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Durability of heat-treated wood
1999 - IRG/WP 99-40145
Heat-treated wood from the French process were laboratory tested against decay using agar block test and a modified soil block test. Water absorption, bending strength, lignin content and acid number were also determined to evaluate the effect of heat treatment. Heat treated samples exhibit a higher lignin content and a lower acid number compared to untreated control indicating the degradation of ...
D P Kamdem, A Pizzi, R Guyonnet, A Jermannaud


Leachability of didecyldimethylammonium chloride (a quaternary ammonium compound) from four wood species
1982 - IRG/WP 3204
Sapwood blocks prepared from red pine, ponderosa pine, southern yellow pine and hem-fir (a commercial mixture of western hemlock and amabilis fir) were treated with didecyldimethylammonium chloride, (an alkylammonium compound, AAC). After oven drying the blocks were vacuum impregnated with distilled water and subjected to a static leach cycle for 48 hours. The leachate was analyzed and the amount ...
J N R Ruddick, A R H Sam


Natural durability transfer from sawmill residues of white cypress (Callitris glaucophylla). - Part 1: Optimisation of the extraction conditions
2000 - IRG/WP 00-30238
As the first phase of a large project aimed at recovering 'waste' durability components from sawmill residues of Callitris glaucophylla, several solvents and extraction methods were evaluated, initially in the laboratory and then at pilot industrial scale. Extracts were compared by crude total dissolved solids content, by chemical analysis using GC-MS and LC-MS, and by laboratory...
M J Kennedy, Hui Jiang, L M Stephens


Alternative technologies for wood wastes recycling - Part A: Supercritical extraction of PAH compounds from wood wastes
1998 - IRG/WP 98-50101-18 a
Alternative technologies have been investigated to detoxify treated wood. Two classes of organic compounds are studied. Creosote-treated wood are classified in France as dangerous wood wastes. A conventional incineration could be provided for these wood wastes but the cost of this elimination could be very high (> 2000 FFR/ton). For these reasons, we have tested two kinds of new processes as al...
L Schrive, C Perre, G Labat


Semi-Solid State Bioremediation of CCA-Treated Wood Using Malted Barley as a Nutrient Source
2002 - IRG/WP 02-50184
Bioremediation processes for recovery and reuse of CCA-treated wood invariably increase the cost of any secondary products manufactured from the remediated fiber. Microbial remediation using either bacteria or fungi has been shown to remove heavy metals from CCA-treated southern yellow pine (SYP). In a two-step remediation process utilizing oxalic acid extraction and the metal-tolerant bacterium...
C A Clausen


The Effect on Biological and Moisture Resistance of Epichlorohydrin Chemically Modified Wood
2002 - IRG/WP 02-40224
Southern pine solid wood and fiber were chemically modified with epichlorohydrin to help in understanding the role of moisture in the mechanism of biological effectiveness of chemically modified wood. The solid wood had weight gains from 11% to 34%, while the fiber had weight gains from 9% to 75%. After modification, part of the specimens were water leached for 2 weeks or extracted for 2 hours ...
R E Ibach, B-G Lee


Assessing the bioresistance conferred to solid wood by chemical modification
1997 - IRG/WP 97-40099
The chemical modification of wood using straight chain alkyl anhydrides can considerably enhance its durability. This paper presents an assessment of the effectiveness of these modifiers in improving the biological resistance of a susceptible softwood when exposed to four different basidiomycete fungi, soft rots and the larvae of the house longhorn beetle (Hylotrupes bajulus). It was clear that so...
E D Suttie, C A S Hill, D Jones, R J Orsler


Solid state NMR study on pine wood degraded by brown rot fungus Gloeophyllum trabeum
1994 - IRG/WP 94-10067
Blocks of Pinus koraiensis wood were degraded by Gloeophyllum trabeum and examined by solid-state 13C NMR spectroscopy. Chemical compositions were estimated from relative signal aras. There was no evidence for preferential degradation of the noncrystalline cellulose which accounted for about 4% by weight of the wood. Loss of partly ordered cellulose on crystal surfaces exceeded the loss of crystal...
Yoon Soo Kim, R Newman


Recovery of copper, chromium, and arsenic compounds from the waste preservative-treated wood
1991 - IRG/WP 3651
In Japan, about 40 percents of waste wood is incinerated and the residue is dumped into the landfill site. The waste preservative-treated wood, which is mixed in nontreated wood, is incinerated in the same way, too. However, it will cause the serious problems that the gases contained with high concentration arsenic compounds are discharged from the smokestacks of the incineration facilities and th...
A Honda, Y Kanjo, A Kimoto, K Koshii, S Kashiwazaki


The multi-phase pressure (MPP) process. One-stage CCA treatment and accelerated fixation process - The process as a new concept in preservative treatment
1997 - IRG/WP 97-40078
The background to current commercial CCA treatment schedules used in New Zealand and fixation processing is reviewed. The limitations of these conventional practices with respect to treated product quality and CCA solution handling issues are defined. A novel, patented treatment schedule has been developed using a combination of hydraulic and pneumatic pressure phases and hot (~ 75°C) CCA solutio...
K Nasheri, A J Pendlebury, J A Drysdale, H Pearson, M E Hedley


Aureobasidium or Hormonema? A Genetic Approach.
2004 - IRG/WP 04-10529
Aureobasidium pullulans is the main organism causing disfigurement of coatings on wood and the surface of exposed timber. This disfigurement of timber in-service is referred to as “bluestain in-service”. A. pullulans is also associated with the sapstaining of dead wood in the forest and in-service. A. pullulans is noted for its highly variable growth forms (polymorphisms). This variability pre...
M J Ray, D J Dickinson, M Buck


Restrictions on the use of chlorosilanes as potential wood preservatives
1985 - IRG/WP 3345
The biological protection of wood by chemical modification with different types of chlorosilanes has been investigated. The impregnation of wood has been carried out by means of liquid phase and vapor phase treatments using pure silane and silane-solvent systems. The biological efficacy against wood rotting fungi, molds and staining fungi was determined in a number of screening trials, subsequentl...
M Stevens


A comparison of analytical techniques
1995 - IRG/WP 95-20061
This paper compares carefully-controlled weight retentions and analysis by XRF, ICP, combustion methods and a new extraction procedure for the new preservative, Copper(II) Dimethyldithiocarbamate (CDDC). Various experimental parameters such as particle size and drying conditions were investigated. In general, the correlations between and among the procedures are very high. The extraction-colorimet...
A C Gallacher, C R McIntyre, M H Freeman, D K Stokes, W B Smith


Investigation of CCA fixation in wood by sequential extraction. I Determination of CCA component fixation and preliminary extraction results
2002 - IRG/WP 02-50188
The fixation of CCA-C preservative was investigated in sapwood of red pine (Pinus resinosa Ait.), trembling aspen (Populus tremuloides Michx.) and red maple (Populus tremuloides Michx.) at target retentions of 4.0, 6.4, 9.6 and 30.0 kg/m3. Treated wood sawdust was water extracted at close time intervals during the fixation and analyzed for the contents of unfixed hexavalent chromium, total Cr, Cu ...
S Radivojevic, P A Cooper


A comparison of the diffusion of boron from two types of solid preservative rods into the heartwood of 3 Eucalypt pole species
2000 - IRG/WP 00-30227
The ability of boron to diffuse from polyborate and boron/fluoride rods through the heartwood of three eucalypt pole species (blackbutt, red ironbark and spotted gum) was examined. The aim was simply to determine the effects of rod type, wood species and time on the longitudinal diffusion of boron in eucalypt heartwood. Rapid diffusion of boron from polyborate or boron/fluoride preservative rods o...
P J Beutel, P D Evans


Anti-fungal properties of pyrolytic oils derived from softwood bark
2000 - IRG/WP 00-30218
Thermal decomposition of balsam fir and white spruce mixed bark residues at 450°C and under vacuum (< 20 kPa abs.) results in high yields of pyroligneous liquors rich in phenolic content. This vacuum pyrolysis process has been scaled-up to a pyrolysis plant with a feed capacity of 3.5 t/h of softwood bark, which is the largest plant of this type in the world. The pyrolytic aqueous condensates ...
D Mourant, Dian-Qing Yang, Xiao Lu, C Roy


Modification of solid wood: research and practical potential
1997 - IRG/WP 97-40098
The polymeric structure of the wooden cellwall mainly consists cellulose, hemicellulose and lignin. The most reactive sites on these components are the hydroxyl groups. The cellwall polymers (and its reactive hydroxyl groups) are responsible for most physical and chemical properties of wood. By changing the basic chemistry of the cellwall polymers, it is possible to change different undesirable at...
H Militz, E P J Beckers, W J Homan


Proposal for a method aiming at the quantification of the impact of wood extraction in Life Cycle Assessment
1998 - IRG/WP 98-50113
Life Cycle Assessment has been accepted as an instrument for the assessment of the environmental impact of products. Characterisation factors for impact assessment of emissions from products have been established. To date no characterisation factor exists for the extraction of biotic resources, for example wood. Since the main disadvantage of using wood as a material lies in the extraction of reso...
P Esser, E Van der Voet


Multiple-Phase Pressure (MPP) Process: One-stage CCA treatment and accelerated fixation process. 4. MPP compared with other processes for achieving acceptable treatment of radiata pine heartwood
1998 - IRG/WP 98-40115
Although radiata pine sapwood is very amenable to preservative treatment, it is often difficult to achieve the required standard for heartwood treatment. A preliminary investigation showed that to achieve the NZ Timber Preservation Council minimum penetration requirements for radiata pine heartwood using the Multiple-Phase Pressure (MPP) Process, a hydraulic pressure of at least 1250 kPa for 20 m...
K Nasheri, J A Drysdale, G Durbin, M E Hedley


Effect of remediation on the release of copper, chromium, and arsenic from particleboard made from CCA treated wood
2001 - IRG/WP 01-50170
This study sought to determine the effect of remediation with oxalic acid (OA) extraction and Bacillus licheniformis fermentation on the release of copper, chromium, and arsenic from particleboard made from remediated wood particles and also investigates durability of the particleboard against white and brown- rot fungi. Particleboard samples were manufactured using untreated, CCA-treated, OA-extr...
S N Kartal, C A Clausen


The extraction of boron from treated wood for quantitative analysis: A comparison of procedures
1992 - IRG/WP 92-2414
The extraction of boron preservative from treated rubberwood and scots pine samples was compared using methods based on refluxing and extraction in 1N NaOH or distilled water at 80°C. The extract solutions were analysed by Inductively Coupled Plasma spectroscopy (ICP/AES). A simple extraction procedure based on immersion of wood samples of approximate dimension 2 x 1 x 1 cm³ in distilled water a...
R J Murphy, D J Dickinson, P W McCormack, M K Lung


Multiple-Phase Pressure (MPP) Process: One-stage CCA treatment and accelerated fixation process. 3. Effect of process variables on sapwood treatment and CCA fixation.
1998 - IRG/WP 98-40114
The Multiple-Phase Pressure (MPP) Process achieves treatment and fixation as combined process using hot CCA, within a 2-3 hour time-frame. Timber is treated to saturation with hot CCA using an empty cell process. During the pneumatic pressure phase, hot solution is held in the wood in an otherwise liquid-free treatment vessel until fixation is >95% complete. This report details a factorial des...
H Pearson, K Nasheri, J A Drysdale, G Durbin, M E Hedley


Treatment and recycle of CCA hazardous waste
1993 - IRG/WP 93-50007
Chromated copper arsenate containing hazardous materials is generated from the manufacture, treatment of the wood, and from the wood itself, after its life cycle. Laboratory treating of these wastes has resulted in materials suitable for recycle or disposal as non-hazardous residues. The extraction, by both acidic and ammoniacal routes, of CCA production and treating plant waste materials has been...
E A Pasek, C R McIntyre


Chemical reactions involved in furfurylation of solid wood - An investigation by ATR-IR spectroscopy
2006 - IRG/WP 06-40347
Wood modification with furfuryl alcohol (FA) has gained renewed interest during the last five to ten years because of advances in process technology and because of increased focus on the environmental hazards of traditional wood impregnation. The reaction mechanisms involved in the furfurylation process are not yet understood in detail. In the work presented here, the chemical reactions and their ...
T Mark Venås, L Garbrecht Thygesen, S Barsberg


Development of preservative treatment method using sub and super critical carbon dioxide
2007 - IRG/WP 07-40385
Significant efforts have been devoted for developing biocide impregnation method into wood materials using supercritical fluid. Developing better understandings of fluid phase and its effect on treatment results would facilitate a more rational development of supercritical fluid (SCF) impregnation. In this project, the preservative treatabilities under super- and sub-critical fluid conditions we...
Myeung-Won Cho, Sung-Mo Kang, Gyu-Hyeok Kim


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