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Leaching and fixation characteristics of chrome-copper-fluoride-zinc (CCFZ) treated wood
1996 - IRG/WP 96-30096
The leaching characteristics of radiata pine sapwood blocks treated with CCFZ were evaluated by the AWPA standard leaching test. The rate of fixation of the preservative components in CCFZ treated radiata pine were also evaluated by quantitative analysis of solution expressed from the treated wood. Both leaching and fixation characteristics of CCFZ were compared with CCA-Type C treated wood sample...
Gyu-Hyeok Kim, Jong-Bum Ra


Corrosion of zinc-coated nails used with preservative-treated western red cedar shakes in service
1982 - IRG/WP 3197
The corrosion of metal fasteners used with certain wood species and with preservative-treated woods can be a serious problem. The chemical reactivity of western red cedar (Thuja plicata Donn) extractives to iron and copper is well documented and wood preservative treatments containing copper, chromium, and/or ammonium hydroxide can be expected to similarly attack some metals. This problem is compo...
R S Smith, E L Johnson, A J Cserjesi


Assessment of the toxicity of some copper-, zinc- and boron-based wood preservatives to the cellar fungus Coniophora cerebella Schröet
1974 - IRG/WP 242
This article reports the use of a method based on the determination of the probability of the protection of timber against destruction by fungi. By converting the probability values to probit values and plotting them as a function of the amount of preservative retained in the timber, curves of the toxic effect are obtained, enabling any timber protection probability to be assessed....
V N Sozonova, D A Belenkov


Preservative treatments of window components with a water-based borate formulation
2000 - IRG/WP 00-40171
Factory finished window joinery components were treated with an aqueous borate preservative in order to investigate penetration and retention levels, associated drying times; and the potential impact of using a water-based treatment on finished items. It was found that by using borates applied by light double vacuum schedules, it was possible to meet standards for penetration and retention, to air...
J Jermer, J D Lloyd


Wood protection by surface treatment of two borate preservatives, TIM-BOR® and BORA-CARE®, for the formosan subterranean termite and eastern subterrean termite
1993 - IRG/WP 93-10044
TIM-BOR® (disodium octaborate tetrahydrate: DOT, Na2B8O134H2O) and BORA-CARE® (40% DOT in ethylene glycol) are two borate products marketed for treating wood in use by brushing or spraying onto the wood surface. The active ingredients presumably diffuse into wood by the 10-15% existing wood moisture. Few data, however, are available to demonstrate the diffusion rate. Su & Scheffrahn (1991) s...
M Toroko, N-Y Su


Laboratory evaluation of borate formulations as wood preservatves to control the subterranean termite coptotermes acinaciformis (isoptera: Rhinotermitidae) in Australia
2001 - IRG/WP 01-30266
The termiticidal efficacy of Borocol (sodium octaborate tetrahydrate), boric acid, bore-ester-7 and tri- methyl borate was evaluated in laboratory bioassays against Coptotermes acinaciformis (Froggatt). Seasoned sapwood blocks of Pinus radiata D. Don, and Eucalyptus regnans (F. Muell) were impregnated with the various borate compounds. There were marked differences in mass loss and mortality rate ...
B M Ahmed, J R J French, P Vinden


Evaluating the natural durability of native and tropical wood species against Reticulitermes flavip
2004 - IRG/WP 04-10539
Environmental pressures to eliminate arsenate from wood preservatives has resulted in voluntary removal of CCA for residential applications in the United States. A new generation of copper organic preservatives has been formulated to replace CCA for decking and in-ground applications but there is no guarantee that these preservatives represent a permanent solution to all related problems. There...
R A Arango, F Green III, K Hintz, R B Miller


Laboratory evaluation of metallic naphthenates as wood preservatives
1991 - IRG/WP 3654
Fungicidal and termiticidal efficacy of copper and zinc naphthenates was appraised according to Japanese standardized laboratory testing methods. Copper and zinc naphthenates succeeded in protecting wood from decay fungi at retentions of 0.5 and 1.0 kg/m³ as metal, respectively. [JIS A 9302 (1976)] when they were applied to vacuum/soak impregnation [JIS A 9301 (1976)]. With respect to the fungici...
K Tsunoda, M Sakurai


Long-term efficacy of wood dip-treated with multicomponent biocides
2005 - IRG/WP 05-30379
Biocides designed for prevention of indoor mold growth on wood-based materials need to provide long-term protection under conditions of high humidity. Specimens of kiln-dried southern pine and unseasoned southern pine, aspen, and Douglas-fir were dip-treated with borate-dimethylcocoamine (DMCA) supplemented with voriconazole, thiabendazole, or thujaplicin and evaluated at 4-week intervals for inhi...
C A Clausen, V W Yang


Comparison of the effects of borate, germanate and tellurate on fungal growth and wood decay
1992 - IRG/WP 92-1533
The tetra-hydroxy borate ion is known to undergo complexation with polyols and has been shown to inhibit dehydrogenase enzymes in this way. It has been previously suggested that this complexation is responsible for the inhibition of fungal growth and the protection of boron treated timber. Other ions that have the ability to complex with polyols have also been shown to inhibit dehydrogenase activi...
J D Lloyd, D J Dickinson


A chemical and mycological evaluation of fused borate rods and a borate/glycol solution for remedial treatment of window joinery
1983 - IRG/WP 3225
The possibility of using fused borate rods (Impel Borpatron) and a borate/glycol solution (Boracol-40) for depot impregnation of window joinery has been examined in a co-operative project between The Swedish Forest Products Research Laboratory, The Swedish University of Agricultural Sciences and Prolignum AB. The fused Impel rod is a glassy rod composed of disodium octaborate which readily dissolv...
M-L Edlund, B Henningsson, A Käärik, P-E Dickèr


Chemical evaluation of borate treated pine sapwood attacked by the subterranean termite Coptotermes acinaciformis
1993 - IRG/WP 93-20003
Sapwood of hoop (Araucaria cunninghamii Ait. ex D. Don) and slash (Pinus elliottii Englem.) pines were treated by Vacuum Pressure Impregnation (VPI) to provide test specimens. The concentration of boron was defined by chemical analyses of the timber, in the zone of primary attack by the termite being bioassayed. A common method of definition of preservative retention, weight uptake of preservative...
A R Moffat, B C Peters


Interim report on the use of borate rods for the in-situ treatment of joinery
1980 - IRG/WP 3159
In the U.K. in recent years, it has been recognised that there is a major need for in-situ treatment of joinery at risk from or showing the early signs of decay. Several techniques have been developed to provide such a treatment, one of which is based on the insertion of anhydrous borate glass rods. The tests in hand are long term and this report is confined to the mycological isolation data from ...
D J Dickinson


L-joint trials: Part 3: Relative performance of a range of preservative products
2002 - IRG/WP 02-30292
Long-term trials using the L-joints described in BS EN 330 and AWPA Standard E9-97 have been in progress at BRE since 1982. This paper records the current assessments of decay of L-joints in trials started between 1982 and 1994 with treatments applied to both Scots pine sapwood (Pinus sylvestris) and spruce (Picea sp.). Data are provided on a range of active ingredients including TnBTO, PCP, a...
J K Carey


Remedial ground-line treatment of CCA poles in service. Results of chemical and microbiological analyses 6 months after treatment
1986 - IRG/WP 3388
CCA-treated poles in service with incipient internal soft rot were remedially treated by inserting borate rods, brushing with a boron/glycol solution and injecting boric acid paste, copper/creosote paste or a commercial product (DFCK paste). The spread of active chemicals in the treated zone as well as the change in microflora have been studied with time. After six months chemicals had spread to m...
B Henningsson, H Friis-Hansen, A Käärik, M-L Edlund


Tendency of the preservative use for impregnation industries in Japan
1998 - IRG/WP 98-50101-05
In Japan, since 1997, the acceptable limit of the arsenic in the waste water become to 0,1 mg/l and the additional regional severer restriction can be established. In this reason, Japanese wood preservation industries intend to use other than CCA, like DDAC, ACQ, Tanalith CuAz, copper-naphthate and zinc-naphthenate, as replacing from CCA. In Jan-June 1997, the share of CCA preservatives was less t...
K Suzuki


Field performance of novel antisapstain formulations
1997 - IRG/WP 97-30125
The effectiveness as antisapstain formulations of combinations of oxine copper (Cu-8), carbendazim, hexaconazole, cyproconazole, flusilazole, didecyldimethyl ammonium chloride (DDAC), an alkanolamine borate (SB), benzalkonium chloride (BAC), 2-n-octylisothiazolin -3-one (isothiazoline) and p-chlorophenyl-3-iodopropagilformal (CPIPF) was determined for freshly sawn, block-stacked radiata pine in th...
D R Eden, R N Wakeling, C M Chittenden, J G Van der Waals


Borate diffusion in wood from rods and liquid product. Application to laminated beams
1988 - IRG/WP 3482
In the aim to use borate preservatives (fused rods and boracol) in fields of building construction other than external joineries, tests of diffusion of borate rods and secondary boracol, were carried out on different species of woods exposed to different moisture conditions. Tests were also applied on laminated beams very often subjected to high moisture contents and thus decay of rot fungi. Diffu...
D Dirol


Performance of borate-treated sill plates (dodai) in a protected, above-ground field test in Japan
2002 - IRG/WP 02-30278
This document is supplemental to the previous IRG document (IRG/WP 2000-30239). An experiment to simulate the dodai (sill plate) of the Japanese houses was conducted at the termite field test site of the Wood Research Institute in Kagoshima, Japan where two economically important subterranean termite species [Coptotermes formosanus Shiraki and Reticulitermes speratus (Kolbe)] are established. DOT...
K Tsunoda, A Adachi, A Byrne, P I Morris, J K Grace


New boron-based biocides for the protection of wood
2002 - IRG/WP 02-30283
Boric acid and other simple inorganic oxides of boron are amongst the oldest wood preservatives currently in use. Their relatively low toxicity and broad-spectrum activity are just some of their desirable characteristics. The primary disadvantage associated with conventional boron-based preservatives is their lack of permanence in exposed applications. A collaborative project between CSIRO and the...
D G Humphrey, P J Duggan, E M Tyndall, J M Carr, L J Cookson


Corrosion of fasteners in treated wood
1971 - IRG/WP 303
Surveying tests for determining the corrosion rates of some metals and alloys in wood untreated as well as treated have been made. It is shown that ordinary steel corrodes faster than other common fastener metals such as copper, brass, aluminium and stainless steel do. Zinc coatings, however, will prevent the steel corrosion effectively provided that the coatings are thick sufficiently. Catalytic ...
T Wallin


The effect of pretreatments on the impregnation of air-dried sawn Belgian spruce
1988 - IRG/WP 3490
In general the impregnation of airdried spruce results in a variable treatment and limited penetration. This is the result of pit aspiration that occurs during drying of the spruce sapwood and heartwood. Spruce timber is becoming of greater importance in Belgium and hence research for better treatment of this vulnerable wood species is needed. Squared airdried timber of different dimensions were e...
J Van Acker, M Stevens


Borate-treated food affects survival, vitamin B12 content, and digestive processes of subterranean termites
1990 - IRG/WP 1448
Toxicity of boron compounds was studied by analyzing survival rates and vitamin B12 contents in Formosan subterranean termites, Coptotermes formosanus Shiraki, that were exposed to dietary treatments for 10 days. The dietary treatments applied in moistened cellulose were (a) 0.05% boric acid equivalent (BAE) of disodium octaborate tetrahydrate, (b) 0.05% BAE of anmonium pentaborate plus sodium sul...
L H Williams, S I Sallay, J A Breznak


Performance of Paraserianthus falcataria treated with ACZA, ACQ, CC or CCA and exposed in Krishnapatnam harbour, India
2005 - IRG/WP 05-30382
Paraserianthus falcataria (=Albizia falcataria) treated to two retentions with ammoniacal copper zinc arsenate (ACZA), ammoniacal copper quaternary (ACQ), ammoniacal copper citrate (CC) and chromated copper arsenate (CCA) was assessed over 34 months in a tropical marine waters at Krishnapatnam harbour on the east coast of India. ACZA treatment showed comparatively better resistance than CCA, ACQ a...
B Tarakanadha, K S Rao, J J Morrell


Prevention of Termite Tubing Over Non-Wood Construction Materials Using Glycol Borate
2004 - IRG/WP 04-30358
Glycol borates have been demonstrated to prevent termite tubing and attack of wood materials and are extensively used as termite preventative applications in new construction in the USA. This study evaluated the ability of such systems to prevent Formosan subterranean termite tubing over non-wood materials. Concrete was selected as a common inert construction material and tests were carried out ...
W R Smith, J D Lloyd


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