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Chemical Analysis of Southern Pine Pole Stubs Thirty-Nine Months Following Treatment with Three Methylisothiocyanate-Based Fumigants
2004 - IRG/WP 04-30349
Agricultural fumigants have been commercially used in the United States for over 20 years to control internal decay in utility poles and other wooden structures. Of the four fumigants which are currently used in the remedial treatment of utility poles, three are based on methylisothiocyanate (MITC) as being the principal fungitoxic component. Two of these MITC-based fumigants, liquid metham sodi...
R J Ziobro, J Fomenko, D J Herdman, J Guzzetta, T Pope


Serviceability of copper naphthenate-treated poles
2000 - IRG/WP 00-30214
Copper naphthenate-treated poles in service were inspected for deterioration, penetration, retention, and serviceability. The study to date has included poles in all hazard zones in the United States. Poles installed by 12 different utilities and eight different treating companies are included in the survey. Both southern pine and Douglas-fir poles and distribution and transmission poles are inclu...
H M Barnes, M H Freeman, J A Brient, C N Kerr Jr


Copper naphthenate-treated Southern Pine pole stubs in field exposure: - Part 1: Gradient & biodeterioration analysis 12 years after treatment
2000 - IRG/WP 00-30242
Naphthenates have been used for the preservation of timber and cellulose since their original identification in Russia in the early 1880's as part of a series of petroleum characterizations. Later work in the development of copper naphthenate as a heavy-duty preservative for poles led to the development of various treating cycles similar to other oil-borne systems. Recent work concerning ...
H M Barnes, M H Freeman


Preservative treatment and field test monitoring of spruce pole stock: Pressure and diffusible chemical treatments
1990 - IRG/WP 3605
One hundred and forty four spruce (test species) and southern yellow pine (reference species) poles were variously treated by center boring, incising, or kerfing, followed by pressure treatment with CCA and/or diffusible preservatives. The diffusible preservatives included NaF/creosote, borax and ammonium bifluoride. The poles were set at a test site and evaluated for preservative distribution and...
B Goodell, A J Pendlebury


Feasibility of using biological control agents to arrest and prevent colonization of Douglas fir and southern pine by decay fungi
1988 - IRG/WP 1345
The use of microfungi to control basidiomycetous decay has been evaluated in Europe for many years, where it has produced mixed results against Lentinus lepideus Fries, the fungus presumed to be the major cause of decay in Scots Pine poles. In the United States, remedial decay control has been largely chemical, with little use of alternative decay control strategies. Increasing restrictions on che...
J J Morrell, C M Sexton


Non leachability of arsenic, copper and chromium from 15 years old CCA-C treated southern pine poles used in brackish water as jetty piles in Bangladesh
1998 - IRG/WP 98-50103
Revealed that chromated copper arsenate type C (CCA-C) treated southern pine poles used in Central Warehouse Jetty of REB, Khulna are stable and resistant to chemical and biological attack without loss of any component from outer 0-12.5 mm zone after 15y of use. Slightly reduced retention (4.44% less) was noted in above water location of piles (bottom end of tree) which would be due to continuous ...
A K Lahiry


Microscopic analysis of southern pine utility pole core segments
1992 - IRG/WP 92-1542
Fifteen macroscopic core descriptive categories were evaluated by microscopic analysis for accuracy in detecting decay and judging decay severity. Five categories were good indicators of decay as decay was detected in 28 of 48 samples. Five categories were possible indicators of early decay as decay was detected in 6 of 40 core segments and an additional 18 contained hyphae. The remaining five cat...
S E Anagnost, C J K Wang, M Wright


Chemical Analysis of Southern Pine Pole Stubs Thirteen Months Following Treatment with Three Methylisothiocyanate Based Commercial Fumigants
2002 - IRG/WP 02-30294
Agricultural fumigants have been commercially used in the United States for over 20 years to control internal decay in utility poles and other wooden structures. Of the four fumigants which are currently used in the remedial treatment of utility poles, three are based on methylisothiocyanate (MITC) as being the principal fungitoxic component. Two of these MITC based fumigants, liquid metham sodi...
R J Ziobro, T C Anderson, D J Herdman, J Guzzetta, T Pope


CCA type C depletion of Southern yellow pine utility poles
1995 - IRG/WP 95-50049
Depletion and redistribution of preservative components were evaluated on five CCA-C treated poles in service for over six years in Conley, Georgia. A statistical approach was taken in which retentions below ground were compared to retentions above ground due to a lack of initial data on individual poles. It was hypothesized that the below ground retentions should be lower than the corresponding a...
P D Osborne, R F Fox


Chemical Analysis of Southern Pine Pole Stubs Sixty Months Following Treatment with a Methylisothiocyanate-Based Solid Fumigant Stick
2019 - IRG/WP 19-30740
Methylisothiocyanate-based fumigants have been commercially used in the United States for over 35 years to control internal decay in utility poles and other wooden structures with little technological advancement. The most recently commercialized methylisothiocyanate-based fumigant is chemically known as dazomet. Dazomet is a free-flowing powder or granule that decomposes in the presence of mois...
D J Herdman, T Pope, R R Browning


Field trial with poles of Scots pine treated with six different creosotes
1996 - IRG/WP 96-30115
In the middle of the 50's field trials with creosote-treated poles were started in France, Germany and Sweden. The trials were initiated by WEI (Western-European Institute for Wood Preservation). Six different creosotes were used and 40 poles per creosote were installed at each test field. Results after 39 years of exposure in Simlangsdalen, Sweden are reported. Poles treated with a heavy...
Ö Bergman


Dimensional stabilization of wood with dimethylol compounds
1987 - IRG/WP 3412
This study showed that a substantial degree of dimensional stability can be imparted to wood by crosslinking with low concentrations of dimethyloldihydroxyethyleneurea. It was demonstrated that by selecting the right catalyst system the cure temperature can be reduced to the point that strength loss of the treated wood is minimized....
D D Nicholas, A D Williams


Movement of boron from fused boron rods implanted in Southern pine, Douglas fir, red oak, and white oak timbers
1995 - IRG/WP 95-30061
This paper reports the distribution of boron from fused boron rods installed into six-inch (15.2 cm) square timbers of Douglas-fir, Southern Pine, red oak and white oak exposed aboveground. The composition and size of rods was: sodium borate and sodium borate-copper oxide (8.5 x 100 mm²); sodium borate-copper, sodium borate and boric oxide-copper oxide (12 x 76 mm²). The boric acid equivalent wa...
T L Highley, L Ferge


Performance of surface-treated hardwoods and softwoods out of ground contact
1990 - IRG/WP 3592
A number of fungicides were tested as brush treatments for protection of southern pine, Douglas-fir, maple, and red oak against decay above ground. Cross-brace and L-joint test units were treated just before assembly and exposed from 3-10 years. Untreated Douglas-fir cross-brace units were not decayed at either the Mississippi or Madison, WI, site. Untreated red oak cross-brace units were not deca...
T L Highley


Chemical investigation of 23-year-old CDDC treated southern yellow pine
1997 - IRG/WP 97-30141
The effect of 23 years exterior exposure on CDDC treated southern yellow pine was evaluated by the application of solid state analytical instrumentation. Analytical methods including environmental scanning electron microscopy (ESEM),energy dispersive X-ray analysis (EDXA), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), inductively coupled plasma (ICP) and atomic absorption spectr...
D P Kamdem, C R McIntyre


Mold inhibition on unseasoned southern pine
2003 - IRG/WP 03-10465
Concerns about indoor air quality due to mold growth have increased dramatically in the United States. In the absence of moisture management, fungicides need to be developed for indoor use to control mold establishment. An ideal fungicide for prevention of indoor mold growth on wood-based materials needs to specifically prevent spore germination and provide long-term protection under conditions of...
C A Clausen, V W Yang


A fixation model, based on the temperature dependence of CCA-C fixation
2000 - IRG/WP 00-40163
A model was prepared for the fixation of 1% CCA-C in red pine that allows the prediction of extent of fixation based on the temperature history of the treated wood following pressure treatment. The reaction kinetics of the rapid initial reaction and the slower main reaction were characterized using the Van t'Hoff equation. The initial reaction could be represented by a 10th order chemical...
P A Cooper, K M F Kazi, Jianbin Chen, Y T Ung


CCA fixation experiments. Part 2
1989 - IRG/WP 3505
CCA fixation in wood was measured by both squeezing solution from treated wood that had not been dried and analyzing the solution for copper, chromium and arsenic, as well as using a chromotropic acid test to detect the presence of chromium VI. Both methods provide useful information on the CCA fixation process and illustrate that chromium VI disappears as CCA becomes fixed within wood....
W S McNamara


Copper naphthenate-treated Southern Pine pole stubs in field exposure. -Part 2: Chemical characterization of full size pole stubs 12 years after treatment
2000 - IRG/WP 00-30246
This study examines the influence of pre-treatment and post-treatment steaming on the character and physio-chemical nature of copper naphthenate in hydrocarbon solvent treated pine in larger, pole diameter, pole stub-length samples. This work is the continuation of two projects that began almost a decade ago. Previous reports indicated that certain morphological changes might occur in small labora...
H M Barnes, D P Kamdem, M H Freeman


Protection of Ochroma pyramidale from fungal decay with N,N-napthaloylhyroxylamine
1998 - IRG/WP 98-30182
Fungal decay of wood in service results in billions of dollars (U.S.) in losses annually. Recent environmental restrictions, both U.S. and international, are limiting and eliminating the use of broad-spectrum, heavy metal biocides for wood preservation. Restrictions result primarily from problems with disposal. New wood preservatives need to be developed and tested which specifically target key el...
F Green III, T L Highley


Contribution of wood components on the absorption of copper amine
2000 - IRG/WP 00-30216
The contribution of wood components on the absorption of copper amine was investigated. Holocellulose, lignin and xylan absorbed significant amount of copper. The amount of copper absorbed by cellulose was almost negligible. The removal of extractive also decreased the amount of copper absorption. This study clearly indicates the importance of lignin, hemicellulose in the absorption of copper amin...
D P Kamdem, Jun Zhang


A method for determining boron diffusion coefficients in wood
1999 - IRG/WP 99-30200
The radial unsteady-state diffusion coefficient for boron in southern yellow pine (Pinus spp.) was determined from measured concentration profiles using Egner's solution, a modified form of Fick's second law. The method uses a slicing technique to accurately determine concentration gradients with time in a single direction. The methodology should be applicable to any diffusible s...
J-B Ra, H M Barnes


Oxalic acid production of fifteen brown-rot fungi in copper citrate- treated southern yellow pine
2001 - IRG/WP 01-10388
Non-arsenical copper-based wood preservatives have grown in number since the 1980's as a response to environmental concerns posed by arsenicals. Interest in copper tolerant decay fungi has increased accordingly. Oxalic acid (OA) production by brown-rot fungi has been proposed as one mechanism of copper tolerance. Fifteen brown-rot fungi representing the genera Postia, Wolfiporia, Serpula,...
F Green III, C A Clausen


Wood extractive concentration and sem examination of pretreated southern yellow pine wood chips with blue-stain fungi for mushroom production
2001 - IRG/WP 01-10407
Mushroom-producing white-rotting basidiomycetes either do not colonize or else colonize very poorly on freshly prepared southern yellow pine wood chips. This study evaluates the resinous extractive content of southern yellow pine before and after treatment with colorless mutant blue-stain fungi. The blue-stain fungi penetrate into the sapwood of southern yellow pine and utilize nonstructural resin...
S C Croan, J Haight


Innovations in the treatment of Southern pine heartwood
2000 - IRG/WP 00-40172
Whereas the sapwood of southern yellow pine (Pinus spp.) is readily treatable, the heartwood is essentially impermeable to preservatives such as chromated copper arsenate (CCA). Preliminary studies at the Mississippi Forest Products Laboratory indicate that increases in penetration and retention of preservative in pine heartwood can be obtained by subjecting kiln dried dimension stock to varying m...
M G Sanders, T L Amburgey, H M Barnes


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