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Copolymers of tannin extracts as wood protection agents
2017 - IRG/WP 17-30709
Wouldn´t be a dream to preserve wood with the substances which the nature already synthesizes for protecting itself? The idea we would like to pursue is simple: Increase the concentration of these substances, the tannins, trying to fix them properly in wood. It appears easy but it is not. Sensibility against leaching, fungal decay and weathering were observed. In this paper new flavonoid co-polym...
G Tondi, L Sommerauer, A Oberle, A Petutschnigg, M-F Thevenon


Improvement of wood decay resistance by tannin impregnation
1991 - IRG/WP 2380
The fungical effect of tannins is appraised after exposure of treated woods samples to wood rotting fungi. A screening-test is carried out with several solutions containing extracts of two kinds of tannins; a condensed tannin derived from Quebracho heartwood (Schinopsis sp.) and a hydrolyzable one extracted from chestnut heartwood (Castanea sativa Mill). If a fungicidal action was indeed found it ...
D Dirol, A Scalbert


Dimensational stabilisation of wood
1981 - IRG/WP 3171
A review is given of the studies on the dimensional stabilisation of wood which have been carried out in the laboratory 5.14 "Wood Technology" since 1967. All stabilisation methods known have first been compiled from the available literature. Practical studies were then started. Wood was treated with monomers (styrene, methyl metacrylate, isocyanate), formaldehyde, tannin and sugar. Despite a sati...
A Burmester


Chemically modified tannin and tannin-copper complexes as preservatives for wood
2001 - IRG/WP 01-30271
The efficacy of Mimosa tannin, chemically modified tannin, and tannin-copper complexes as wood preservatives was studied. When the tannin-ammonia-CuCl2 solutions were impregnated into wood specimens in a one-step procedure, a large quantity of the tannin-copper complex was fixed in the specimens. Little of the complex was leached from specimens by a weathering treatment, and these specimens showed...
H Yamaguchi


Compatibility of deltamethrin with wood adhesives
1993 - IRG/WP 93-30031
This work presents the studies conducted on the compatibility of deltamethrin when mixed with wood adhesive to manufacture plywood in order to protect the wood against wood-borers insects and termites. The following types of adhesive were tested: PVA, Urea-formaldehyde, phenol-formaldehyde and a formulation based on tannin. The experiments were made in the adhesive manufacturers' laborato...
A M F Oliveira


Impregnation of timber with tannin as a mean of improving its dimensional stability
1992 - IRG/WP 92-3695
The results of a joint project carried out at the Timber Division of LNEC under the 2nd research programme of the CEC DGXII - "Wood as a renewable raw material" entitled "Stabilization of wood by impregnation processes" is presented. Pieces Maritime pine timber was impregnated with tannin under pressure to see if the treatment with tannin improved the behavior of wood regarding its dimensional sta...
J S Machado


The Comparison of Fixation and Leachability of Bark, Fruit and Leaf Tannin Extracts with Boron Minerals
2008 - IRG/WP 08-30473
Tannins extracted from several plants have natural durability properties. Due to these properties, some of the researchers have studied them for protecting wood. In this study, Scots pine (Pinus sylvestris) and beech (Fagus orientalis) wood samples were treated with bark, fruit, and leaf extracts as well as water-based wood preservative salts at various concentrations to increase fixation. The pen...
S Sen, C Tascioglu, K Tirak


Fungal decay resistance and durability of wood products made from borax-impregnated wood and bonded with corn starch and tannin adhesive
2009 - IRG/WP 09-30494
At present, the production of wood composites mainly relies on the petrochemical-based and formaldehyde-based adhesives such as phenol formaldehyde (PF) resins and urea formaldehyde (UF) resins, which are non-renewable and therefore ultimately limited in supply. This paper concerns the decay resistance of wood products bonded with a new, environment-friendly adhesive derived from abundant and rene...
A Moubarik, A Pizzi, A Allal, F Charrier, B Charrier


Fungal decay resistance and mechanical properties of plywood panels made from maritime pine (Pinus pinaster) and bonded with cornstarch-quebracho tannin-phenol formaldehyde adhesive
2010 - IRG/WP 10-40490
The aim of this work is to demonstrate the performances of cornstarch-quebracho tannin-based resins designed as adhesive in the plywood production. In this way, the cornstarch and quebracho tannin was introduced in the classic adhesive formulation in order to supply a part of phenol-formaldehyde (PF). In order to evaluate the mechanical performances of optimal cornstarch-quebracho tannin-PF, plywo...
F Charrier, A Moubarik, A Allal, A Pizzi, B Charrier


Tannin resin-boron for outdoor wood protection and fire retardancy
2011 - IRG/WP 11-30567
Boron in the form of boric acid is well known for its efficacy against wood destroying organisms, as well as for its high leachability from treated wood when in outside exposure. Moreover, due to the European directive 2008/58/EC, boric acid is only authorized at low levels. In order to keep considering boric acid as an interesting active ingredient for wood protection, the issue is now to fix it ...
M-F Thévenon, G Tondi, N Leménager, S Wieland, A Pizzi


Biological and mechanical performances of particleboard panels made from maritime pine (Pinus pinaster) and glued with cornstarch-mimosa tannin-urea formaldehyde adhesive
2011 - IRG/WP 11-40542
The objective of this work was to demonstrate the utility of cornstarch-mimosa tannin-based resins designed for application as an adhesive in the particleboard production. Bond qualities of cornstarch-mimosa tannin- urea formaldehyde (UF) (10:4:86, weight ratios) resins and commercial UF resin were assessed by using an automatic bonding evaluation system, prior to production of particleboard panel...
A Moubarik, F Charrier, A Pizzi, A Allal, B Charrier


Tannin resin-boron associations: Leaching and biological resistance
2012 - IRG/WP 12-30587
The easy leaching of boron in wood preservation formulations has allowed to use this fungicide only for short term applications. The recently discovered adduct with flavonoids allows boron to resist longer periods of time within wood and consequently extend its life. Two different leaching treatments were compared and the fungal and termite decay was examined. The biological tests have shown extre...
G Tondi, S Wieland, N Lemenager, A Petutschnigg, A Pizzi, M-F Thevenon


Thermal durability and biodegradation of tannin lignin adhesives
2014 - IRG/WP 14-40657
Mimosa tannins and lignosulfonates were used in wood adhesives formulation to substitute resins based on formaldehyde. Mimosa tannins were mixed with either glyoxalated sodium lignosulfonates or glyoxalated ammonium lignosulfonates. The ratios of mimosa tannins and sodium lignosulfonates varied from 20% tannins to 60% tannins. The thermal durability of the adhesives were analysed by thermogravimet...
L Chupin, B Charrier, A Pizzi, F Charrier


Evaluation of advanced tannin-boron preservative in unsterile soil-bed tests
2016 - IRG/WP 16-30693
In Europe, boron compounds are facing restrictions, and due to their natural solubility into water, the only way to keep using them for wood protection is to fix them into the wood, at very low level (Obanda et al. 2008). In the meantime, the idea of protecting wood with natural preservatives has been back into favour (Lotz and Hollaway 1988, Nakayama et al. 2001, Singh and Singh 2012). Tannin a ...
Jinbo Hu, Yiqiang Wu, Shanshan Chang, Guangming Yuan, G Tondi, M-F Thévenon


Environmentally Friendly Wood Modification based on Tannin-Furfuryl alcohol - Effect on stabilisation, mechanical properties and decay durability
2022 - IRG/WP 22-40929
Furfurylation is a well-known wood modification technology. This paper studied the effect of tannin addition on the wood furfurylation. Three kinds of dicarboxylic acids, adipic acid, succinic acid, and tartaric acid, as well as glyoxal as a comparing agent, were used to catalyse the polymerisation of furanic or tannin-furanic solutions during wood modification. Impregnation of furanic or tannin-f...
M Mubarok, E Azadeh, F O Akong, S Dumarçay, A Pizzi, C Charbonnier-Gérardin, P Gérardin


Novel bio-based tannin/furfurylic alcohol thermosets: application to wood preservation
2022 - IRG/WP 22-40959
This project is integrated within the overall context of sustainable development and targets the valorization the wood industry by-products such as polyphenolic extractives, and in particular tannins. The objective targets the use of the same polymer used for production of tannin-furanic foams, but here for wood preservation to avoid the utilization of biocides. The aims is to the design of copoly...
C Gérardin-Charbonnier, E Azadeh, A Pizzi, P Gerardin


Geopolymer as a fixation method for tannin-based wood preservatives
2023 - IRG/WP 23-30774
This study aims to test if a second step impregnation with a geopolymer solution can fix Colatan GT10, a commercial extract rich in tannins, to wood, reducing their leaching and improving their performance as wood preservatives. Scots pine sapwood specimens of 40×10×5 mm3 were impregnated with Colatan GT10 tannin mix, geopolymer, and as combined treatment Colatan GT10 with subsequent geopolymer ...
Y M López-Gómez, A Barbero-López, A Haapala


Optimization of furfurylic alcohol/tannin ratio to improve the performance of biosourced thermoset resins for wood protection
2023 - IRG/WP 23-40994
This study concerns the chemical modification of wood with different ratios of tannin and furfuryl alcohol (FA) in the presence of maleic acid as catalyst. Tannins were used not only as cross-linking agents, but also as co-monomers to improve wood durability, while reducing the amount of FA used. Different aqueous formulations were prepared containing decreasing amount of FA (from 45.45% to 0%) an...
E Azadeh, A Pizzi, P Gérardin, C Gérardin-Charbonnier