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Distribution and availability of preservative components in ACQ treated wood - effects of coatings and weathering
2010 - IRG/WP 10-30537
Copper and quaternary ammonium compound (quat) distributions across lumber (gradients) and availability, as measured by amount removed by intensive leaching of wood flour, were measured in ACQ treated southern pine lumber. Samples were evaluated just after treatment and stabilization, or after 3 years of laboratory storage, or after 3 years of natural weathering exposure. The objective was to in...
T Ung, M Nejad, P Cooper


A Comparison of the Performance of Related Copper Based Preservatives against Soft Rot
2010 - IRG/WP 10-30540
The performance of pine and beech wood treated with either a soluble copper + quat (ACQ type D) preservative system or a particulate copper + quat system was evaluated in unsterile soil using the European standard ENV 807 soft rot decay test procedure. In addition, to compare soft rot performance of soluble and particulate copper directly without the influence of co-biocides, beech and pine test...
M Ray, D Dickinson, K Archer


Extruded wood plastic composites based on ACQ and MCQ-treated wood materials
2010 - IRG/WP 10-40495
This paper deals with wood plastic composites manufactured using ACQ and MCQ-treated wood fibers recovered from a wood treatment plant. The goal was to investigate the effect of coupling treatments on the properties of manufactured wood plastic composites (WPCs) through injection molding and to manufacture co-extruded WPC with treated wood fibers. The result demonstrated sound mechanical propertie...
Qinglin Wu, Fei Yao, K Ragon, J Curole, M Voitier, T Shupe


Influence of Copper Preservative Type on Earlywood and Latewood Distribution of Copper in Treated Wood
2010 - IRG/WP 10-40507
Some of the new water based copper containing wood preservative systems use particulate “micronized” copper as the primary biocide instead of the more traditional soluble amine copper based systems. Studies were conducted to investigate how this difference in the type of copper system might impact both initial and post drying distribution of the preservatives in wood. Of specific interest wa...
A Zahora


A comparison of the corrosion of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-40515
With the replacement of chromate copper arsenate (CCA) by alkaline copper wood preservatives, there have been reports of increasing corrosion of metal fasteners and connectors in contact with treated wood. This may be explained by the presence of more mobile copper in the treated wood. One novel industrial response has been to develop a wood preservative based on an aqueous solution containing sus...
M Kofoed, J N R Ruddick


Further Studies on the Distribution of Copper in Treated Wood Using an XRF Microscope Technique
2011 - IRG/WP 11-40549
There are two distinct forms of copper in aqueous copper based wood preservative systems that are currently used in the United States for treatment of southern pine lumber. These are systems using either soluble copper (typically amine based) or the more recent particulate or “micronized” copper as the primary biocide. Studies reported last year showed that there were distinct differences in...
A Zahora


Characterizing long term leaching behaviour of copper from preservative treated wood in a practical exposure scenario
2011 - IRG/WP 11-50278
To investigate the prediction of the long term emission of copper from preservative treated wood in a Use Class Class 3 scenario, treated boards were exposed vertically above ground to natural weather conditions. The study included two products; an amine copper ACQ-type formulation, air-dried after treatment to a 22 kg/m3 retention, and the same formulation which was hot oil vacuum dried after tre...
T Mark Venås, M Klamer


Inhibition of Basidiospore Germination by Copper from MCQ, ACQ and CCA Leachates
2012 - IRG/WP 12-10778
The long-term decay resistance of refractory wood shell-treated with chromated copper arsenate (CCA) in above-ground exposures has been attributed to mobile copper that migrates into checks and inhibits the germination of basidiospores. Copper from micronized copper quat (MCQ) has also been shown to migrate into checks suggesting similar performance as a shell treatment, but questions have been ra...
R Stirling, J Drummond, P I Morris


Performance of Wood Protection Systems at Multiple Field Test Sites Using the Ground Proximity Test Method
2012 - IRG/WP 12-20499
A series of preservative systems were used to treat southern pine ground proximity test samples which were then exposed at a range of test sites located throughout the world. The sites were chosen on the basis of having vastly different Scheffer Climate decay indices. After almost 14 years exposure, distinct differences are apparent in how different preservative systems perform at the different ...
A Zahora, A Preston, L Jin


Mold Control for Treated Lumber in Block-Stack Storage Conditions
2012 - IRG/WP 12-30588
The mold development and control for freshly treated and block-stacked wood have been evaluated using a green house mold testing method. The results for the mold resistance of several commonly used water boron preservative treatment systems, such as ACQ, Copper Azole, and borates with and without inclusion of mold inhibitors are presented. The data suggest that the different preservative treatme...
L Jin, P Walcheski, A Preston


Scale-up of a chemical process for copper-based preservative-treated wood wastes recycling
2012 - IRG/WP 12-50286
In recent years, the development of appropriate wood waste disposal options has been encouraged by severe regulations and expensive fees associated with wastes landfilling or burning. An efficient and economically attractive leaching process was developed at laboratory scale (200 mL) for CCA-, ACQ- and CA-treated wood wastes recycling. This leaching process consisted of three leaching steps of 2 h...
L Coudert, L Gastonguay, J F Blais, G Mercier, P Cooper, P Morris, A Janin, N Reynier


Developing Analytical Methods for Determination of Quaternary Ammonium Compounds (DDAC) using HPLC and HPLC-MS (Application to treating solution and preservatives treated wood)
2013 - IRG/WP 13-20516
Korea preservative treating industry has mainly used alkaline copper quaternary (ACQ) expected over 80% of market share in Korea. ACQ employs dodecyl dimethyl ammonium chloride (DDAC) and benzyl dimethyl dodecyl ammonium chloride (DBAC) for active ingredient along with copper. The strongly increasing domestic applications for wood preservatives require developing accurate and reproducible analytic...
Sung-Mo Kang, Kwon-Min Kim, Won-Mo Koo, Myeong-Won Cho


Combined effects of thermal modification and ACQ-D impregnation on properties of southern yellow pine wood
2013 - IRG/WP 13-40637
In this study, samples of southern yellow pine sapwood were first thermally modified and then treated by the alkaline copper quat-type D (ACQ-D) wood preservative. Two heating temperature (180℃ and 220℃) and two concentrations of ACQ-D solution (0.9% and 1.35%) were used in the experiments. The combined effects of thermal modification and ACQ-D on leaching performance, mechanical prope...
Wang Wang, Yuan Zhu, Jinzhen Cao


Conclusions and Summary Report on an Environmental Life Cycle Assessment of ACQ-Treated Lumber Decking with Comparisons to Wood Plastic Composite Decking
2013 - IRG/WP 13-50295
The Treated Wood Council has completed a quantitative evaluation of the environmental impacts associated with the national production, use, and disposition of ACQ (alkaline copper quaternary)-treated lumber decking and wood plastic composite decking using life cycle assessment (LCA) methodologies and following ISO 14044 standards. The results for treated wood decking are significant. • Less En...
AquAeTer, Inc.


Field performance of wood-based decking materials in the Western United States
2014 - IRG/WP 14-30645
While wood has long been used for the construction of decks and other outdoor features, a variety of wood-plastic composite (WPC) decking products have emerged over the past decade with claims of exceptional durability and low maintenance. There are relatively few long term comparative tests on these products. The performance of selected WPC decking products was compared with naturally durable we...
S Lipeh, C S Love, J J Morrell


Three-year field test of preservative-treated Canadian species in Korea
2014 - IRG/WP 14-30646
The purpose of this study was to generate field performance data in Korea on Canadian softwood species preservative-treated to Canadian standards. Two field tests of preservative-treated Canadian softwood species, one in ground contact and one above ground, were installed in Jinju, Korea in November 2010. Western hemlock and white spruce were incised and pressure-treated with alkaline copper quate...
Jieying Wang, Jong Bum Ra, P I Morris


Effect of exposure site on metal migration from copper azole, alkaline copper quat or chromated copper arsenate treated southern pine decking
2015 - IRG/WP 15-50313
Metal migration from chromated copper arsenate, copper azole or alkaline copper quaternary compound treated southern pine lumber was assessed at sites in Mississippi and Oregon. Metal levels tended to be consistently higher in decks exposed in Mississippi. Rainfall characteristics did differ slightly at the two sites, but the levels did not appear to be of a magnitude that might affect metal mobi...
J J Morrell, H M Barnes


Overview of the treated wood quality control program in the United States with the recent challenges and advances
2017 - IRG/WP 17-20616
In the past two decades, there have been significant and rapid changes in wood protection technologies for residential applications which have moved away from long established heavy duty metal oxide based products such as chromated copper arsenate (CCA). The successor generation of wood protection systems usually contain copper as the primary biocide, in combination with carbon-based co-biocides s...
L Jin


Review of Leaching Experiments of CCA-Treated Wood and Wood Treated with Copper-based Alternatives
2017 - IRG/WP 17-50330
The objective of this study was to compare leaching rates of various wood preservatives from treated wood and the tests used to gather this information. The preservatives compared included CCA and the copper-based alternatives, MCQ, ACQ, and MCA. The tests compared included AWPA E11, SPLP, TCLP, and environmental leaching tests. Among all of the tests evaluated, environmental tests most closely si...
A Jones, J Marini, H Solo-Gabriele


Evaluation of Decay Resistance of Copper-based Preservatives Treated-Wood exposed to different field test sites in Korea
2022 - IRG/WP 22-20679
In Korea, preservative treated wood is required to have a stamp on the surface which contains information such as wood species, use categories, and the company that treated the wood. Such stamping is necessary to safely and appropriately use the treated wood. Since majority of treated wood is being used outdoor environment, the treated wood must have efficacy against wood decay fungi or termite. I...
W-J Hwang, S-M Yoon, Y Park, Y-S Choi, H-M Lee, J-W Kim


Virtual Reality of Wood Protection
2023 - IRG/WP 23-20698
Virtual reality (VR) is a technology that allows people to explore and interact with computer generated environments using devices that stimulate different senses (sight, sound and touch). VR is mainly used for education, training and entertainment, but it also has the potential to provide new insights into scientific phenomena. In this paper we describe the evolution of VR and its many uses, focu...
D Feng, Y Liu, M Turner, A Limaye, P D Evans


Above Ground Proximity Decay Field Trial of Modified ACQ-A, Wolman® CA-B and Wolman® CA-C in Taiwan
2023 - IRG/WP 23-30793
An above ground proximity decay field trial was established at Chiayi county, Taiwan in July 2016. The purpose of this study was to generate local field performance data for Taiwan for Slash Pine treated with Wolman® CA-B, Wolman® CA-C and a modified ACQ-A product at AWPA UC3B actives retention. After 6 years of field trial, the efficacy of the wood preservative in preventing decay fungi and ter...
J-Y Gan


Non-vacuum/pressure ACQ treatment
2023 - IRG/WP 23-40971
Many developing countries are located in sub-tropical or tropical regions where rapid wood deterioration results in early failure of many structures. Whilst preservative treatment would help to reduce these losses and extend the forest resource commercial vacuum pressure treatment systems are often too expensive. The use of lower technology treatment systems, while not as quick as vacuum pressure ...
J Norton


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