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Danish wood preservatives approval system with special focus on assessment of the environmental risks associated with industrial wood preservatives
2001 - IRG/WP 01-50166-01
The following is a description of the procedure used by the Danish Environmental Protection Agency to assess the environmental risks associated with preservatives used in the pressure impregnation of wood. The risk assessment covers issues considered to be of significance for the environment and which are adequately documented so as to allow an assessment. Such issues are persistence and mobility ...
J Larsen


Laboratory investigations about the mobility of some inorganic wood preservatives in soils
1998 - IRG/WP 98-50101-22
Wood preservatives and components of wood preservatives leached from impregnated wood can enter the soil and thus contribute to the pollution of the groundwater. However, there is lack of understanding concerning the interacting parameters of wood preservative, leachate, soil and soil solution. To characterise of the behaviour of active ingredients and for the assessment of their environmental imp...
E Melcher, R-D Peek


Detection of trace organics by ion mobility spectrometry
1990 - IRG/WP 3635
Ion Mobility Spectrometry (IMS) is a time of flight analytical technique that is suited to detect chemicals in the low parts per billion range. Some of the advantages of IMS are: operation at atmospheric pressure, fast response time (0.1-10 sec), and the ability to characterize individual chemical species in complex matrices without any prior sample preparation. In this paper, the utility of IMS i...
A H Lawrence


Detection of brown rot decay in wood by ion mobility spectrometry
1991 - IRG/WP 2377
A test method for the detection of brown rot decay in wood is described and involves a two-step procedure: thermal release of vapours from wood samples followed by analysis using Ion Mobility Spectrometry (IMS), with results being obtained in 5-10 seconds. The advantages, limitations as well as the detection limit of the technique are presented....
A H Lawrence, T Nilsson


Health hazards and environmental aspects when using Cu-HDO-containing wood preservatives in vacuum pressure plants
1993 - IRG/WP 93-50001-11
Apart from the biological efficacy of wood preservatives, the health and environmental aspects concerning the utilisation of wood preservatives, the use of treated timber and the disposal of impregnated wood are of high significance today. Therefore, information on a possible aerial concentration of wood preservatives, on the mobility of active substances in soil leached from treated timber in ser...
W Hettler, S Breyne, M Maier


An investigation into the influence of soil cation exchange capacity on preservative component depletion
1994 - IRG/WP 94-20050
The mobility of preservative components from treated wood into the soil environment is regarded as an important determinant of preservative performance. Standard procedures for the investigation of this phenomenon have not been developed to any great extent. Soil bed studies conducted in this laboratory using natural soil and modified soil media have provided interesting comparative data on the in...
K J Archer, L Jin


An evaluation of the potential of ion mobility spectrometry for detection of organic wood preservative components in solutions and treated wood
1994 - IRG/WP 94-20038
For the disposal of wood waste under ecological sound conditions information about its hazardous potential is required. Until now, no highly sensitive rapid analytical methods are available for the detection of wood preservatives under industrial process conditions. Preliminary experiments showed that Ion Mobility Spectrometry (IMS) could be a promising method for rapid detection of organic preser...
A Voss, J N R Ruddick, W J Homan, H Militz, H Willeitner


Studies on the mobility of arsenic, copper and chromium in CCA-contaminated soil
1990 - IRG/WP 3571
CCA contaminated soils from six Swedish preservation plants were investigated primarily to study the mobility of arsenic but also that of copper and chromium in the soils. The soil samples represented average types with different amounts of clay, organic matter, arsenic, copper, chromium and different pH. The total soluble amounts of the elements were measured. The pH dependent solubility and the ...
J Bergholm


Surface accumulation of copper on CCA-impregnated Pinus patula stakes during marine preservative trials in the southern hemisphere
1992 - IRG/WP 92-4181
Pinus patula stakes treated with CCA to target retentions of 30 kg/m³ salts were exposed to sea water in marine and estuarine ecosystems off the coast of Southern Africa for two years. Samples were then analysed for copper and arsenic. Analysis of samples from the marine ecosystem showed (IRG/WP/4167) that arsenic was longitudinally and transversely leached from the wood, whereas the copper was r...
G D Shelver, C D McQuaid, M Tarin, A A W Baecker


Leaching of preservative components from pine decking treated with CCA and copper azole, and interactions of leachates with soils
2001 - IRG/WP 01-50171
Radiata pine decking was treated with CCA and copper azole preservatives to Australian H3 retention using conventional and modified Bethel schedules, and air-dried. Treated decking boards and durable hardwood controls were subjected to leaching in weather-exposed decks, and matching 19mm cubes were leached in extended AWPA E11-97 lab tests. Deck runoff and E11 leachate water was analysed after rai...
M J Kennedy, P A Collins


Mobility of zinc borate wood composite preservative
1997 - IRG/WP 97-30153
Zinc borate (ZB) is being used as an antifungal and insecticidal wood preservative for flake/strand-based composites. Data is reported on the laboratory and field leaching behavior of ZB when contained in apen flake composites. In general, the performance results correlate with leaching hazard. Although the boron in ZB is more resistant to depletion than in sodium borates, the ZB boron will deplet...
P E Laks, M J Manning


Mobility and bioavailability of wood preservation chemicals in soil - actual field measurements
1998 - IRG/WP 98-50101-11
Wood material intended for outdoor use is often impregnated with chemicals to withstand attack from fungi and bacteria. Both inorganic and organic substances are used to protect the wood, and they are used in a toxic and bioavailable form. At wood preservation facilities severe soil contamination can be encountered due to spills and deposition of sludge, especially at old sites. Two sites, one whe...
S Andersen, G Rasmussen


The content and mobility of copper, chromium and arsenic in the soil of a wood preserving plant using CCA
1998 - IRG/WP 98-50122
Analyses were carried out on soil and water samples obtained from a wood preserving plant using CCA-type preservatives. The plant has been in operation since 1969. The soil samples were obtained on 8 points from 4 different depths. The estimation of the type of soil was followed by investigations of copper, chromium and arsenic contents, and the mobility of these elements. The soil samples were al...
N Erdin, S N Kartal, A Dilek Dogu, M O Engür


Quantification of methylene bis thiocyanate in wood and its effect on a sapstain fungus Ophiostoma floccosum
2006 - IRG/WP 06-10591
The mobility and concentrations of MBT at different depths of wood billets (200 mm long, 40 mm in diameter) were determined using NMR spectroscopy and ICP-ASE, and then correlated the effect of wood MBT concentrations on growth of O. floccosum in a bioassay using stereomicroscopy and confocal laser scanning microscopy (CLSM). The 13C NMR spectra showed the presence or absence of MBT in wood but w...
T Singh


Kd values of Cu, Cr, As in different soil matrix
2007 - IRG/WP 07-50247
Chromated copper arsenate (CCA), a long history of successful preservative, have raised environmental concerns. Adsorption characteristics of domestic soils for chromium, copper, and arsenic were assessed by measuring distribution coefficient (Kd) values of these metal components. The results revealed that Kd values were higher in chromium, followed by arsenic and copper in soil matrix. Different...
Sung-Mo Kang, Seung-Hun Shin, Ja-Oon Koo


Alkaline copper treated wood for use in residential decking
2008 - IRG/WP 08-30490
Alkaline copper quaternary ammonium compound (ACQ) treated decking was exposed in a field experiment and the mobile copper assessed based on that collected in the leachate. The amount of copper which leached was modeled after 4 years. The results showed that boards which leached most chemical initially provided the greatest loss over four years. The reduction in the mobility of copper with time wa...
J N R Ruddick


Mobility of Copper from MCQ in Shell-Treated Wood Exposed Above Ground
2010 - IRG/WP 10-30534
Most Canadian treated decking in service has been given just a thin shell of preservative treatment but it has still performed very well. This is because copper migrated into checks and prevented germination of basidiospores on the freshly exposed untreated wood. Unlike soluble copper systems, MCQ has its copper primarily in the form of small basic copper carbonate particles. For MCQ to be effecti...
R Stirling, P I Morris


Limiting Polysaccharide Motion Protects Wood From Decay
2020 - IRG/WP 20-40890
It is well known that chemical modifications to improve decay resistance also reduce the equilibrium moisture content (EMC) of wood. The mechanism of this action, however, has been the subject of much debate. Several groups have suggested that decay resistance is a result of lower diffusion rates of fungal degradation agents through the wood cell wall. A recent paper explained the fundamental prin...
C G Hunt, S L Zelinka, J E Jakes


Application of suberin fatty acids extracted from birch bark for wood coating
2021 - IRG/WP 21-40914
It is well known that chemical modifications to improve decay resistance also reduce the equilibrium moisture content (EMC) of wood. The mechanism of this action, however, has been the subject of much debate. Several groups have suggested that decay resistance is a result of lower diffusion rates of fungal degradation agents through the wood cell wall. A recent paper explained the fundamental prin...
A Kumar, Risto Korpinen, Veikko Möttönen