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Leaching of CCA preservative from treated timber in marine environment
2001 - IRG/WP 01-30254
Knowledge on the amount of preservatives leaching out of treated wood is essential to optimise the chemical loading in various species of timber required for different end uses. In order to gain more insight into this aspect, the residual CCA content in 40 treated timber panels belonging to 14 species removed on destruction by marine organisms from a series of durability tests conducted in Kochi w...
M V Rao, V Kuppusamy, K S Rao, L N Santhakumaran


Leaching of CCA components from treated wood under acidic conditions
1993 - IRG/WP 93-50004
The leaching of CCA components from treated wood under acidic conditions were investigated. Western hemlock treated with three types of CCA and two levels of target retention was subjected to leaching at four different levels of pH. After leaching tests, leached samples were subjected to laboratory decay and soft rot tests. The amount of CCA components leached was dependent on acidity of leaching ...
Jae-Jin Kim, Gyu-Hyeok Kim


The course of fixation of Cu-Cr-As wood preservatives
1972 - IRG/WP 307
Copper-chrome-arsenic (CCA) preservatives in contact with wood result in an instant extensive increase of pH, because of ion-exchange and adsorption reactions with the wood. During precipitation of the active elements the pH continuously increases but reaches a maximum, when all chrome is consumed. Some of the early reaction products are unstable and slowly convert via dissolution into stable comp...
S-E Dahlgren


Chemical analyses of IRG/COIPM INTERNATIONAL MARINE TEST (to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water) samples
1987 - IRG/WP 4114
Chemical analysis of CCA and CCB treated timber was carried out after exposure at tropical and temperate marine sites. Results indicated that losses of all elements had occurred. In particular, losses of boron were severe. Arsenic and copper were also lost. The chromium components in both formulations was the most dominant metal remaining. The results suggest that chromium modification was importa...
L E Leightley


The effect of felling time of year on CCA fixation rate and quality of selected hardwoods
1998 - IRG/WP 98-40116
White birch (Betula papyrifera), poplar (Populus sp.) and red maple (Acer rubrum) trees were harvested in winter, in spring, before the leaves flushed, after leaf flush and later in the summer. Sapwood discs were cut from the freshly felled trees, dried and cut into 25 mm and 19 mm cubes. The cubes were pressure impregnated with CCA-C and fixed under high relative humidity and at 50°C or at room ...
Y T Ung, A Taylor, P A Cooper, D P Kamdem


Health hazards and environmental aspects when using Cu-HDO-containing wood preservatives in vacuum pressure plants
1993 - IRG/WP 93-50001-11
Apart from the biological efficacy of wood preservatives, the health and environmental aspects concerning the utilisation of wood preservatives, the use of treated timber and the disposal of impregnated wood are of high significance today. Therefore, information on a possible aerial concentration of wood preservatives, on the mobility of active substances in soil leached from treated timber in ser...
W Hettler, S Breyne, M Maier


Long-term protection of stored lumber against mould, stain, and specifically decay: A comparative field test of fungicidal formulations
1984 - IRG/WP 3281
The problem of decay in packaged, unseasoned lumber stored for many months has become of major importance in recent years. Large financial claims have resulted from decay in Canadian lumber stored at length in seaports and storage yards of distributors. For decades acceptable protection from moulds and sapstain was readily achieved with chlorinated phenols applied at appropriate treating levels. H...
A J Cserjesi, A Byrne, E L Johnson


A comparative study of CCA type C and B treated poles in service
1993 - IRG/WP 93-50001-05
CCA K33 type B and C treated utility poles, 9 pieces of each treatment type, were analyzed for preservative retention after 11 years in use. Borings were taking 1 m above and 0.3 m below the ground line. Also total amount of copper, chromium and arsenic was determined in soil surrounding the poles. The solubility of these active components in soil was monitored by using different leaching procedur...
A J Nurmi


The shower test method. A leaching test for assessing preservative losses from treated timber under simulated open storage conditions
1993 - IRG/WP 93-50001-04
In the late 1980's against the background of increasing environmental concern a laboratory based accelerated leaching test method for assessing preservative losses-from stored, treated timber was developed by the Dutch organisation for applied Scientific Research (TNO). This test method quantifies the amount of specific preservative components which leach from treated timber under simulat...
J B G A Havermans, W J Homan, M J Boonstra


Evaluation of the fire retardant efficacy and leach resistance of an amino resin fire retardant - Preliminary report
1983 - IRG/WP 3260
The Early Fire Hazard Indices of untreated Pinus radiata were determined by testing to Australian Standard 1530, Part 3 - 1976. Differences in the performance of heartwood and sapwood were noted, with heartwood samples giving higher Ignitability, Heat Evolved and Spread of Flame indices. The treatability of Pinus radiata with Pyrogard H was assessed, and backsawn sapwood treated more effectively t...
W D Gardner, P N Alexiou, P Lind, D Butler


Leachability And Decay Resistance of Copper-Treated Wood
2004 - IRG/WP 04-30337
Samples of scots pine sapwood (Pinus sylvestris L.) were treated with solutions of (Copper II sulfat-5 hydro + fluoroboric acid) and (Copper II sulfat-5 hydro + fluoroboric acid + boric acid) in order to determining to leachability and decay resistance against brown rot fungus (Postia placenta) and white rot fungus (Coriolus versicolor). Results indicated that the copper in treated wood is less s...
A Temiz, T Nilsson, I Deemirtas, Ü C Yildiz


Leaching results of shower test on L-joints with boric acid, bifluoride and TBTO rods
1995 - IRG/WP 95-50051
As part of the EC-project "Improvement of a local preservation process for wood products with reduced environmental impact", TNO has performed a leaching test on L-joints treated with pills with boric acid (Defence corner), bifluorides (Woodpil 55) and TBTO (Woodcap). The L-joints were exposed in an adapted shower test during 10 days, using 70 liters of water per day. The experiment is designed to...
P Esser, M J Boonstra, W L D Suitela, A J Pendlebury


Albumin borate: A new non-toxic, wide-spectrum, long-term wood preservative
1998 - IRG/WP 98-30167
Boron, widely recognized for its broad range of activity towards both fungi and insects and for its low mammalian toxicity, can not provide long term protection to treated timber due to its high leachability. Boron, in the form of boric acid, can be partially fixed to timber by the formation of an association with egg albumin, which is insolubilized by heat-induced coagulation. Chemical investiga...
M-F Thévenon, A Pizzi, J-P Haluk


Effect of vegetable compost on leaching of CCA components from treated wood - An Update
1995 - IRG/WP 95-50048
In an earlier study, the effect of compost on CCA-C leaching was compared with leaching losses under different exposure conditions. Small treated cubes (25 mm³) were destructively sampled over a 12 month period and the residual CCA determined for exposure to compost in a compost bin, exposed to natural rain and buried in soil. This study provides a comparison after 3 years of samples exposed to c...
P A Cooper, Y T Ung


Leaching Characteristics of Copper in Copper Treated Wood
2003 - IRG/WP 03-30316
The leaching characteristics of copper in copper treated bamboo and other wood species such as slash pine and poplar has been conducted in this paper according to AWPA M11-87 standard, the result indicates that: --Copper fixation rate of salts from organic acids such as citrate and oxalate and malate is less than other non-organic acid formulations. --Copper fixation rate of oven-dried bamboo sa...
Mingliang Jiang, Junliang Liu, Daochun Qin, Yamei Wang, Zehui Jiang


Leaching and fixation characteristics of chrome-copper-fluoride-zinc (CCFZ) treated wood
1996 - IRG/WP 96-30096
The leaching characteristics of radiata pine sapwood blocks treated with CCFZ were evaluated by the AWPA standard leaching test. The rate of fixation of the preservative components in CCFZ treated radiata pine were also evaluated by quantitative analysis of solution expressed from the treated wood. Both leaching and fixation characteristics of CCFZ were compared with CCA-Type C treated wood sample...
Gyu-Hyeok Kim, Jong-Bum Ra


Applications of the shower test. Part B: Results from CC and CCB treated wood: influence of fixation process
1993 - IRG/WP 93-50010
This report outlines the results of shower tests conducted on CC and CCB treated wood. The results indicate the fairly good fixation of chromium and the reasonable fixation of copper in CC and CCB formulations, as judged by the leaching limits within the Environmental Regulations. In general boron leaches to a higher extent than chromium and copper. The shower test has proven to be a useful qualit...
W J Homan, H Militz


Effect of soil parameters on biocide depletion: laboratory and field studies of water- and emulsion-borne preservatives
2000 - IRG/WP 00-30234
Two field test sites with different soils were selected. Soil analysis showed that the soil at the two sites had considerable texture, base saturation, acidity, and cation exchange capacity differences. Five sets of field stakes were treated as follows: three with water-borne CCA to about 0.4 pcf (6.4 kgm-3) retention, one with 0.75% DDAC, and one with 0.75% DDAC:0.25% chlorothalonil. The last two...
T Schultz, D D Nicholas, D E Pettry, M G Kim


Moisture uptake and volumetric swelling as probable factors also affecting leaching in CCA-treated wood. A preliminary study of treated Eucalyptus saligna sapwood
2003 - IRG/WP 03-30318 IRG/WP 03-30318
A number of factors affecting leaching of CCA from treated wood have been variously investigated and discussed. However, the possible effects of moisture movement in treated timbers on leaching have not received attention yet. The present study examines and compares moisture uptake and volumetric swelling in CCA-treated and untreated sapwood of Eucalyptus saligna, and tries to establish a correl...
R Venkatasamy


Susceptibility of CCB treated wood to fungal colonization
2003 - IRG/WP 03-10492
CCB treated wood is generally resistant to all wood decay fungi. However, like CCA impregnated wood, susceptibility of CCB treated wood to copper tolerant fungi have been observed. The ability of various brown rot fungal hyphae to penetrate and overgrow the wood samples was investigated. Samples made of Norway spruce (Picea abies) were impregnated with 5 % CCB solution according to the EN 113 proc...
F Pohleven, U Andoljsek, P Karabegovic, C Tavzes, S A Amartey, M Humar


Fixation and leaching of selected Malaysian tropical hardwood after treated with CCA
2001 - IRG/WP 01-40207
The objective of this study is to investigate the fixation and leaching properties of selected Malaysian tropical hardwood (sentang wood (sapwood and heartwood) and rubberwood) after being treated with copper chrome arsenate (CCA) type-C preservative. The samples were treated with retention level of 0.5%, 2.0% and 5.0%. The samples were leached and the leachate were analyzed by AAS and the amount ...
R Hashim, O Sulaiman, Tan Siew Ching, K Yamamoto


Leaching of Arsenic from Mulch Made from Recycled Construction and Demolition Wood
2005 - IRG/WP 05-50232
Mulch made from recycled construction and demolition (C&D) wood has been reported to contain chromated copper arsenate (CCA)-treated wood and potentially release arsenic in the leachate by rainfall. Such recycled wood mulch is commonly masked with iron-oxide colorant, which is known to combine with arsenic. The objective of this study was to evaluate the levels of arsenic leaching from C&...
T Shibata, H M Solo-Gabriele, T G Townsend, B Dubey


The new National Directive on wood preservation in the Netherlands
1998 - IRG/WP 98-50101-03
In the Netherlands the major part of treated timber is sold under the KOMO-certificate. The National Directive for vacuum pressure treated timber on which certification is based, is currently being revised. The new National Directive will contain a code of good practice including maximum leaching figures. It incorporates quality requirements for treated timber, existing legislative requirements an...
W J Homan, J K B Kwisthout, J Dubelaar


Copper leaching from Kemwood ACQ and Embalit CBC treated wood products
2000 - IRG/WP 00-50150
TNO has performed a study on the leaching of copper from Kemwood ACQ and Embalit CBC treated wood products, further referred to as ACQ and CBC. The sawn dry wood has been impregnated using an industrial vacuum-pressure process with ACQ (with or without Ultrawood 4) or with CBC, under supervision of Flexchemie B.V. After treatment samples have been transported and subjected to leaching tests at TNO...
P Esser, W L D Suitela, H Trompetter


Effectiveness of CCA fixation to avoid hexavalent chromium leaching
2002 - IRG/WP 02-50187
It is generally assumed that hexavalent chromium in chromated copper arsenate wood preservative is substantially reduced to trivalent chromium during fixation and that the potential to leach the more toxic CrVI is minimal. However, there are occasional claims some hexavalent chromium remains in wood after fixation and that small amounts of CrVI are available for leaching. One problem is that ot...
P A Cooper, D Jeremic, Y T Ung


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