prochloraz, benomyl and 8-hydroxy-quinoline copper (copper oxine) were selected to conduct the laboratory test of fungicidal activity by method of inhibition zone against Botryodiplodia theobromae Pat., Fusarium sp., Alternaria tenuis Nees., Penicillium purpurogenum Stoll, Tr...
Xingxia Ma, Airui Sun, Mingliang Jiang, Daochun Qin


Leaching properties of copper and triazole
2009 - IRG/WP 09-30509
The leaching rate of copper and triazole (such as tebuconazole and propiconazole) in different preservative formulations was determined according to AWPA E11-06. Of all copper triazole and ACQ formulations, copper fixation rate of ammonia based was higher than that of ethanolamine based and the mixture of them. Copper fixation rate at relatively higher retention was slight higher than that at lowe...
Zhiqiang Li, Xiaowen Li, Ying Zhang, Mingliang Jiang


The Form of Copper: Does It Really Matter?
2009 - IRG/WP 09-30513
In recent years, several micronized copper formulations for lumber treatment have supplanted the solubilized copper formulations that in turn replaced CCA after its voluntary relabeling in 2004. The micronized or dispersed copper systems use finely ground but solid copper particles and deposit those particles within the wood framework. In contrast, copper in the soluble formulations is relativel...
C R McIntyre, M H Freeman, T F Shupe, Q Wu, D P Kamdem


Mold-resistance Effect of Bamboo Wood Treated with CCC-organic Complexes
2009 - IRG/WP 09-30514
Mold resistant effect of CCA, ACQ, CuAz, CCC and the compound of CCC and propiconazole were researched on bamboo wood of Phyllostachys pubescens were reported in this paper. Results showed that all of the test fungicides could protect bamboo wood better from Penicillam citrinum than from Trichoderma viride and Aspergillus niger. The complex of CCC and propiconazole had the best resisting effect on...
Sun Fangli, Yang Le, Chen Anliang, Bao Binfu, Li Qiao


Micronized Copper Preservative Systems: Observations on the Release of Cupric ion (Cu2+) from Treated Wood and Performance against Wood Decay Fungi
2009 - IRG/WP 09-30519
In an attempt to address the mechanism of action of micronized copper preservatives, a 20-week continuous water leaching study was conducted. The leaching results indicated that, once impregnated in wood, micronized copper preservatives continuously release cupric ion, and the levels of cupric ion released from micronized copper treated wood are higher than those released from CCA treated wood, a...
J Zhang, R Ziobro


Leaching of the copper component from full scale decking boards during one summer season
2009 - IRG/WP 09-50260
The leaching of copper has been tested in laboratory and in outside exposure for freshly treated pine sapwood samples with three different copper preservatives, Cu HDO, copper quat and copper triazoles. We found in the laboratory leaching test that a fixation with warming to 60 °C (140 °F) for 48 hours without drying and then drying in the laboratory in room temperature gave the lowest leach...
F G Evans


Component leaching from CCA, ACQ and a micronized copper quat (MCQ) system as affected by leaching protocol
2009 - IRG/WP 09-50261
Leaching results for Cu, Cr and As (CCA) and Cu (ACQ and MCQ) from southern pine are compared for laboratory tests (AWPA E11, and draft OECD methods I and II) and natural weathering of horizontally and vertically oriented lumber samples over two seasons. This paper expands on results and comparison of results presented at the IRG regional meeting in Costa Rica in Dec 2008 (Cooper and Ung 2008) a...
P A Cooper, Y T Ung


Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe


Factors affecting sodium hypochlorite extraction of CCA preservative components from out of service treated wood for recycling
2009 - IRG/WP 09-50263
Significant amounts of chromated copper arsenate (CCA) treated wood products such as utility poles and residential constructions remain in service. There is an increasing public concern about environmental contamination from CCA treated wood when it is removed from service for reuse or recycling, placed in landfills or burned in commercial incinerators. In this paper, we investigate the effects of...
E D Gezer, P A Cooper


Termite resistance of some modified wood species
2009 - IRG/WP 09-40449
During the last few decades, researchers worldwide have investigated and developed new treatment techniques to improve intrinsic wood properties. Some of these techniques were introduced to the market recently and are gaining in importance.. Various wood properties of these new materials have been studied intensively. These include physical-mechanical properties (dimensional stability, moisture ...
H Militz, B C Peters, C J Fitzgerald


Effects of concentration and temperature of CCA and CCB on wood strength of Turkish fir (Abies bornmulleriana Mattf.)
2009 - IRG/WP 09-40450
The purpose of this study was to present evidence for the effects of concentration and temperature of solutions of water-borne preservatives (chromated copper arsenate, CCA and chromated copper boron, CCB) on the static bending properties (modulus of elasticity, MOE and modulus of rupture, MOR) of Turkish fir (Abies bornmulleriana Mattf.). Wood samples were mechanically tested after a mild full ce...
I Usta, M Hale


Tensile stress relaxation of wood impregnated in different ACQ formulations at various temperatures
2009 - IRG/WP 09-40456
The reactions between ammoniacal copper quat (ACQ) constituents and wood components were investigated by tensile stress relaxation approach. Small wood samples were stressed and impregnated in ACQ solutions with different formulation including the ethanolamine (MEA) to copper molar ratio, copper (as copper oxide) to quat (as DDAC) weight basis, treatment temperature and also the solution concentra...
Lili Yu, Jinzhen Cao


Wood properties influencing the penetration of Scots pine (Pinus sylvestris) sapwood with the wood modification agent furfuryl alcohol
2009 - IRG/WP 09-40470
The European standard EN 350-2 classifies Scots pine sapwood as class 1 (easy to treat). However large variations in sapwood penetration exist which affect a homogenous distribution of preservatives. Hence individual penetration schemes have to be developed and adjusted to the material most difficult to treat in order to provide adequate sapwood penetration. To ensure better economic process con...
K Zimmer, E Larnøy, G Koch


Future Directions in Wood and Engineered Wood Products Research in China
2009 - IRG/WP 09-40479
This paper has summarized the research advance of basic wood science and engineered wood products in the 20th century in China and introduced the research advance and directions of basic wood science, engineered wood products and the extensive researches based on the basic wood science such as wood chemical rheology, wood fractal analysis, wood environmental science and nano-wood material etc in t...
Guangjie Zhao


Physical and Mechanical Properties of Bamboo Oriented Strand Board Treated with Copper-based Preservatives
2009 - IRG/WP 09-40482
Oriented strand board (OSB) has been gradually accepted, used and developed in China. Bamboo is a renewable and potential non-wood fibre resource for making OSB. But the nature of bamboo makes its products including bamboo OSB (BOSB) more prone to decay and mold. Protection BOSB from biodegradation is the key both to efficiently using bamboo resource and to improving the durability of the final pr...
Juwan Jin, Daochun Qin


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